Abstract
Cu2O thin films were electrodeposited on n-Si (100) and p-Si (111) substrates, and characterized by X-ray diffraction, atomic force microscopy, transmission electron microscopy and optical reflectance measurements. The results showed Cu2O deposits with low surface roughness that increase continuously with the thickness. The grains are columnar with cone-shape and texture that follows the orientation of the substrate. The optical gap and the refraction index were also dependent on the texture of the layers.
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Nagase K, Zheng Y, Kodama Y, Kakuta J (1999) J Catal 187:123
Wang JB, Tsai DH, Huang TJ (2002) J Catal 208:370
White B, Yin M, Hall A, Le D, Stolbov S, Rahman T, Turro N, O’Brien S (2006) Nano Lett 6:2095
Chang TY, Liang RM, Wu PW, Chen JY, Hsieh YC (2009) Mater Lett 63:1001
Hara M, Kondo T, Komoda M, Ikeda S, Shinohara K, Tanaka A, Kondo JN, Domen K (1998) Chem Commun 3:357
Delatorre RG, Stenger V, Zoldan VC, da Silva DL, dos Santos SG, Viegas ADC, Pasa AA (2009) ECS Trans 23:77
Switzer JA, Liu R, Bohannan EW, Ernst F (2002) J Phys Chem 106:12369
Sun BZ, Chen WK, Xu YJ (2009) J Chem Phys 131:174503
Wyckoff RWG (1963) Crystal Structures, 2nd edn. Interscience Publishers, New York
Cisneros JI (1998) Appl Opt 37:5262
Mahalingam T, Chitra JSP, Rajendran S, Sebastian PJ (2002) Semicond Sci Technol 17:565
Papadimitropoulos G, Vourdas N, Vamvakas VE, Davazoglou D (2006) Thin Solid Films 515:2428
Rakhshani AE (1987) J Appl Phys 62:1528
Murphy AB (2007) Sol Energy Mater Sol Cells 91:1326
Khan SUM, Al-Shahry M, Ingler WB Jr (2002) Science 297:2243
Acknowledgments
The authors wish to acknowledge the Brazilian agencies CAPES (PRODOC and Pro-equipamentos), CNPQ, CNPQ/NAMITEC, FINEP/CT-INFRA, and FAPESC that supported this research and the measurements at labs LCME (TEM) and LDRX (XRD).
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Brandt, I.S., Stenger, V., Zoldan, V.C. et al. Surface Roughness and Structure of Electrodeposited Cu2O Layers on Si Substrates. Top Catal 54, 97–100 (2011). https://doi.org/10.1007/s11244-011-9629-6
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DOI: https://doi.org/10.1007/s11244-011-9629-6