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Determination of Polycarbonyl Species on Nickel-Containing Catalysts by Adsorption of CO Isotopic Mixtures

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Abstract

The possibilities to identify polycarbonyl species using different CO isotopic mixtures (12C16O + 13C16O and 12C16O + 13C18O) are regarded. The examples concern two nickel-containing catalysts, Ni–ZSM-5 and Ni/SiO2. Ni+ ions, present in Ni–ZSM-5 reduced by CO, can coordinate up to three CO molecules each. Ni+(CO)2 dicarbonyl structures are well established by both, 12C16O + 13C16O and 12C16O + 13C18O isotopic mixtures. However, the 12C16O + 13C18O mixture is advantageous in the determination of tricarbonyl structures. This is due to the much higher 12C16O → 13C18O isotopic shift (about 100 cm−1) as compared to the 12C16O → 13C16O shift (ca. 50 cm−1) which allows a better resolution of the different carbonyl bands. The use of 12C16O + 13C18O mixtures also permits assignment of the bands due to polycarbonyl structures when CO is adsorbed on a reduced Ni/SiO2 catalyst.

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Acknowledgments

This work was supported by the Bulgarian National Scientific Foundation (Grant 02-290/2008).

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia, 1113, Bulgaria

    M. Mihaylov, O. Lagunov, E. Ivanova & K. Hadjiivanov

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  1. M. Mihaylov
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  2. O. Lagunov
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  3. E. Ivanova
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  4. K. Hadjiivanov
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Correspondence to K. Hadjiivanov.

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Mihaylov, M., Lagunov, O., Ivanova, E. et al. Determination of Polycarbonyl Species on Nickel-Containing Catalysts by Adsorption of CO Isotopic Mixtures. Top Catal 54, 308–317 (2011). https://doi.org/10.1007/s11244-011-9661-6

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  • DOI: https://doi.org/10.1007/s11244-011-9661-6

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