Abstract
Gas-to-liquids (GTL) is a viable pathway to synthesize clean fuels from natural gas. The continuing technological advances in natural gas conversion technology have led several companies to make investment in the Fischer–Tropsch (F–T) route to synthesize clean hydrocarbon fuels. But, a highly efficient gas conversion process to capitalize on remote natural gas fields still remains elusive. Heterogeneous catalyst assemblies are typically utilized in the GTL conversion reactions but an in-depth characterization of catalytic materials is needed to design the next-generation more efficient catalysts. Computed microtomography (CMT) and micro-X-ray fluorescence (μXRF), techniques at the National Synchrotron Light Source (NSLS), Brookhaven National Laboratory (BNL), are complementary methods that allow mapping of catalyst constituents. We describe here the experimental apparatus and give examples of utilization of these techniques in catalyst characterization in different processes. The potential of using CMT and μXRF techniques for monitoring changes in the catalyst composition during F–T synthesis are discussed and an example based on the use of X-ray fluorescence imaging is presented.
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Dry M.E. In: Catalysis, Science and Technology, Anderson J.R., M.␣Boudart (eds), (Springer Verlag, Berlin, 1981), p.159, and references therein.
P.J. Flory (1936) J. Am. Chem. Soc. 58 1877
R.A. Friedel R.B. Anderson (1950) J. Am. Chem. Soc. 72 1211
R.L. Espinoza A.P. Steynberg B. Jager A.C. Voslo (1999) Appl. Catal. A: General 186 13
E. Iglesia S.C. Reyes R.J. Madon S.L. Soled (1993) Adv. Catal. 39 32
D.B Burkur M. Koranne X. Lang K.R.P.M. Rao G.P. Huffman (1995) Appl. Catal. A. 126 IssueID1 85
Shroff M.D., Kalakkad D.S., Coulter K.E., K S.D.öhler, M.S.␣Harrington, Jackson N.B., Sault A.G. and Datye A.K., J. Catal. 156 (1995) 185. Datye A.K., Presented at the DOE Coal Liquefaction and Solid Fuels Contractors’ Review Conference, Pittsburgh, PA. Sept. 3–4, 1997.
D.B. Bukur X. Lang Y. Ding (1997) J. Am. Chem. Soc., Div. Fuel Chem. 42 IssueID2 623
Y. Jin A.K. Datye (1998) Electron Microscopy II 379
Xu L., Bao S., O’Brien R.J., Raje A., Davis B.H., CHEMTECH (1998) 47.
L.D. Mansker Y. Jin D.B. Bukur A.K. Datye (1999) Appl. Catal A: General 186 IssueID1 277
H. Itoh S. Nagano E. Kikuchi (1991) Appl. Catal. 67 215
Mahajan D., Kobayashi A., Gupta N. J. Chem. Soc., Chem. Commun. (1994) 795.
E. Kikuchi R. Sorita H. Takahashi T. Matsuda (1999) Appl. Catal. A: General 186 121
D. Mahajan P. Gütlich U. Stumm (2003) Catal. Commun. 4 101
D. Mahajan P. Gütlich J. Ensling K. Pandya U. Stumm P. Vijayaraghavan (2003) Energ. Fuel. 17 1210
Dowd B.A., Andrews A.B., Marr R.B., Siddons D.P., Jones K.W., Peskin A.M., in: Advances in X-Ray Analysis, (Plenum Publishing Corp., New York, 1999) and references therein.
Hazlett R.D., M. E. Coles, Jones K.W., B. Andrews, B. Dowd, D. P. Siddons and A. Peskin, Presented at the 1996 Annual Technical Conference of the Society of Core Analysts (SCA), Montpellier, France September, 1996; Paper No. SCA-96.
W.C. Conner S.W. Webb P. Spanne K.W. Jones (1990) Macromolecules 23 4742
K.W. Jones P. Spanne S.W. Webb W.C. Conner R.A. Beyerlein W.J. Reagan F.M. Dautzenberg (1991) Nucl Instrum Methods B 56/57 427
M.A. Ferrero R. Sommer P. Spanne K.W. Jones W.C. Conner (1993) J. Polym. Sci.: Part A: Polymer Chemistry 31 2507
K.W. Jones W.J. Berry D.J. Borsay H.T. Cline W.C. Conner SuffixJr. C.S. Fullmer (1997) X-Ray Spectrom. 26 350
Beyerlein R.A., Reagan W.J., Zajac G.W., Hall J.B., Huggins B.J., C. Chin, Jones K.W. and P. Spanne. Presented at the Chicago Catalysis Club Spring Meeting, Chicago, Illinois, May 1990.
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Jonesa, K.W., Fengb, H., Lanzirottic, A. et al. Mapping metal catalysts using synchrotron computed microtomography (CMT) and micro-X-ray fluorescence (μXRF). Top Catal 32, 263–272 (2005). https://doi.org/10.1007/s11244-005-2908-3
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DOI: https://doi.org/10.1007/s11244-005-2908-3