Skip to main content
SpringerLink
Log in

CoxPy Catalysts in HDO of Phenol and Dibenzofuran: Effect of P content

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

Cobalt phosphide catalysts supporting on SiO2 presenting different CoxPy stoichiometry were proved in hydrodeoxygenation (HDO) of two different model molecules present in biomass derived bio-oil such as phenol (Ph) and dibenzofuran (DBF). To investigate composition effects a series of cobalt phosphide catalysts presenting different initial P/Co atomic ratio were prepared. The catalysts were characterized by a range of techniques (N2 physisorption, XRD, TEM, NH3-TPD and XPS) and tested for DBF and Ph HDO activity and selectivity. Characterization results evidenced good textural properties, high dispersion of the active phase, as well as the presence of acid sites after P and Co incorporation. The highest activity was observed for catalysts containing an intermediate P/Co content were the CoP phase was the predominat one. Those catalyst containing Co2P or CoP2 phases were less active in these reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Scheme 1
Fig. 8
Fig. 9
Fig. 10
Scheme 2
Scheme 3

Similar content being viewed by others

References

  1. Lewis NS (2007) MRS Bull 32:808–820

    Article  Google Scholar 

  2. Lewis NS, Nocera DG (2007) PNAS 103:15729–15735

    Article  Google Scholar 

  3. Alonso DM, Bond JQ, Dumesic JA (2010) Green Chem 12:1493

    Article  CAS  Google Scholar 

  4. Venkatakrishnan VK, Delgass WN, Ribeiro FH, Agrawal R (2015) Green Chem 17:178–183

    Article  CAS  Google Scholar 

  5. Mohan D, Pittman CU Jr, Steele PH (2006) Energy Fuels 20:848–889

    Article  CAS  Google Scholar 

  6. Quan Bu HL, Zacher AH, Wang L, Ren S, Liang J, Wei Y, Liu Y, Tang J, Zhang Q, Ruan R (2012) Bioresour Technol 124:470–477

    Article  Google Scholar 

  7. Furimsky E (2000) Appl Catal A 199:147–190

    Article  CAS  Google Scholar 

  8. Huber GW, Iborra S, Corma A (2006) Chem Rev 106:4044–4098

    Article  CAS  Google Scholar 

  9. De S, Saha B, Luque R (2015) Bioresour Technol 178:108–118

    Article  CAS  Google Scholar 

  10. Romero Y, Richard F, Brunet S (2010) Appl Catal B 98:213–223

    Article  CAS  Google Scholar 

  11. Ryymin E-M, Honkela ML, Viljava T-R, Krause AOI (2009) Appl Catal A 358:42–48

    Article  CAS  Google Scholar 

  12. Honkela ML, Viljava T-R, Gutierrez A, Krause AOI (2010) R Soc Chem 11:288–306

    Google Scholar 

  13. Li N, Huber GW (2010) J Catal 270:48–59

    Article  CAS  Google Scholar 

  14. Wildschut J, Mahfud FH, Venderbosch RH, Heeres HJ (2009) Ind Eng Chem Res 48:10324–10334

    Article  CAS  Google Scholar 

  15. Ruddy DA, Schaidle JA, Ferrell III JR, Wang J, Moens L, Hensley JE (2014) Green Chem 16:454–490

    Article  CAS  Google Scholar 

  16. Bui P, Cecilia JA, Oyama ST, Takagaki A, Infantes-Molina A, Zhao H, Li D, Rodríguez-Castellón E, López AJ (2012) J Catal 294:184–198

    Article  CAS  Google Scholar 

  17. Whiffen VML, Smith KJ, Straus SK (2012) Appl Catal A 419–420:111–125

    Article  Google Scholar 

  18. Oyama ST, Gott T, Zhao H, Lee Y-K (2009) Catal Today 143:94–107

    Article  CAS  Google Scholar 

  19. Zhao HY, Li D, Bui P, Oyama ST (2011) Appl Catal A 391:305–310

    Article  CAS  Google Scholar 

  20. Infantes-Molina A, Gralberg EE, Cecilia JA, Finocchiob E, Rodríguez-Castellón E (2015) Catal Sci Technol 5:3403–3415

    Article  CAS  Google Scholar 

  21. Berenguer A, Sankaranarayanan TM, Gómez G, Moreno I, Coronado JM, Pizarro P, Serrano DP (2016) Green Chem 18:1938–1951

