Skip to main content
SpringerLink
Log in

Manganese(II) complexes of 5-(4-pyridyl), 5-phenyl and 5-(4-methoxy-phenyl)-1,3,4-oxadiazole-2-thione containing 2, 2′-bipyridyl/ethylenediamine: synthesis, spectral, and X-ray characterization

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Three new mixed ligand complexes [Mn(4-pytone)2(bipy)2]bipy (1), [Mn(pot)2(en)2] (2) and [Mn(4-mot)2(en)2] (3) (4-pytone = 5-(4-pyridyl)-1,3,4-oxadiazole-2-thione, pot = 5-phenyl-1,3,4-oxadiazole-2-thione, 4-mot = 5-(4-methoxy-phenyl)-1,3,4-oxadiazole-2-thione) have been prepared containing bipy/en as coligands. The starting material potassium N-(aryl-carbonyl)-hydrazinecarbodithioates (RCONHNHCSSK) underwent cyclization during complexation in the presence of bipy or en to give the corresponding 5-aryl-1,3,4-oxadiazole-2-thiones. The complexes have been characterized by physicochemical techniques and single crystal X-ray structure determination. In all cases, the manganese has a six coordinate octahedral arrangement coordinated by 4N atoms of two bipy/en and two covalently bonded N atoms of the oxadiazole-2-thione anions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Wieghardt K (1989) Angew Chem Int Ed 28:1153. doi:10.1002/anie.198911531

    Article  Google Scholar 

  2. Greenwood NN, Earnshaw A (1997) Chemistry of the Elements, 2nd edn. Reed educational and Professional, Oxford

    Google Scholar 

  3. Jakubkiene V, Burbuliene MM, Mekuskiene G, Udrenaite E, Gaidelis P, Vainilavicius P (2003) Il Farmaco 58:323. doi:10.1016/S0014-827X(02)00022-8

    Article  CAS  Google Scholar 

  4. Tripathi P, Pal A, Jancik V, Pandey AK, Singh J, Singh NK (2007) Polyhedron 26:2597. doi:10.1016/J.poly.2006.12.046

    Article  CAS  Google Scholar 

  5. Singh NK, Bharty MK, Dulare R, Butcher RJ (2009) Polyhedron 28:2443. doi:10.1016/J.poly.2009.04.030

    Article  CAS  Google Scholar 

  6. Singh M, Butcher RJ, Singh NK (2008) Polyhedron 27:3151. doi:10.1016/J.poly.2008.08.007

    Article  CAS  Google Scholar 

  7. Amin OH, Al-Hayaly LJ, Al-Jibori SA, Al-Allaf TAK (2004) Polyhedron 23:2013. doi:10.1016/J.poly.2004.05.006

    Article  CAS  Google Scholar 

  8. Zhang ZH, Tian YL, Guo YM (2007) Inorg Chim Acta 360:2783. doi:10.1016/J.ica.2006.11.020

    Article  CAS  Google Scholar 

  9. Zhang ZH, Li CP, Tang GM, Tian YL, Guo YM (2008) Inorg Chem Commun 11:326. doi:10.1016/J.poly.2006.09.008

    Article  Google Scholar 

  10. Wang YT, Tang GM (2007) Inorg Chem Commun 10:53. doi:10.1016/Jinoche.2006.09.010

    Article  Google Scholar 

  11. Du M, Zhang ZH, Zhao XJ, Xu Q (2006) Inorg Chem 45:5785. doi:10.1021/ic060129v

    Article  CAS  Google Scholar 

  12. Wang YT, Tang GM (2007) Inorg Chem Commun 10:53. doi:10.1016/Jinoche.2006.09.010

    Article  Google Scholar 

  13. Xu HX, Ma JP, Huang RQ, Dong YB (2005) Acta Cryst E61:m2462. doi:10.1107/S1600536805034987

    CAS  Google Scholar 

  14. Wang YT, Tang GM, Qiang ZW (2007) Polyhedron 26:4542. doi:10.1016/J.poly.2007.06.026

    Article  CAS  Google Scholar 

  15. Obi K, Kojima A, Fukuda H, Hirai K (1995) Bioorg Med Chem Lett 5:2777. doi:10.1016/0960-894X(95)00485-C

    Article  CAS  Google Scholar 

  16. Mishra L, Said MK, Itokawa H, Takeya K (1995) Bioorg Med Chem 3:1241. doi:10.1016/0968-0896(95)00095-X

    Article  CAS  Google Scholar 

  17. Amabilino DB, Stoddart JF (1995) Chem Rev 95:2725. doi:10.1021/cr00040a005

    Article  CAS  Google Scholar 

  18. Claessens CG, Stoddart JF (1997) J Phys Org Chem 10:254. doi:10.1002/(SICI)1099-1395(199705)10:5<254:AID-POC875>3.0.CO;2-3

