Abstract
Although subsurface contamination by organic chemicals is a pervasive environmental problem, a permeable reactive barrier (PRB) as a typical in-situ remediation technology is often successful at many sites. Laboratory tests have shown that perchloroethylene (PCE) can be dechlorinated by the combination of zero-valent iron and anaerobic microbial communities (FeMB), and the degradation pathway was: PCE → TCE → 1, 1-DCE → ethylene→ ethane (Ma amd Wu Environ Geol 55(1):47–54, 2008). Based on Ma’s experimental results, we have extended MT3DMS to simulate mother-daughter chain reactions using MODFLOW-2005 V1.7/MT3DMS V5.2. Second, using FeMB as multi-PRB’s reactive media, a 5-component transport model for a three-dimensional aquifer contaminated by PCE subject to multi-PRB remediation was built. Third, the adsorption and degradation parameters of reactive media were estimated by means of genetic algorithm. Finally, the three-dimensional, homogeneous aquifer contaminated by PCE subject to multi-PRB remediation was simulated. Overall, the purpose of this paper was to use FeMB as multi-PRB’s reactive media, and develop a modified MODFLOW/MT3DMS that can simulate a three-dimensional aquifer contaminated by PCE and its daughters. Results demonstrated that FeMB could be a potential reactive media for PCE-contaminated groundwater. Multi-PRB could be a preferred option for secondly pollution caused by application of one-stage PRB. The modified MODFLOW/MT3DMS can effectively simulate multispecies mother–daughter chain kinetic reactions. Sensitivity analysis showed that losses of reactivity and permeability may have a significant effect on remediation’s success.
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References
Barry D.A., Prommer H., Miller C.T. et al.: Modelling the fate of oxidisable organic contaminants in groundwater. Adv. Water Resour. 25(8–12), 945–983 (2002)
Blowes D.W., Ptacek C.J.: Geochemical remediation of ground-water by permeable reactive walls; removal of chromate by reduction with iron bearing solids. In: Proceedings of the Subsurface Restoration Conference, pp. 214–216. Dallas: Third International Conference on Groundwater Quality Research (1992)
Borden R.C.: Concurrent bioremediation of perchlorate and 1,1,1-trichloroethane in an emulsified oil barrier. J. Contam. Hydrol. 94(1–2), 13–33 (2007)
Clement T.P.: RT3D v2.5 Updates to User’s Guide. Pacific Northwest National Laboratory, Richland (2003)
Environmental security technology certification program. (ESTCP): Bioaugmentation for remediation of chlorinated solvents: technology development, status, and research needs (2005)
Harbaugh A.W.: MODFLOW-2005, The U.S. Geological Survey, Modular ground-water model -the ground-water flow process: U.S. Geological Survey Techniques and Methods 6-A16(2005)
Henderson Andrew D., Demond A.H.: Long-Term Performance of Zero-Valent Iron Permeable Reactive Barriers: A Critical Review. Environ. Eng. Sci. 24(4), 401–423 (2007)
Hirata T., Nakasugi , Yoshioka M. et al.: Groundwater pollution by volatile organochlorines in Japan and related phenomena in the subsurface environment. Water Sci. Technol. 26(12), 9–16 (1992)
Lai K.C.K., Irene M.C.L., Birkelund V. et al.: Field monitoring of a permeable reactive barrier for removal of chlorinated organics. J. Environ. Eng. 132(2), 199–210 (2006)
Lee J.-Y., Lee K.-J., Young Youm S. et al.: Stability of multi-permeable reactive barriers for long term removal of mixed contaminants. Bull. Environ. Contam. Toxicol. 84(2), 250–254 (2010)
Legates D.R., McCabe G.J. Jr: Evaluating the use of “goodness-of-fit” measures in hydrologic and hydroclimatic model validation. Water Resour. Res. 35(1), 233–241 (1999)
Liu M., Chen H., Hu L. et al.: Modeling of transformation and transportation of PCE and TCE by biodegradation in shallow groundwater. Earth Sci. Front. 13(1), 155–159 (2006)
Liu M.: Study on numerical simulation of migration and transformation of chlorinated hydrocarbon in shallow groundwater. China University of Geosciences, Beijing (2002)
Long Cameron M., Borden R.C.: Enhanced reductive dechlorination in columns treated with edible oil emulsion. J. Contam. Hydrol. 87(1-2), 54–72 (2006)
Lu X., Sun Y., Petersen J.N.: Analytical solutions of TCE transport with convergent reactions. Transp. Porous Med. 51(2), 211–225 (2003)
Macdonald J.A., Kavanaugh M.C.: Restoring contaminated groundwater: an achievable goal?. Environ. