Skip to main content
Log in

From Mountain Ranges to Sweeping Plains, in Droughts and Flooding Rains; River Murray Water Quality over the Last Four Decades

  • Published:
Water Resources Management Aims and scope Submit manuscript

Abstract

The aim of this paper was to analyse the spatial and temporal patterns and drivers of water quality in a large arid/semi-arid river system (River Murray, Australia) using a long term (1978 − 2015) dataset collected from 24 monitoring sites. The water quality is highly variable, but on average electrical conductivity (EC), pH, turbidity, dissolved and total nutrient, colour and chlorophyll a levels increase with distance downstream from the headwaters to the lower reaches. This is a function of the natural accumulation of dissolved and particulate components and intermittent, mostly diffuse source, pollutant inputs. The Darling tributary inflow increases turbidity, total phosphorus and pH in the main River Murray channel. Based on long-term trend analysis at four representative sites, EC, nutrients and colour showed declining trends on average at most sites except in the headwaters. Increased flow increases concentrations of most quality parameters, although at very high flows decreases in pH, EC, turbidity and oxidized nitrogen were apparent at many sites. The extreme “Millennium” drought (2002 − 2009) period resulted in lowered concentrations of many water quality parameters, indicating retention in the landscape. In the post-drought flooding (2010 − 2012) period a large amount of organic material was mobilised, resulting in much higher peak colour concentrations than when mid-range flooding was more frequent. It is critical that this monitoring program is continued as a Basin-wide water management plan is implemented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • APHA (2005) Standard methods for the examination of water and wastewater, 21st edn. American Public Health Association, American Water Works Association and Water Environment Federation, Washington, DC

    Google Scholar 

  • Atech (2000) Aggregated nutrient emissions to the Murray-Darling basin. Report for the National Pollutant Inventory Environment Australia, Atech Group Available at: http://www.npi.gov.au/system/files/resources/3084e6e3-8e3f-c654-e9ec-acf6865ca069/files/mdbreport.pdf

    Google Scholar 

  • Biswas TK (2014) Old basin same problems: murray darling basin salinity impacts and management interventions. In: Proceedings of Third International Salinity Forum, Riverside, California, pp 44–45. http://salinityforum2014.ucr.edu

  • Bowling LC, Merrick C, Swann J, Green D, Smith G, Neilan BA (2013) Effects of hydrology and river management on the distribution, abundance and persistence of cyanobacterial blooms in the Murray River, Australia. Harmful Algae 30:27–36

    Article  Google Scholar 

  • Burt TP, Howden NJK, Worrall F (2014) On the importance of very long-term water quality records. Wiley Interdiscip Rev Water 1:41–48

    Article  Google Scholar 

  • Croome R, Wheaton L, Henderson B, Oliver R, Vilizzi L, Paul W, McInerney P (2011) River Murray water quality monitoring program: phytoplankton data trend analysis 1980-2008. Final Report prepared for the Murray-Darling Basin Authority by The Murray-Darling Freshwater Research Centre, MDFRC Publication 06/2011, June, 81pp [plus Appendices I to IV, 131pp]

  • Crosbie RS, Morrow D, Cresswell RG, Leaney FW, Lamontagne S, Lefournour M (2012) New insights into the chemical and isotopic composition of rainfall across Australia. CSIRO Water for a Healthy Country Flagship, Australia

    Google Scholar 

  • Donnelly TH, Grace MR, Hart BT (1997) Algal blooms in the Darling-Barwon River, Australia. Water Air Soil Pollut 99:487–496

    Google Scholar 

  • Douglas GB, Hart BT, Beckett R, Gray CM, Oliver RL (1999) Geochemistry of suspended particulate matter (SPM) in the Murray-Darling river system: a conceptual isotopic/geochemical model for the fractionation of major, trace and rare earth elements. Aquat Geochem 5:167–194

    Article  Google Scholar 

  • Fitzpatrick R, Shand P, Mosley L (2017) Acid sulfate soil evolution models and pedogenic pathways during drought and reflooding cycles in irrigated areas and adjacent natural wetlands. Geoderma 308:270–290

    Article  Google Scholar 

  • GHD (1992) An investigation of nutrient pollution in the Murray-Darling river system. Report to the Murray-Darling Basic Commission

  • Giakoumakis S, Tsakiris G (1997) Meteorological drought effect on sediment yield. Water Resour Manag 11:365–376

    Article  Google Scholar 

  • Harris GP (2001) A nutrient dynamics model for Australian waterways: land use, catchment biogeochemistry and water quality in Australian Rivers, Lakes and Estuaries. Australian State of the Environment Second Technical Paper Series (Inland Waters), Department of Environment and Heritage, Canberra

