Abstract
Friction and wear of polyphenylene sulfide (PPS) mixed with ethylene butyl acrylate (EBA) were studied using a block-on-ring tribotester. Results showed that the friction coefficient decreases with an increase in the EBA content due to the reduced surface contact area occupied by the PPS. The PPS/EBA composite showed higher threshold temperatures for viscoelastic behavior and the wear rate was significantly decreased after mixing with EBA due to a radical reduction in transfer films. The wear mechanism of the composite changed from an adhesive wear mode to an abrasive wear mode upon the addition of EBA, which supports the wear debris morphology and the wear map suggested by Lancaster (Proc Inst Mech Eng 183:98–106, 1968).
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References
Domininhaus, H.: Plastics for Engineering: Materials, Properties and Applications. Hanser Publishers, Munich (1993)
Budinski, K.G., Budinski, M.K.: Engineering Materials; Properties and Selection. Prentice-Hall, Upper Saddle River (1997)
Fridirich, K.: Recent advances in polymer composites’ tribology. Wear 190, 139–144 (1995)
Matthews, F.L., Rawlings, R.D.: Composite Materials: Engineering and Science. Woodhead Publishing Limited, Cambridge (1999)
Chawla, K.K.: Composite Materials: Science and Engineering, 2nd edn. Springer, New York (1998)
Duan, Y., Cong, P., Liu, X., Li, T.: Comparative study of tribological properties of polyphenylene sulfide, polyethersulfone, and polysulfone. J. Macromol. Sci. B 48, 269–281 (2009)
Yamamoto, Y., Hashimoto, M.: Friction and wear of water lubricated PEEK and PPS sliding contacts. Part 2. Composites with carbon or glass fibre. Wear 257, 181–189 (2004)
Yu, L.G., Liu, W.M., Xue, Q.J.: Transition between transient and steady-state wear in the sliding of poly(phenylene sulfide) against a tool steel counterface. J. Appl. Polym. Sci. 69, 1099–1106 (1998)
Bahadur, S.: The development of transfer layers and their role in polymer tribology. Wear 245, 92–101 (2000)
Yu, L., Bahadur, S.: An investigation of the transfer film characteristics and the tribological behaviors of polyphenylene sulfide composites in sliding against tool steel. Wear 214, 245–251 (1998)
Bahadur, S., Sunkara, C.: Effect of transfer film structure, composition and bonding on the tribological behavior of polyphenylene sulfide filled with nano particles of TiO2, ZnO, CuO and SiC. Wear 258, 1411–1421 (2005)
Schwartz, C.J., Bahadur, S.: Studies on the tribological behavior and transfer film-countersurface bond strength for polyphenylene sulfide filled with nanoscale alumina particles. Wear 237, 261–273 (2000)
Chen, Z., Li, T., Yang, Y., Liu, X., Lü, R.: Mechanical and tribological properties of PA/PPS blends. Wear 257, 696–707 (2004)
Chen, Z., Liu, X., Li, T., Lü, R.: Mechanical and tribological properties of PA66/PPS blend. II. Filled with PTFE. J. Appl. Polym. Sci. 101, 969–977 (2006)
Chen, Z., Liu, X., Lü, R., Li, T.: Mechanical and tribological properties of PA66/PPS blend reinforced with carbon fiber. J. Appl. Polym. Sci. 105, 602–608 (2007)
Shin, M.W., Kim, S.S., Jang, H.: Friction and wear of polyamide 66 with different weight average molar mass. Tribol. Lett. 44, 151–158 (2011)
Stachowiak, G.W., Batchelor, A.W.: Engineering Tribology, 3rd edn. Butterworth-Heinemann, Oxford (2005)
Cheng, S.: Phase Transitions in Polymers. Elsevier Science, Amsterdam (2008)
Kim, S.S., Shin, M.W., Jang, H.: Tribological properties of short glass fiber reinforced polyamide 12 sliding on medium carbon steel. Wear 274–275, 34–42 (2012)
Lancaster, J.K.: Relationships between the wear of polymers and their mechanical properties. Proc. Inst. Mech. Eng. 183, 98–106 (1968)
Aharoni, S.M.: Wear of polymer by roll-formation. Wear 25, 309–327 (1973)
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This study was supported by the Korea Research Foundation (KRF) through the National Research Laboratory Program (no. 2011-0020470).
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Kim, S.S., Shin, M.W. & Jang, H. The Wear Mechanism of a Polyphenylene Sulfide (PPS) Composite Mixed with Ethylene Butyl Acrylate (EBA). Tribol Lett 47, 165–173 (2012). https://doi.org/10.1007/s11249-012-9973-0
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DOI: https://doi.org/10.1007/s11249-012-9973-0