Abstract
Template reactions of 2,4-dihydroxy-, 2,5-dihydroxy-, 2-hydroxy-3-methoxy- and 2-hydroxy-4-methoxy-benzaldehyde with methoxy- and hydroxy-substituted salicylaldehyde S-methylthiosemicarbazones in the presence of NiCl2 and FeCl3 resulted in the corresponding hydroxy- and methoxy-substituted N1,N4-diarylidene-S-methylthiosemi-carbazone complexes. Characterization of the compounds, [Fe(L)Cl] and [Ni(L)], was accomplished by means of elemental analysis, conductivity and magnetic measurements, i.r. and 1H-n.m.r. spectra. A systematic trend has been observed for the chemical shift values of the aromatic protons in the spectra of complexes.
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S.G. Shova M.A. Yampol’skaya B.G. Zemskov K.I. Turte I.N. Ivleva (1985) Russ. J. Inorg. Chem. 30 1312
W.J. Geary (1971) Coord. Chem. Rev. 7 81 Occurrence Handle10.1016/S0010-8545(00)80009-0
N.V. Gerbeleu M.A. Yampol’skaya K.I. Turte B.Ya. Kuyavskaya S.S. Sokhibov Kh. M. Yakubov (1987) Russ. J. Inorg. Chem. 32 1722
A.G. Melson D. Bush (1965) J. Am. Chem. Soc. 87 1706 Occurrence Handle10.1021/ja01086a015
K.P. Balakrishnan V. Krisnan (1979) J. Inorg. Chem. 41 37
W.D. Allen D.E. Cropper (1990) Polyhedron 9 134
D.X. West A.E. Liberta S.B. Padhye R.C. Chikate P.B. Sonwane A.S. Kumbhar R.G. Yerande (1993) Coord. Chem. Rev. 123 49 Occurrence Handle10.1016/0010-8545(93)85052-6
B. Ülküseven M. Cerito\v glu (2002) Transition Met. Chem. 27 390 Occurrence Handle10.1023/A:1015003120160
V.M. Leovac L.S. Jovanovic L.J. Bjelica V.I. Cesljevic (1989) Polyhedron 8 135 Occurrence Handle10.1016/S0277-5387(00)86494-3
M.A. Yampol’skaya S.G. Shova N.V. Gerbeleu Yu.A. Simonov V.K. Bel’skii A.A. Dvorkin (1983) Russ. J. Inorg. Chem. 28 984
D.X. West A.E. Liberta S.B. Padhye R.C. Chikate P.B. Sonawane A.S. Kumbhar R.G. Yerande (1993) Coord. Chem. Rev. 123 49 Occurrence Handle10.1016/0010-8545(93)85052-6
M.J.M. Campbell (1975) Coord. Chem. Rev. 15 279 Occurrence Handle10.1016/S0010-8545(00)80276-3
A.R. Cowley J.R. Dilworth P.S. Donnelly E. Labisbal A. Sousa (2002) J. Am. Chem. Soc. 124 5270 Occurrence Handle10.1021/ja012668z Occurrence Handle11996559
D.R. Richardson (2002) Crit. Rev. Oncol./Hematol. 42 267 Occurrence Handle10.1016/S1040-8428(01)00218-9
S.E. Asis A.M. Bruno A.R. Martinez M.V. Sevilla C.H. Gaozza A.M. Romano J.D. Coussio G. Ciccia (1999) II. Farmaco 54 517 Occurrence Handle10.1016/S0014-827X(99)00050-6
A. Kolocouris K. Dimas C. Pannecouque M. Witvrouw G.B. Foscolos G. Stamatiou G. Fytas G. Zoidis N. Kolocouris G. Andrei R. Snoeck E. De Clercq (2002) Biorg. Med. Chem. Lett. 12 723 Occurrence Handle10.1016/S0960-894X(01)00838-1
Ah. Altun M. Kumru A. Dimoglo (2001) J. Mol. Struct. (Theochem.) 535 23 Occurrence Handle10.1016/S0166-1280(00)00582-0
N.C. Kasuga K. Sekino C. Koumo N. Shimada M. Ishikawa K. Nomiya (2001) J. Inorg. Biochem. 84 55 Occurrence Handle10.1016/S0162-0134(00)00221-X Occurrence Handle11330482
C. Yamazaki (1975) Can. J. Chem. 53 610
K.M. Szécsényi V.M. Leovac E.Z. Ivegeś L. Arman A. Kovács G. Pokol S. Gál (1997) Thermochimica Acta 291 101 Occurrence Handle10.1016/S0040-6031(96)03086-9
D.X. West M.M. Salberg G.A. Bain A.E. Liberta (1997) Transition Met. Chem 22 180 Occurrence Handle10.1023/A:1018431600844
V.M. Leovac V. Divjakovic V.I. Cesljevic (1987) Polyhedron 6 1901 Occurrence Handle10.1016/S0277-5387(00)81101-8
V.M. Leovac V.I. Cesljevic (1988) Polyhedron 7 2641 Occurrence Handle10.1016/S0277-5387(00)83886-3
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Bal, T., Ülküseven, B. Hydroxy and methoxy substituted N1,N4-diarylidene-S-methylthiosemicarbazone iron(III) and nickel(II) complexes. Transition Met Chem 29, 880–884 (2004). https://doi.org/10.1007/s11243-004-2240-y
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DOI: https://doi.org/10.1007/s11243-004-2240-y