  • Hart BT (2015a) The Australian Murray-Darling basin plan: challenges in its implementation (part 1). Internat J Water Resour Develop. https://doi.org/10.1080/07900627.2015.1083847

  • Hart BT (2015b) The Australian Murray-Darling basin plan: challenges in its implementation (part 2). Internat J Water Resour Develop. https://doi.org/10.1080/07900627.2015.1084494

  • Hart BT, Davidson D (2017) The Murray-Darling basin plan. In: Hart BT, Doolan J (eds) Decision making in water resources policy, planning and management: the Australian experience, chapter 13. Elsevier Publishing, New York, pp 221–244

    Chapter  Google Scholar 

  • Helsel DR, Hirsch RM (2002) Statistical methods in water resources. Chapter A3. In: Techniques of water-resources investigations of the United States geological survey; Book 4, hydrologic analysis and interpretation, 510 pp. Available at http://water.usgs.gov/pubs/twri/twri4a3/

  • Henderson B (2006) Updated water quality trend analyses for key sites monitored as part of the MDBC's River Murray Water Quality Monitoring Program, 1978-2005. A report for the Murray-Darling Basin Commission. CMIS Report Number 06/78, June 2006

  • Henderson B, Liu Y, Baldwin D (2013) Trends in physical and chemical aspects of water quality in the Murray-Darling basin 1978-2012. CSIRO Water for a Healthy Country Flagship, Australia

    Google Scholar 

  • Herczeg AL, Dogramaci SS, Leaney FWJ (2001) Origin of dissolved salts in a large, semi-arid groundwater system: Murray Basin, Australia. Mar Freshw Res 52:41–52

    Article  Google Scholar 

  • Higgins RJ (1990) Off-river storages as sources and sinks for environmental contaminants. River Res Appl 5:401–412

    Article  Google Scholar 

  • Howden NJK, Burt TP, Worrall F, Whelan MJ, Bieroza M (2010) Nitrate concentrations and fluxes in the river Thames over 140 years (1868–2008): are increases irreversible? Hydrol Process 23:2657–2662

    Article  Google Scholar 

  • Howitt JA, Baldwin DS, Rees GN, Williams JL (2007) Modelling Blackwater: predicting water quality during flooding of lowland river forests. Ecol Model 203:229–242

    Article  Google Scholar 

  • Lutz SR, Mallucci S, Diamantini E, Majone B, Bellin A, Merz R (2016) Hydroclimatic and water quality trends across three Mediterranean river basins. Sci Total Environ 571:1392–1406

    Article  Google Scholar 

  • Mackay N, Hillman T, Rolls J (1988) Water quality of the river Murray – review of monitoring 1978 to 1986. Water Quality. Report No.1, Murray-Darling Basin Commission, Canberra. 62 pp

  • Maheshwari BL, Walker KF, McMahon TA (1995) Effects of regulation on the flow regime of the river Murray, Australia. River Res Appl 10:15–38

    Article  Google Scholar 

  • Mann HB (1945) Nonparametric test against trend. Econometrica 13:245–259

    Article  Google Scholar 

  • MDBA (2010) Guide to the proposed Basin Plan: technical background, Murray–Darling Basin Authority, Canberra, 1188pp. Available at: http://www.mdba.gov.au/kid/guide/

  • MDBA (2015) Basin Salinity Management 2030 (BSM2030). Murray–Darling Basin Authority. Publication No. 21/15

  • MDBA (2017) Towards a healthy, working Murray–Darling basin: Basin Plan annual report 2015-16. Canberra: Murray–Darling Basin Authority. Publication No. 4/17

  • Mosley LM (2015) Drought impacts on the water quality of freshwater systems; review and integration. Earth Sci Rev 140:203–214

    Article  Google Scholar 

  • Mosley LM, Fleming N (2010) Pollutant loads returned to the lower Murray River from flood-irrigated agriculture. Water Air Soil Pollut 211:475–487

    Article  Google Scholar 

  • Mosley LM, Zammit B, Leyden E, Heneker TM, Hipsey MR, Skinner D, Aldridge KT (2012) The impact of extreme low flows on the water quality of the lower Murray River and lakes (South Australia). Water Resour Manag 26:3923–3946

    Article  Google Scholar 

  • Mosley LM, Zammit B, Jolley A-M, Barnett L, Fitzpatrick R (2014) Monitoring and assessment of surface water acidification following rewetting of oxidised acid sulfate soils. Environ Monit Assess 186(1):1–18

