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Synthesis, Crystal Structure and NLO Properties of a Novel Ruthenium(II) Complex with Unusual Coordination Mode

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Abstract

A new Schiff base 4-[N-hydroxyethyl-N-(methyl)amino]benzaldehyde S-methyl dithiocarbazate (HL, where H is a dissociable proton) and the ruthenium complex [Ru(bpy)2L]PF6 (bpy = 2,2′-bipyridine) have been synthesized. The structural determinations of the ligand and its ruthenium complex, by X-ray crystallography, show that the ligand is coordinated as a monoanionic bidentate N, S-donor, forming a four-member chelate ring with a bite angle of 65.91°. The complex shows intense MLCT transitions in the visible region. Fluorescent and electrochemical properties have been also studied. The complex in DMF solution exhibited a strong two-photon absorption (t.p.a.) at 532 nm nanosecond laser pulses. The t.p.a. coefficient β, t.p.a. cross-section σ and the third-order optical nonlinearity χ(3) of the complex and the ligand have been determined by the Z-scan technique.

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Authors and Affiliations

  1. Department of Chemistry, Anhui University, Hefei, 230039, P.R. China

    Yu-Peng Tian, Ming-Liang Zhang, Zhang-Jun Hu, Han-Mei Hu, Jie-Ying Wu, Xuan-Jun Zhang & Sheng-Yi Zhang

  2. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, P.R. China

    Xu-Tang Tao & Min-Hua Jiang

  3. Department of Physics, Anhui University, Hefei, 230039, P.R. China

    He-Ping Chen

  4. Crystallography Unit, School of Physics, Universiti Sain Malaysia, Penang, USM 11800, Malaysia

    Suchada Chantrapromma & Hoong-Kun Fun

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  1. Yu-Peng Tian
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Tian, YP., Zhang, ML., Hu, ZJ. et al. Synthesis, Crystal Structure and NLO Properties of a Novel Ruthenium(II) Complex with Unusual Coordination Mode. Transition Met Chem 30, 778–785 (2005). https://doi.org/10.1007/s11243-005-4825-5

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