Abstract
PTFE/α-alumina composites are well known to exhibit very low wear rates compared to unfilled PTFE and various other PTFE-matrix composites. The improved wear life of these composites is attributed in part to the formation of a uniform protective transfer film on the metal countersurface. It is postulated that the retention of transferred material and the recirculation of third bodies between the transfer film and running surface of the polymer composite are necessary for the maintenance of low wear within this tribological system. The accumulation of these third bodies was observed in reciprocating sliding tests on countersamples prescribed with aligned roughness. Wear performance of the polymer composite was tested as a function of the between the sliding direction and the aligned roughness of the countersample, ranging from parallel to perpendicular to the sliding direction. The wear rate of roughness oriented with the sliding direction was 300 times higher than roughness perpendicular to the sliding direction, revealing the importance of surface morphology and third body retention.
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Renfrew, M.M., Lewis, E.E.: Polytetrafluoroethylene. Heat resistant, chemically inert plastic. Ind. Eng. Chem. 38, 870–877 (1946)
Shooter, K.V., Tabor, D.: The frictional properties of plastics. Proc. Phys. Soc. Sect. B 65, 661–671 (1952)
King, R.F., Tabor, D.: The effect of temperature on the mechanical properties and the friction of plastics. Proc. Phys. Soc. London Sect. B 66, 728–736 (1953)
Flom, D.G., Porile, N.T.: Friction of teflon sliding on teflon. J. Appl. Phys. 26, 1088–1092 (1955)
Makinson, K.R., Tabor, D.: The friction and transfer of polytetrafluoroethylene. Proc. R. Soc. A. Math. Phys. Eng. Sci. 281, 49–61 (1964)
Deli, G., Qunji, X., Hongli, W.: Study of the wear of filled polytetrafluoroethylene. Wear 134, 283–295 (1989)
Deli, G., Bing, Z., Qun-Ji, X., Hong-Li, W.: Investigation of adhesion wear of filled polytetrafluoroethylene by ESCA, AES and XRD. Wear 137, 25–39 (1990)
Blanchet, T.A., Kennedy, F.E.: Sliding wear mechanism of polytetrafluoroethylene (PTFE) and PTFE composites. Wear 153, 229–243 (1992)
Sawyer, W.G., Freudenberg, K.D., Bhimaraj, P., Schadler, L.S.: A study on the friction and wear behavior of PTFE filled with alumina nanoparticles. Wear 254, 573–580 (2003)
Tanaka, K., Kawakami, S.: Effect of various fillers on the friction and wear of polytetrafluoroethylene-based composites. Wear 79, 221–234 (1982)
Bahadur, S., Tabor, D.: The wear of filled polytetrafluoroethylene. Wear 98, 1–13 (1984)
Li, F., Hu, K., Li, J., Zhao, B.: The friction and wear characteristics of nanometer ZnO filled polytetrafluoroethylene. Wear 249, 877–882 (2002)
Chen, W.X., et al.: Tribological behavior of carbon-nanotube-filled PTFE composites. Tribol. Lett. 15, 275–278 (2003)
Burris, D.L., et al.: A route to wear resistant PTFE via trace loadings of functionalized nanofillers. Wear 267, 653–660 (2009)
Burris, D.L., Sawyer, W.G.: Improved wear resistance in alumina-PTFE nanocomposites with irregular shaped nanoparticles. Wear 260, 915–918 (2006)
Lai, S.-Q., Yue, L., Li, T.-S., Hu, Z.-M.: The friction and wear properties of polytetrafluoroethylene filled with ultrafine diamond. Wear 260, 462–468 (2006)
McElwain, S.E., Blanchet, T.A., Schadler, L.S., Sawyer, W.G.: Effect of particle size on the wear resistance of alumina-filled PTFE Micro- and nanocomposites. Tribol. Trans. 51, 247–253 (2008)
