Skip to main content
SpringerLink
Log in

Homogeneous versus heterogeneous catalytic reactions to eliminate organics from waste water using H2O2

  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Homogeneous (Cu2+ ions) and heterogeneous (Cu2+-pillared clay) Fenton-like catalysts have been compared in the conversion of p-coumaric acid. The performances of the two classes of catalysts are similar for an analogous amount of copper, but there are some relevant differences in terms of (i) the presence of an induction time, (ii) the turnover frequency, (iii) the efficiency in the use of H2O2, (iv) the initial attack of p-coumaric acid (hydroxylation on the aromatic ring or oxidative attack on the double bond of the lateral chain), and (v) the effect of dissolved oxygen on the removal of total organic carbon (TOC). These differences were interpreted in terms of reaction network of generation of radical oxygen species and of organics conversion. The possible formation of a surface peroxo adduct coordinated to a copper binulcear site was also evidenced for the solid heterogeneous catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Centi and S. Perathoner, in Catalysis (J.J. Spivey Ed., Royal Society of Chemistry Pub.: Cambridge U.K.), 18 (2005) 46

  2. G. Centi and S. Perathoner, La Chimica e L’Industria (Milan), 83 (2001) 43

  3. S. Perathoner G. Centi (2005) Top. Catal. 33 207 Occurrence Handle10.1007/s11244-005-2529-x Occurrence Handle1:CAS:528:DC%2BD2MXjvV2msL8%3D

    Article  CAS  Google Scholar 

  4. R-C. Yang M-J. Shu S-T. Zhou (1998) J. Environ. Sci. (China) 10 176 Occurrence Handle1:CAS:528:DyaK1cXjslSmtr8%3D

    CAS  Google Scholar 

  5. H. Maurer G. Bach J. Schneider (2003) Wasser, Luft und Boden 47 32 Occurrence Handle1:CAS:528:DC%2BD3sXjt1eisLY%3D

    CAS  Google Scholar 

  6. J.R. Bolton J.E. Valladares J.P. Zanin W.J. Cooper M.G. Nickelsen D.C. Kajdi T.D. Waite C.N. Kurucz (1998) J. Adv. Oxid. Techn. 3 174 Occurrence Handle1:CAS:528:DyaK1cXmsFaks7c%3D

    CAS  Google Scholar 

  7. S. Abate G. Centi S. Melada S. Perathoner F. Pinna G. Strukul (2005) Catal. Today 104 323 Occurrence Handle10.1016/j.cattod.2005.03.054 Occurrence Handle1:CAS:528:DC%2BD2MXltFGhs7c%3D

    Article  CAS  Google Scholar 

  8. S. Melada F. Pinna G. Strukul S. Perathoner G. Centi (2005) J. Catal. 235 241 Occurrence Handle10.1016/j.jcat.2005.07.024 Occurrence Handle1:CAS:528:DC%2BD2MXhtVSqsLnN

    Article  CAS  Google Scholar 

  9. G. Centi S. Perathoner T. Torre M.G. Verduna (2000) Catal. Today 55 61 Occurrence Handle10.1016/S0920-5861(99)00226-6 Occurrence Handle1:CAS:528:DyaK1MXnvVWisLY%3D

    Article  CAS  Google Scholar 

  10. G. Centi S. Perathoner G. Romeo (2001) Stud. Surf. Sci. Catal. 135 5156 Occurrence Handle1:CAS:528:DC%2BD3MXnslCmsbs%3D

    CAS  Google Scholar 

  11. (a) K. Fajerwerg and H. Debellefontaine, Appl. Catal. B: Env., 10 (1996) L229. (b) K. Fajerwerg, J.N. Foussard, A. Perrard and H. Debellefontaine, Water Sci. Technol., 35 (1997) 103

  12. F. Larachi S. Levesque A. Sayari (1998) J. Chem. Technol. Biotechnol. 73 127 Occurrence Handle10.1002/(SICI)1097-4660(1998100)73:2<127::AID-JCTB941>3.0.CO;2-T Occurrence Handle1:CAS:528:DyaK1MXltFahtg%3D%3D

    Article  CAS  Google Scholar 

  13. N. Frini M. Crespin M. Trabelsi D. Messad H. Damme ParticleVan F. Bergaya (1997) Appl. Clay. Sci. 12 281 Occurrence Handle10.1016/S0169-1317(97)00016-1 Occurrence Handle1:CAS:528:DyaK2sXltVymsbo%3D

    Article  CAS  Google Scholar 

  14. J. Barrault C. Bouchoule K. Echachoui N. Frini-Srasra M. Trabelsi F Bergaya (1998) Appl. Catal B: Env. 15 L269 Occurrence Handle10.1016/S0926-3373(97)00054-4

    Article  Google Scholar 

  15. (a) J. Barrault, M. Abdellaoui, C. Bouchoule, A. Majeste, J.M. Tatibouet, A. Louloudi, N. Papayannakos and N.H. Gangas, Appl. Catal. B: Env., 27 (2000) L225. (b) E. Guélou, J. Barrault, J. Fournier and J.-M. Tatibouët, Appl. Catal. B: Env., 44 (2003) 1. (c) J-M. Tatibouët, E. Guélou and J. Fournier, Top. Catal., 33 ( 2005) 225

  16. E.V. Kuznetsova E.N. Savinov L.A. Vostrikova V.N. Parmon (2004) Appl. Catal. B: Env. 51 165 Occurrence Handle10.1016/j.apcatb.2004.03.002 Occurrence Handle1:CAS:528:DC%2BD2cXks1Cisrs%3D