    Article  CAS  Google Scholar 

  19. Hirsch KA, Wilson SR, Moore JS (1997) Chem Eur J 3:765. doi:10.1002/Chem.19970030517

    Article  CAS  Google Scholar 

  20. Lee RH, Griswold G, Kleinberg H (1964) Inorg Chem 3:1278. doi:10.1021/ic50019a019

    Article  CAS  Google Scholar 

  21. Singh NK, Butcher RJ, Tripathi P, Srivastava AK, Bharty MK (2007) Acta Cryst E63:o782. doi:10.1107/S1600536806052238

    CAS  Google Scholar 

  22. Nonius (1998) COLLECT Nonius BV, Delft. The Netherlands

  23. Otwinowski Z, Minor W (1997) In: Carter CW, Sweet RM (eds) Methods in enzymology, macromolecular crystallography, part A, vol 276. Academic Press, London, p 307

    Chapter  Google Scholar 

  24. Altomare A, Burla MC, Camalli M, Cascarano GL, Giacovazzo C, Guagliardi A, Moliterni AGG, Polidori G, Spagna R (1999) J Appl Cryst 32:115. doi:10.1107/S0021889898007717

    Article  CAS  Google Scholar 

  25. Oxford Diffraction (2007) CrysAlis RED and CrysAlis CCD Versions 1.171.31.8. Oxford Diffraction Ltd Abingdon, Oxafordshire, England

    Google Scholar 

  26. Sheldrick GM (2008) Acta Cryst A64:112. doi:10.1107/S0108767307043930

    CAS  Google Scholar 

  27. Bruno IJ, Cole JC, Edgington PR, Kessler M, Macrae CF, McCabe P, Pearson J, Taylor R (2002) Acta Crystallogr Sect B58:389. doi:10.1107/S0108768102003324

    CAS  Google Scholar 

  28. Farrugia LJJ (1997) Appl Crystallogr 30:565. doi:10.1107/S0021889897003117

    Article  CAS  Google Scholar 

  29. Molina P, Tarraga A, Espinosa A (1988) Synthesis 9:690. doi:10.1055/s-1988-27672

    Article  Google Scholar 

  30. Patricia GS, Javier GT, Miguel AM, Francisco JA, Teofilo R (2002) Inorg Chem 41:1345. doi:10.1021/ic015625s

    Article  Google Scholar 

  31. Lever ABP (1984) Inorganic electronic spectroscopy, 2nd edn. Elsevier, Amsterdam

    Google Scholar 

  32. Feng X, Shi XG, Ruan F (2009) Z. Kristallogr. NCS 224:193 ISSN:1433-7266

    CAS  Google Scholar 

  33. Chen XM, Huang XY, Xu YJ, Zhu YJ (1995) J Chemical Crystallography 25:605. doi:10.1007/BF01667032

    Article  CAS  Google Scholar 

  34. Usuki N, Yamada M, Ohba M, Okawa H (2001) J Solid State Chem 159:328. doi:10.1006/JSSC.2001.9165

    Article  CAS  Google Scholar 

  35. Bensch W, Nather C, Schur M (1997) Chem Commun 18:1773. doi:10.1039/a702844j

    Article  Google Scholar 

  36. Janiak C (2000) J Chem Soc Dalton Trans 3885. doi:10.1039/b003010o

Download references

Acknowledgments

Authors thank CSIR, New Delhi for financial support by grant No. 01 (2152)07/EMR-II.

Author information

Authors and Affiliations

  1. Department of Chemistry, Banaras Hindu University, Varanasi, 221005, India

    Nand K. Singh, Manoj K. Bharty, Surendra K. Kushawaha & Ram Dulare

  2. Department of Chemistry, Howard University, 525 College Street NW, Washington, DC, 20059, USA

    Raymond J. Butcher

Authors
  1. Nand K. Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Manoj K. Bharty
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Surendra K. Kushawaha
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ram Dulare
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Raymond J. Butcher
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nand K. Singh.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 155 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Singh, N.K., Bharty, M.K., Kushawaha, S.K. et al. Manganese(II) complexes of 5-(4-pyridyl), 5-phenyl and 5-(4-methoxy-phenyl)-1,3,4-oxadiazole-2-thione containing 2, 2′-bipyridyl/ethylenediamine: synthesis, spectral, and X-ray characterization. Transition Met Chem 35, 337–344 (2010). https://doi.org/10.1007/s11243-010-9332-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-010-9332-7

Keywords

Search

Navigation