Blanchet, T., Kandanur, S., Schadler, L.: Coupled effect of filler content and countersurface roughness on PTFE nanocomposite wear resistance. Tribol. Lett. 40, 11–21 (2010)
Khedkar, J., Negulescu, I., Meletis, E.I.: Sliding wear behavior of PTFE composites. Wear 252, 361–369 (2002)
Klaas, N.V., Marcus, K., Kellock, C.: The tribological behaviour of glass filled polytetrafluoroethylene. Tribol. Int. 38, 824–833 (2005)
Burris, D.L., Sawyer, W.G.: Tribological sensitivity of PTFE/alumina nanocomposites to a range of traditional surface finishes. Tribol. Trans. 48, 147–153 (2005)
Krick, B.A., Ewin, J.J., Blackman, G.S., Junk, C.P., Sawyer, W.G.: Environmental dependence of ultra-low wear behavior of polytetrafluoroethylene (PTFE) and alumina composites suggests tribochemical mechanisms. Tribol. Int. 51, 42–46 (2012)
Ye, J., Khare, H.S., Burris, D.L.: Transfer film evolution and its role in promoting ultra-low wear of a PTFE nanocomposite. Wear 297, 1095–1102 (2013)
Dascalescu, D., Polychronopoulou, K., Polycarpou, A.A.: The significance of tribochemistry on the performance of PTFE-based coatings in CO2 refrigerant environment. Surf. Coat. Technol. 204, 319–329 (2009)
Khare, H.S., et al.: Interrelated effects of temperature and environment on wear and tribochemistry of an ultralow wear PTFE composite. J. Phys. Chem. C 119, 16518–16527 (2015)
Pitenis, A.A., Ewin, J.J., Harris, K.L., Sawyer, W.G., Krick, B.A.: In vacuo tribological behavior of polytetrafluoroethylene (PTFE) and alumina nanocomposites: the importance of water for ultralow wear. Tribol. Lett. 53, 189–197 (2014)
Krick, B.A., Ewin, J.J., McCumiskey, E.J.: Tribofilm formation and run-in behavior in ultra-low-wearing polytetrafluoroethylene (PTFE) and alumina nanocomposites. Tribol. Trans. 57, 1058–1065 (2014)
Pitenis, A.A., et al.: Ultralow wear PTFE and alumina composites: it is all about tribochemistry. Tribol. Lett. 57, 4 (2015)
Urueña, J.M., Pitenis, A.A., Harris, K.L., Sawyer, W.G.: Evolution and wear of fluoropolymer transfer films. Tribol. Lett. 57, 9 (2015)
Harris, K.L., et al.: PTFE tribology and the role of mechanochemistry in the development of protective surface films. Macromolecules 48, 3739–3745 (2015). doi:10.1021/acs.macromol.5b00452
Wieleba, W.: The statistical correlation of the coefficient of friction and wear rate of PTFE composites with steel counterface roughness and hardness. Wear 252, 719–729 (2002)
Scherge, M., Kramlich, J., Böttcher, R., Hoppe, T.: Running-in due to material transfer of lubricated steel/PA46 (aliphatic polyamide) contacts. Wear 301, 758–762 (2013)
Santner, E., Czichos, H.: Tribology of polymers. Tribol. Int. 22, 103–109 (1989)
Franklin, S.E., de Kraker, A.: Investigation of counterface surface topography effects on the wear and transfer behaviour of a POM–20 % PTFE composite. Wear 255, 766–773 (2003)
Friedrich, K., Lu, Z.: Effects of steel counterface roughness and temperature on the friction and wear of PE (E) K composites under dry sliding conditions *. Wear 148, 235–247 (1991)
Bahadur, S.: The development of transfer layers and their role in polymer tribology. Wear 245, 92–99 (2000)
Biswas, S.K., Vijayan, K.: Friction and wear of PTFE—a review. Wear 158, 193–211 (1992)
Chromik, R.R., Baker, C.C., Voevodin, A.A., Wahl, K.J.: In situ tribometry of solid lubricant nanocomposite coatings. Wear 262, 1239–1252 (2007)