  • Murdoch PS, Baron JS, Miller TL (2000) Potential effects of climate changce on surface-water quality in North America. J American Water Resour Assoc 36:347–366

    Article  Google Scholar 

  • Olley J, Wallbrink P (2004) Recent trends in turbidity and suspended sediment loads in the Murrumbidgee River, NSW, Australia. In Sediment Transfer through the Fluvial Svstem (Proceedings of a symposium held in Moscow. August 2004). IAI IS Publ. 288

  • Orr HG, Simpson GL, des Clers S, Watts G, Hughes M, Hannaford J, Dunbar MJ, CLR L, Wilby RL, Battarbee RW, Evans R (2015) Detecting changing river temperatures in England and Wales. Hydrol Process 29:752–766

    Article  Google Scholar 

  • Qiao Y, Feng J, Liu X, Wang W, Zhang P, Zhu L (2016) Surface water pH variations and trends in China from 2004 to 2014. Environ Monit Assess 188:443. https://doi.org/10.1007/s10661-016-5454-5

    Article  Google Scholar 

  • Roberts J, Kumar A, Du J, Hepplewhite C, Ellis DJ, Christy AG, Beavis SG (2016) Pharmaceuticals and personal care products (PPCPs) in Australia's largest inland sewage treatment plant, and its contribution to a major Australian river during high and low flow. Sci Total Environ 541:1625–1637

    Article  Google Scholar 

  • Shafron M, Croome R, Rolls J (1990) Water quality. In: Mackay N, Eastburn D (eds) The Murray. Murray-Darling Basin Commission, Canberra

    Google Scholar 

  • Small K, Keller R, Kopf RJ, Watts JH (2014) Hypoxia, Blackwater and fish kills: experimental lethal oxygen thresholds in juvenile predatory Lowland River fishes. PLoS One. https://doi.org/10.1371/journal.pone.0094524

  • Turner RE, Rabalais NN (1991) Changes in Mississippi River water quality this century. BioScience 41:140–147

    Article  Google Scholar 

  • van Dijk AIJM, Beck HE, Crosbie RS, de Jeu RAM, Liu YY, Podger GM, Timbal B, Viney NR (2013) The millennium drought in Southeast Australia (2001–2009): natural and human causes and implications for water resources, ecosystems, economy, and society. Water Resour Res 49. https://doi.org/10.1002/wrcr.20123

  • van Vliet MTH, Ludwig F, Zwolsman JJG, Weedon GP, Kabat P (2011) Global river temperatures and sensitivity to atmospheric warming and changes in river flow. Water Resour Res 47:W02544

    Google Scholar 

  • Ward NJ, Bush RT, Sullivan LA, Fyfe DM, Coughran J, Tulau M, Allman B, Morand D, Wong VNL (2010) Assessment of acid sulfate soil materials in the Edward and Wakool Rivers region of the Murray-Darling Basin. Southern Cross GeoScience Technical Report No. 410, Southern Cross University, Lismore, NSW, 162 pp

  • Whitworth KL, Baldwin DS, Kerr JL (2012) Drought, floods and water quality: drivers of a severe hypoxic Blackwater event in a major river system (the southern Murray–Darling basin, Australia). J Hydrol 450–451:190–198

    Article  Google Scholar 

  • Whitworth KL, Kerr JL, Mosley LM, Conallin J, Hardwick L, Baldwin DS (2013) Options for managing hypoxic Blackwater in river systems: case studies and framework. Environ Manag 114:139–147

    Google Scholar 

  • Zhang A, Oldham C (2001) The use of an ultrafiltration technique for measurement of orthophosphate in shallow wetlands. Sci Total Environ 266:159–167

    Article  Google Scholar 

Download references

Acknowledgements

We would like to thank Prof. Barry Hart for a critical review of an earlier draft of this manuscript that enabled us to greatly improve our analysis. The funding support of the Murray Darling Basin Authority and provision of this valuable dataset is greatly acknowledged, as is the various individuals and organisations who have been involved in the successful delivery of the water quality monitoring program.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Luke M. Mosley.

Ethics declarations

Conflict of Interest

None.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

ESM 1

(DOCX 1040 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Biswas, T.K., Mosley, L.M. From Mountain Ranges to Sweeping Plains, in Droughts and Flooding Rains; River Murray Water Quality over the Last Four Decades. Water Resour Manage 33, 1087–1101 (2019). https://doi.org/10.1007/s11269-018-2168-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11269-018-2168-1

Keywords

Navigation