Abstract
Extensive measurements were made using an Aerodyne quantum cascade laser absorption spectrometer (QCLAS) to study the diurnal and seasonal cycles of NH3 concentrations in Manchester city centre. Measurements made at rooftop levels showed traffic to be a significant source of NH3 concentrations in the winter. This was illustrated by a bimodal diurnal cycle of NH3 concentrations that was synchronized with traffic, and also by a correlation with NOx, a traffic related pollutant. These patterns were not observed during the summer, suggesting other sources become more important. Measurements were also made at street level during winter and summer, close to the traffic source. This time the contribution from traffic was also observed in the summer, albeit weaker. Enhanced NH3 concentrations were often seen in winds from the southwest that could not be related to local sources, suggesting that ambient concentrations in the city are strongly influenced by sources outside the city. It is estimated that the total NH3 emission from the city centre is between 0.7 and 2.3 t km−2 year−1.
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Bari, A., Ferraro, V., Wilson, L. R., Luttinger, D., & Husain, L. (2003). Measurements of gaseous HONO, HNO3, SO2, HCl, NH3, particulate sulphate and PM2.5 in New York, NY. Atmospheric Environment, 37, 2825–2835.
Brunekreef, B., & Holgate, S. T. (2002). Air pollution and health. Lancet, 360, 1233–1242.
Cadle, S. H., & Mulawa, P. A. (1980). Low molecular weight aliphatic amines in exhaust from catalyst-equipped cars. Environmental Science & Technology, 14, 718–723.
Cape, J. N., Tang, Y. S., van Dijk, N., Love, L., Sutton, M. A., & Palmer, S. C. F. (2004). Concentrations of ammonia and nitrogen dioxide at roadside verges, and their contribution to nitrogen deposition. Environmental Pollution, 132, 469–478.
DEFRA (2002). Ammonia in the UK. London, UK: Department for Environment, Food & Rural Affairs.
Dore, C. J., Watterson, J. D., Murrells, T. P., Passant, N. R., Hobson, M. M., Baggott, S. L. et al. (2005). UK emissions of air pollutants 1970 to 2003, National Atmospheric Emissions Inventory. UK: National Environmental Technology Centre.
Fraser, M. P., & Cass, G. R. (1998). Detection of excess ammonia emissions from in-use vehicles and the implications for fine particle control. Environmental Science & Technology, 32, 1053–1057.
Harkins, J. H., & Nicksic, S. W. (1967). Ammonia in auto exhaust. Environmental Science & Technology, 1, 751–752.
Horvath, H. (1992). Effects on visibility, weather and climate. In: M. Radojevic, & R. M. Harrison (Eds.), Atmospheric acidity: sources, consequences and abatement, chapter 13. London: Elsevier Applied Science.
Huai, T., Durbin, T. D., Miller, J. W., Pisano, J. T., Sauer, C. G., Rhee, S. H. et al. (2003). Investigation of NH3 emissions from new technology vehicles as a function of vehicle operating conditions. Environmental Science & Technology, 37, 4841–4847.
Kean, A. J., Harley, R. A., Littlejohn, D., & Kendall, G. R. (2000). On-road measurement of ammonia and other motor vehicle exhaust emissions. Environmental Science & Technology, 34, 3535–3539.
Kirchner, M., Braeutigam, S., Feicht, E., & Löflund, M. (2002). Ammonia emissions from vehicles and the effects on ambient air concentrations. Fresenius Environmental Bulletin, 11, 454–458.
Krupa, S. V. (2003). Effects of atmospheric ammonia (NH3) on terrestrial vegetation: A review. Environmental Pollution, 124, 179–221.
Lee, D. S., & Dollard, G. J. (1994). Uncertainties in current estimates of emissions of ammonia in the United Kingdom. Environmental Pollution, 86, 267–277.
Lee, H. S., Kang, C. M., Kang, B. W., & Kim, H. K. (1999) Seasonal variations of acidic air pollutants in Seoul, South Korea. Atmospheric Environment, 33, 3143–3152.
Li, Y., Schwab, J. J., & Demerjian, K. L. (2006). Measurements of ambient ammonia using a tunable diode laser absorption spectrometer: Characteristics of ambient ammonia emissions in an urban area of New York City. Journal of Geophysical Research, 111(D10), doi:10.1029/2005JD006275.