    Article  CAS  Google Scholar 

  22. Cecilia JA, Infantes-Molina A, Rodríguez-Castellón E, Jiménez-López A, Oyama ST (2013) Appl Catal B 136–137:140–149

    Article  Google Scholar 

  23. Cecilia JA, Infantes-Molina A, Rodriguez-Castellon E, Jimenez-Lopez A (2013) J Hazard Mater 260:167–175

    Article  CAS  Google Scholar 

  24. Cecilia JA, Infantes-Molina A, Rodríguez-Castellón E, Jiménez-López A (2009) Appl Catal B 92:100–113

    Article  CAS  Google Scholar 

  25. Burns AW, Layman KA, Bale DH, Bussell ME (2008) Appl Catal A 343:68–76

    Article  CAS  Google Scholar 

  26. Cecilia JA, Infantes-Molina A, Rodríguez-Castellón E, Jiménez-López A (2009) J Phys Chem B 113:17032–17044

    CAS  Google Scholar 

  27. Abu II, Smith KJ (2007) Appl Catal A 328:58–67

    Article  CAS  Google Scholar 

  28. Iino A, Cho A, Takagaki A, Kikuchi R, Oyama ST (2014). J Catal 311:17–27

    Article  CAS  Google Scholar 

  29. Mortensen PM, Grunwaldt JD, Jensen PA, Knudsen KG, Jensen AD (2011) Appl Catal A 407:1–19

    Article  CAS  Google Scholar 

  30. Cecilia JA, Infantes-Molina A, Rodriguez-Castellon E (2015) J Hazard Mater 296:112–119

    Article  CAS  Google Scholar 

  31. Kim S-S, Lee HW, Ryoo R, Kim W, Park SH, Jeon J-K, Park Y-K (2014) J Nanosci Nanotechnol 14:2414–2418

    Article  CAS  Google Scholar 

  32. Wang L, Li C, Jin S, Li W, Liang C (2014) Catal Lett 144:809–816

    Article  CAS  Google Scholar 

  33. Lee HW, Jun BR, Kim H, Kim DH, Jeon J-K, Park SH, Ko CH, Kim T-W, Park Y-K (2015) Energy 81:33–40

    Article  CAS  Google Scholar 

  34. Wang Y, Fang Y, He T, Hu H, Wu J (2011) Catal Commun 12:1201–1205

    Article  CAS  Google Scholar 

  35. Infantes-Molina A, Moretti E, Segovia E, Lenarda A, Rodríguez-Castellón E (2016) Catal Today 277:143–151

    Article  CAS  Google Scholar 

  36. Wang L, Wan H, Jin S, Chen X, Li C, Liang C (2015) Catal Sci Technol 5:465–474

    Article  CAS  Google Scholar 

  37. Rana MS, Srinivas BN, Maity SK, Dhar GM, Rao TP (2000) J Catal 195:31–37

    Article  CAS  Google Scholar 

  38. Xinghua Z, Tiejun W, Longlong M, Chuangzhi W (2010) Fuel 89:2697–2702

    Article  Google Scholar 

  39. Massoth F, Politzer P, Concha M, Murray J, Jakowski J, Simons J (2006) J Phys Chem B 110:14283–14291

    Article  CAS  Google Scholar 

  40. Resasco DE (2011) J Phys Chem Lett 2:2294–2295

    Article  CAS  Google Scholar 

  41. Romero Y, Richard F, Renème Y, Brunet S (2009) Appl Catal A 353:46–53

    Article  CAS  Google Scholar 

  42. Echeandia S, Pawelec B, Barrio VL, Arias PL, Cambra JF, Loricera CV, Fierro JLG (2014) Fuel 117:1061–1073

    Article  CAS  Google Scholar 

  43. Kung HH (1989) Stud Surf Sci Catal 45:53–71

    Article  CAS  Google Scholar 

  44. Idriss H, Barteau MA (2000) Adv Catal 45:261–331

    CAS  Google Scholar 

  45. Popov A, Kondratieva E, Gilson J-P, Mariey L, Travert A, Maugé F (2011) Catal Today 172:132–135

    Article  CAS  Google Scholar 

  46. Liu H, Jiang T, Han B, Liang S, Zhou Y (2009) Science 326:1250–1252

    Article  CAS  Google Scholar 

  47. Rensel DJ, Kim J, Bonita Y, Hicks JC (2016) Appl Catal A 524:85–93

    Article  CAS  Google Scholar 

  48. Mortensen PM, Grunwaldt J-D, Jensen PA, Jensen AD (2013) ACS Catal 3:1774–1785

    Article  CAS  Google Scholar 

  49. Yang Y, Gilbert A, Xu C (2009) Appl Catal A 360:242–249

    Article  CAS  Google Scholar 

  50. Boullosa-Eiras S, Lødeng R, Bergem H, Stöcker M, Hannevold L, Blekkan EA (2014) Catal Today 223:44–53

    Article  CAS  Google Scholar 

  51. Echeandia S, Arias PL, Barrio VL, Pawelec B, J.L.G. Fierro (2010) Appl Catal B 101:1–12

    Article  CAS  Google Scholar 

  52. Infantes-Molina A, Pawelec B, J.L.G. Fierro, Loricera CV, Jiménez-López A, Rodríguez-Castellón E (2015) Top Catal 58:247–257

    Article  CAS  Google Scholar 

  53. Cecilia JA, Infantes-Molina A, Sanmartín-Donoso J, Rodríguez-Aguado E, Ballesteros-Plata D, Rodríguez-Castellón E (2016) Catal Sci Technol 6:7323–7333

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the projects CTQ2015-68951-C3-3R (Ministerio de Economía y Competitividad, Spain and FEDER Funds) and P12-RNM-1565 (Junta de Andalucía, Spain). A.I.M. thanks the Ministry of Economy and Competitiveness for a Ramón y Cajal contract (RyC2015-17870).

Author information

Authors and Affiliations

  1. Departamento de Química Inorgánica, Cristalografía y Mineralogía (Unidad Asociada al ICP-CSIC), Facultad de Ciencias, Universidad de Málaga, Campus de Teatinos, 29071, Málaga, Spain

    E. Rodríguez-Aguado, A. Infantes-Molina, J. A. Cecilia, D. Ballesteros-Plata, R. López-Olmo & E. Rodríguez-Castellón

Authors
  1. E. Rodríguez-Aguado
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Infantes-Molina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. A. Cecilia
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. Ballesteros-Plata
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. López-Olmo
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. Rodríguez-Castellón
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to A. Infantes-Molina or E. Rodríguez-Castellón.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 186 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rodríguez-Aguado, E., Infantes-Molina, A., Cecilia, J.A. et al. CoxPy Catalysts in HDO of Phenol and Dibenzofuran: Effect of P content. Top Catal 60, 1094–1107 (2017). https://doi.org/10.1007/s11244-017-0791-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-017-0791-3

Keywords

Search

Navigation