    Article  CAS  Google Scholar 

  17. (a) C. Catrinescu, C. Teodosiu, M. Macoveanu, J. Miehe-Brendlé and R. Le Dred, Water Res. 37 (2003) 1154. (b) M. Neamtu, C. Zaharia, C. Catrinescu, A. Yediler, M. Macoveanu and A. Kettrup, Appl. Catal. B: Env. 48 (2004) 287. (c) M. Neamtu, C. Catrinescu and A. Kettrup, Appl. Catal. B: Env. 51 (2004) 149

  18. J. Guo M. Al-Dahhan (2003) Ind. Eng. Chem. Res. 42 2450 Occurrence Handle10.1021/ie020344t Occurrence Handle1:CAS:528:DC%2BD3sXhtlSrs7g%3D

    Article  CAS  Google Scholar 

  19. R. Lloyd P.M. Hanna R.P. Mason (1997) Free Rad. Biol. Med. 22 885 Occurrence Handle10.1016/S0891-5849(96)00432-7 Occurrence Handle1:CAS:528:DyaK2sXos1ymtg%3D%3D

    Article  CAS  Google Scholar 

  20. H. Gallard J. Laat ParticleDe B. Legube (1999) Rev. Sc. l’Eau. 12 713 Occurrence Handle1:CAS:528:DC%2BD3cXmtVOrtrc%3D

    CAS  Google Scholar 

  21. N. K. Urbañski A. Berêsewicz (2000) Acta Biochim. Polonica 47 951

    Google Scholar 

  22. (a) B. Ensing, F. Buda, P.E. Blöchl and E.J. Baerends, Angew. Chem. Int. Ed., 40 (2001) 2893. (b) B. Ensing, F. Buda, P.E. Blöchl and E.J. Baerends, J. Phys. Chem. Chem. Phys., 4 (2002) 3619. (c) B. Ensing, F. Buda and E.J. Baerends, J. Phys. Chem. A, 107 (2003) 5722

  23. F. Haber J. Weiss (1934) J. Proc. R. Soc. London 147 332 Occurrence Handle10.1098/rspa.1934.0221 Occurrence Handle1:CAS:528:DyaA2MXnvVSq

    Article  CAS  Google Scholar 

  24. W.C. Bray M.H. Gorin (1932) J. Am. Chem. Soc. 54 2124 Occurrence Handle10.1021/ja01344a505 Occurrence Handle1:CAS:528:DyaA38Xjtlaquw%3D%3D

    Article  CAS  Google Scholar 

  25. (a) G. Centi, G. Giordano, P. Fejes, A. Katovic, K. Lazar, I. Marsi, J.B. Nagy, S. Perathoner and F. Pino, Stud. Surf. Sci. Catal., 154 (2004) 2566. (b) G. Centi, S. Perathoner, F. Pino, R. Arrigo, G. Giordano, A. Katovic and V. Pedulà, Catal. Today, 110 (2005) 211

  26. S. Caudo, G. Centi, C. Genovese and S. Perathoner, Appl. Catal. B: Env., (2005) accepted

  27. J. Bandara V. Nadtochenko J. Kiwi C. Pulgarin (1997) Water Sci. Technol. 35 87 Occurrence Handle10.1016/S0273-1223(97)00013-9 Occurrence Handle1:CAS:528:DyaK2sXitFyktbc%3D

    Article  CAS  Google Scholar 

  28. B. Ensing, PhD Thesis (Chemistry in Water. First Principles Computer Simulations), Vrije Univ. Amsterdam, The Netherlands (2003)

  29. Y-J. Zhagn Y-X. Gao Y. Zhang M. Yang D-S. Wang C-F. Du (2005) Huanjing Huaxue 24 361 Occurrence Handle1:CAS:528:DC%2BD2MXnvVajurg%3D

    CAS  Google Scholar 

  30. G.R. Rao B.G. Mishra (2005) Mater. Chem. Phys. 89 110 Occurrence Handle10.1016/j.matchemphys.2004.08.037 Occurrence Handle1:CAS:528:DC%2BD2cXovVCkurY%3D

    Article  CAS  Google Scholar 

  31. S.A. Yashnik Z.R. Ismagilov V.F. Anufrienko (2005) Catal. Today 110 310 Occurrence Handle10.1016/j.cattod.2005.09.029 Occurrence Handle1:CAS:528:DC%2BD2MXht1Cqu7nN

    Article  CAS  Google Scholar 

  32. C. Lorain, G. Guyot and M. Bolte, J. Chimie Phys. et de Physico-Chimie Biol., 81 (1984) (4) 243.

  33. A. Karaliota O. Kretsi C. Tzougraki (2001) J. Inorg. Biochem. 84 33 Occurrence Handle10.1016/S0162-0134(00)00214-2 Occurrence Handle1:CAS:528:DC%2BD3MXisValsLc%3D

    Article  CAS  Google Scholar 

  34. S. Fox A. Nanthakumar N. Wei N.N. Murthy K.D. Karlin (1993) Pure Appl. Chem. 65 2235

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Industrial Chemistry and Engineering of Materials, University of Messina and ELCASS (European Laboratory for Catalysis and Surface Science), Salita Sperone 31, 98166, Messina, Italy

    Simona Caudo, Gabriele Centi, Chiara Genovese & Siglinda Perathoner

Authors
  1. Simona Caudo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Gabriele Centi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chiara Genovese
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Siglinda Perathoner
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Gabriele Centi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Caudo, S., Centi, G., Genovese, C. et al. Homogeneous versus heterogeneous catalytic reactions to eliminate organics from waste water using H2O2 . Top Catal 40, 207–219 (2006). https://doi.org/10.1007/s11244-006-0122-6

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-006-0122-6

Keywords

Search

Navigation