Longley, I. D., Inglis, D. W. F., Gallagher, M. W., Williams, P. I., Allan, J. D., & Coe, H. (2005). Using NOx and CO monitoring data to indicate fine aerosol number concentrations and emission factors in three UK conurbations. Atmospheric Environment, 39, 5157–5169.
McManus, J. B., Nelson, D. D., Shorter, J. H., Zahniser, M. S., Mueller, A., Bonetti, Y. et al. (2002). Quantum cascade lasers for open- and closed-path measurement of trace gases. Proceedings of SPIE, 4817, 22–33.
Moeckli, M. A., Fierz, M., & Sigrist, M. W. (1996). Emission factors for ethane and ammonia from a tunnel study with a photoacoustic trace gas detection system. Environmental Science & Technology, 30, 2864–2867.
Perrino, C., Catrambone, M., Di Menno Di Bucchianico, A., & Allegrini, I. (2002). Gaseous ammonia in the urban area of Rome, Italy, and its relationship with traffic emissions. Atmospheric Environment, 36, 5385–5394.
Pierson, W. R., & Brachaczek, W. W. (1983). Emissions of ammonia and amines from vehicles on the road. Environmental Science & Technology, 17, 757–760.
Pryor, S. C., Anlauf, K., Boudries, H., Hayden, K., Schiller, C. L., & Wiebe, A. (2004). Spatial and temporal variability of high resolution reduced nitrogen concentrations in the Fraser Valley. Atmospheric Environment, 38, 5825–5836.
Sakurai, T., Fujita, S. I., Hayami, H., & Furuhashi, N. (2003). A case study of high ammonia concentration in the nighttime by means of modeling analysis in the Kanto region of Japan. Atmospheric Environment, 37, 4461–4465.
Sutton, M. A., Dragosits, U., Tang, Y. S., & Fowler, D. (2000). Ammonia emissions from non-agricultural sources in the UK. Atmospheric Environment, 34, 855–869.
Twigg, M., Famulari, D., Fowler, D., Gallagher, M., Nemitz, E., Sutton, M. A. et al. (2005) Principles and development of tunable laser diode absorption spectroscopy for measuring fluxes of ammonia and nitric acid. Proceedings of the First ACCENT Symposium, Urbino, pp. 12–16 (Sept.).
Vogt, E., Held, A., & Klemm, O. (2005). Sources and concentrations of gaseous and particulate reduced nitrogen in the city of Münster (Germany). Atmospheric Environment, 38, 7393–7402.
Whitehead, J. D. (2006) Atmospheric ammonia measurements using a quantum cascade laser absorption spectrometer. PhD thesis, School of Earth, Atmospheric and Environmental Sciences, The University of Manchester, UK.
Wyers, G. P., Otjes, R. P., & Slanina, J. (1993) A continuous-flow denuder fro the measurements of ambient concentrations and surface-exchange fluxes of ammonia. Atmospheric Environment, 27A, 2085–2090
Yamamoto, N., Kabeya, N., Onodera, M., Takahahi, S., Komori, Y., Nakazuka, E. et al. (1988). Seasonal variation of atmospheric ammonia and particulate ammonium concentrations in the urban atmosphere of Yokohama over a 5-year period. Atmospheric Environment, 22, 2621–2623.
Yamamoto, N., Nishiura, H., Honjo, T., Ishikawa, Y., & Suzuki, K. (1995). A long-term study of atmospheric ammonia and particulate ammonium concentrations in Yokohama, Japan. Atmospheric Environment, 29, 97–103.
Acknowledgments
The Mason Centre for Environmental Flows, Manchester provided the funds for purchasing the QCLAS system as part of a SRIF award. The authors are also grateful to Mark Zahniser and his team at Aerodyne Research, Inc. for all their continuing support.
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Whitehead, J.D., Longley, I.D. & Gallagher, M.W. Seasonal and Diurnal Variation in Atmospheric Ammonia in an Urban Environment Measured Using a Quantum Cascade Laser Absorption Spectrometer. Water Air Soil Pollut 183, 317–329 (2007). https://doi.org/10.1007/s11270-007-9381-5
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DOI: https://doi.org/10.1007/s11270-007-9381-5