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Kinetics and Active Surfaces for CO Oxidation on Pt-Group Metals Under Oxygen Rich Conditions

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Abstract

This mini review summaries recent works on identifying the active surfaces for CO oxidation on Pd, Pt, and Rh under oxygen rich conditions. A significantly high reaction rate for CO oxidation under oxygen rich conditions has been observed. Results using in situ characterization methods of ambient scanning tunneling microscope, surface X-ray diffraction, ambient pressure X-ray photoemission spectroscopy, X-ray absorption spectroscopy, and infrared reflection adsorption spectroscopy (IRAS), were included. Most X-ray related methods reveal that the achievements of the high reaction rates for CO oxidation on Pd, Pt, and Rh under oxygen rich conditions are accompanied with the appearance of oxides on the surface, leading to that the oxide phase is considered to be the active surface. In contrast, recent in situ IRAS results conclude that a chemisorbed oxygen covered metallic surface is the active surface. Kinetic data support that the reaction on the metallic surfaces can reach the high rate, e.g. a mass-transfer limit turnover frequency, without the necessity of the presence of oxide. Therefore, we point out that the appearance of oxides on Pt-group metals during CO oxidation is possibly due to the transfer-limit of CO gas, resulting in exposing the catalyst surface to an ambient atmosphere much richer in oxygen and thus building-up the oxide. Moreover, photons in X-ray related experiments may aid to overcome the formation barrier of oxide on a chemisorbed oxygen covered metallic surface. The formation of oxide is also affected by the mass-transfer properties of the in situ reaction cells. If the amount of incoming CO molecules under the mass-transfer limit of CO is high enough, the build-up of oxide may be precluded being consumed by reacting with CO.

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Acknowledgments

We gratefully acknowledge the support of this work by the National Basic Research Program of China (973 Program: 2010CB732303, 2013CB933102), the Major Project of Chinese Ministry of Education (No. 309019), the National Natural Science Foundation of China (20923004, 21033006, 21073149, 21273178), the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT1036), and the PhD Programs Foundation of Chinese Ministry of Education (No. 20110121110010).

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  1. State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, Fujian, China

    Mingshu Chen, Yanping Zheng & Huilin Wan

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  1. Mingshu Chen
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  2. Yanping Zheng
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  3. Huilin Wan
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Correspondence to Mingshu Chen.

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Chen, M., Zheng, Y. & Wan, H. Kinetics and Active Surfaces for CO Oxidation on Pt-Group Metals Under Oxygen Rich Conditions. Top Catal 56, 1299–1313 (2013). https://doi.org/10.1007/s11244-013-0140-0

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  • DOI: https://doi.org/10.1007/s11244-013-0140-0

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