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Synthesis and characterization of mononuclear copper(II) and dinuclear cadmium(II) complexes with di-(2-picolyl)sulfide

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Abstract

The reaction of CuCl2 · 2H2O and CdCl2 with di-(2-picolyl)sulfide (dps) leads to the formation of mononuclear copper(II) and binuclear cadmium(II) complexes, [Cu(dps)Cl2] · H2O (1) and [(dps)(Cl)CdII(μ-Cl)2CdII(Cl)(dps)] (2). The copper atom in (1) is coordinated to one sulfur and two nitrogen atoms from the dps ligand and two chlorides in a distorted square-pyramidal environment. Complex (2) has two distorted octahedra sharing the basal edge that contain the bridging chloro ligands, each of which resides at a center of inversion. Cyclic voltammetric data show that (1) undergoes two reversible one-electron waves corresponding to CuII/CuIII and CuII/CuI processes. However, cyclic voltammetry of (2) gives two irreversible reduced waves.

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Authors and Affiliations

  1. Division of Applied Biology and Chemistry, Research Center for Transgenic Cloned Pigs, Chungnam National University, Taejon, 305-764, Korea

    Nack-Do Sung

  2. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea

    Ki-Young Choi, Han-Hyoung Lee & Kyu-Chul Lee

  3. Department of Physics, Soonchunhyang University, Asan , 336-600, Korea

    Moon-Jip Kim

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  1. Nack-Do Sung
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  2. Ki-Young Choi
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  3. Han-Hyoung Lee
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  4. Kyu-Chul Lee
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  5. Moon-Jip Kim
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Sung, ND., Choi, KY., Lee, HH. et al. Synthesis and characterization of mononuclear copper(II) and dinuclear cadmium(II) complexes with di-(2-picolyl)sulfide. Transition Met Chem 30, 273–277 (2005). https://doi.org/10.1007/s11243-004-3827-z

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  • DOI: https://doi.org/10.1007/s11243-004-3827-z

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