Abstract
The tribological properties of Cu-based and Zr-based bulk metallic glasses (BMGs) sliding against Si3N4 under dry and water lubrication were studied on a pin-on-disc tribometer. The wear mechanisms of bulk metallic glasses were investigated based on the calculated flash temperature. The friction coefficients if fully amorphous alloy are about 0.7, while those of BMGs with nanocrytalline are a little higher. The wear rates of Cu-based BMG (V101) are about one order of magnitude lower than those of Zr-based BMG (Vit1) under dry friction, even two orders of magnitude lower under water lubrication. The wear resistance of bulk metallic glasses was influenced by the flash temperature. The calculated flash temperature (3,337 K) on the friction surface of Zr-based amorphous alloy exceeds its glass transition temperature, even its melting temperature. The high flash temperature leads to glass transition accompanied with viscous flow and material transfer, which is responsible for the poor wear resistance of Zr-based BMGs.
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Inoue, A., Takeuchi, A.: Recent progress in bulk glassy, nanoquasicrystalline and nanocrystalline alloys. Mater. Sci. Eng. A 375–377, 16–20 (2004). doi:10.1016/j.msea.2003.10.159
Hiromoto, S., Tsai, A.P., Sumita, M., Hanawa, T.: Corrosion behavior of Zr65Al7.5Ni10Cu17.5 amorphous alloys for biomedical use. Mater. Trans. 41, 654–659 (2000)
Greer, A.L.: Metallic glasses. Curr. Opin. Solid State Mater. Sci. 2(4), 412–416 (1997)
Fleury, E., Lee, S.M., Ahn, H.S., Kim, W.T., Kim, D.H.: Tribological properties of bulk metallic glasses. Mater. Sci. Eng. A 375–377, 276–279 (2004). doi:10.1016/j.msea.2003.10.065
Yokoyama, Y., Yamano, K., Fukaura, K., Sunada, H., Inoue, A.: Nanocrystalline Zr-based bulk glassy alloys with high flexural strength. Mater. Trans. 40, 1015–1018 (1999)
Ma, M.Z., Liu, R.P., Xiao, Y., Lou, D.C., Liu, L., Wang, Q., Wang, W.K.: Wear resistance of Zr-based bulk metallic glass applied in bearing rollers. Mater. Sci. Eng. A 386, 326–330 (2004)
Tam, C.Y., Shek, C.H.: Abrasive wear of Cu60Zr30Ti10 bulk metallic glass. Mater. Sci. Eng. A 384, 138–142 (2004). doi:10.1016/j.msea.2004.05.073
Fu, X.Y., Rigney, D.A., Falk, M.L.: Sliding and deformation of metallic glass: experiments and MD simulations. J. Non-Cryst. Solids 317, 206–214 (2002). doi:10.1016/S0022-3093(02)01999-3
Fu, X.Y., Kasai, T., Falk, M.L., Rigney, D.A.: Sliding behavior of metallic glass Part I. Experimental investigations. Wear 250, 409–419 (2001). doi:10.1016/S0043-1648(01)00605-6
Fu, X.Y., Rigney, D.A., Falk, M.L.: Sliding behavior of metallic glass Part II. Computer simulations. Wear 250, 420–430 (2001). doi:10.1016/S0043-1648(01)00607-X
Yavari, A.R., Botta Filho, W.J., Rodrigues, C.A.D., Greer, A.L., Uriarte, J.L., Huenen, G., Vaughan, G., Inoue, A.: FeNiB-based metallic glasses with fcc crystallisation products. J. Non-Cryst. Solids 304, 44–50 (2002). doi:10.1016/S0022-3093(02)01002-5
Calin, M., Eckert, J., Schultz, L.: Improved mechanical behavior of Cu-Ti-based bulk metallic glass by in situ formation of nanoscale precipitates. Scr. Mater. 48, 653–658 (2003). doi:10.1016/S1359-6462(02)00560-2
Gloriant, T.: Microhardness and abrasive wear resistance of metallic glasses and nanostructured composite materials. J. Non-Cryst. Solids 316, 96–103 (2003). doi:10.1016/S0022-3093(02)01941-5
Yokoyama, Y., Yamano, K., Fukaura, K., Sunada, H., Inoue, A.: Nanocrystalline Zr-based bulk glassy alloys with high flexural strength. Mater. Trans. 40, 1015–1018 (1999)
Venkataraman, S., Stoica, M., Scudino, S., Gemming, T., Mickel, C., Kunz, U., Kim, K.B., Schultz, L., Eckert, J.: Revisiting the Cu47Ti33Zr11Ni8Si1 glass-forming alloy. Scr. Mater. 54, 835–840 (2006). doi:10.1016/j.scriptamat.2005.11.007
Fleury, E., Lee, S.M., Ahn, H.S., Kim, W.T., Kim, D.H.: Tribological properties of bulk metallic glasses. Mater. Sci. Eng. A 375–377, 276–279 (2004). doi:10.1016/j.msea.2003.10.065
Lim, S.C., Ashby, M.F.: Wear mechanism maps. Acta Metall. 35(1), 1–24 (1987). doi:10.1016/0001-6160(87)90209-4
Bossuyt, S.: Micostructure and crystallization behavior in bulk glass forming alloys, PH.D. Thesis, California Institute of Technology (2001)
Aydiner, C.C., Ustundag, E., Prime, M.B., Peker, A.: Modeling and measurement of residual stresses in a bulk metallic glass plate. J. Non-Cryst. Solids 316, 82–95 (2003). doi:10.1016/S0022-3093(02)01940-3
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The works was supported by National Natural Science Foundation of China (project number: 50575106), Natural Science Foundation of Jiangsu Province of China (BK2006206) and (kjsmcx06002), and Young Scholar Foundation of Nanjing University of Science and Technology (project number: AB41325).
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Kong, J., Xiong, D., Li, J. et al. Effect of Flash Temperature on Tribological Properties of Bulk Metallic Glasses. Tribol Lett 35, 151–158 (2009). https://doi.org/10.1007/s11249-009-9444-4
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DOI: https://doi.org/10.1007/s11249-009-9444-4