Wahl, K.J., Chromik, R.R., Lee, G.Y.: Quantitative in situ measurement of transfer film thickness by a Newton’s rings method. Wear 264, 731–736 (2008)
Scharf, T.W., Singer, I.L.: Role of the transfer film on the friction and wear of metal carbide reinforced amorphous carbon coatings during run-in. Tribol. Lett. 36, 43–53 (2009)
Singer, I.L., Dvorak, S.D., Wahl, K.J., Scharf, T.W.: Role of third bodies in friction and wear of protective coatings. J. Vac. Sci. Technol. A Vac. Surf. Film 21, S232–S240 (2003)
Feser, T., Stoyanov, P., Mohr, F., Dienwiebel, M.: The running-in mechanisms of binary brass studied by in situ topography measurements. Wear 303, 465–472 (2013)
Fusaro, R.L.: Self-lubricating polymer composites and polymer transfer film lubrication for space applications. Tribol. Int. 23, 105–122 (1990)
Schwartz, C.J., Bahadur, S.: Studies on the tribological behavior and transfer film–counterface bond strength for polyphenylene sulfide filled with nanoscale alumina particles. Wear 237, 261–273 (2000)
Maurice, G.: The third-body approach: a mechanical view of wear. Wear 100, 437–452 (1984)
Jintang, G.: Tribochemical effects in formation of polymer transfer film. Wear 245, 100–106 (2000)
Junk, C.P., Sawyer, W.G., Krick, B.A., Blackman, G.S., Wetzel, M.D.: Low-wear fluoropolymer composites. World Patent Application WO2012158650A1 (2012)
Schmitz, T.L., Action, J.E., Ziegert, J.C., Sawyer, W.G.: The difficulty of measuring low friction: uncertainty analysis for friction coefficient measurements. J. Tribol. 127, 673–678 (2005)
Rowe, K.G., Erickson, G.M., Sawyer, W.G., Krick, B.A.: Evolution in surfaces: interaction of topography with contact pressure during wear of composites including dinosaur dentition. Tribol. Lett. 54, 249–255 (2013)
Archard, J.F., Hirst, W.: The wear of metals under unlubricated conditions. Proc. R. Soc. London. Ser. A. Math. Phys. Sci. 236, 397–410 (1956)
Schmitz, T.L., Action, J.E., Burris, D.L., Ziegert, J.C., Sawyer, W.G.: Wear-Rate uncertainty analysis. J. Tribol. 126, 802–808 (2004)
Godet, M.: In tribology. Wear 136, 29–45 (1990)
Colombié, C., Berthier, Y., Floquet, A., Vincent, L., Godet, M.: Fretting: load carrying capacity of wear debris. J. Tribol. 106, 194 (1984)
Godet, M., Play, D., Berthe, D.: An attempt to provide a unified treatment of tribology through load carrying capacity, transport, and continuum mechanics. J. Lubr. Technol. 102, 153 (1980)
Wahl, K.J., Belin, M., Singer, I.L.: A triboscopic investigation of the wear and friction of MoS2 in a reciprocating sliding contact. Wear 214, 212–220 (1998)
Scharf, T.W., Singer, I.L.: Tribometry. Tribol. Trans. 45, 363–371 (2002)
Dvorak, S.D., Wahl, K.J., Singer, I.L.: In situ analysis of third body contributions to sliding friction of a Pb–Mo–S coating in dry and humid air. Tribol. Lett. 28, 263–274 (2007)
Shockley, J.M., Descartes, S., Irissou, E., Legoux, J.G., Chromik, R.R.: Third body behavior during dry sliding of cold-sprayed Al–Al 2O3 composites: in situ tribometry and microanalysis. Tribol. Lett. 54, 191–206 (2014)
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Harris, K.L., Curry, J.F., Pitenis, A.A. et al. Wear Debris Mobility, Aligned Surface Roughness, and the Low Wear Behavior of Filled Polytetrafluoroethylene. Tribol Lett 60, 2 (2015). https://doi.org/10.1007/s11249-015-0581-7
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DOI: https://doi.org/10.1007/s11249-015-0581-7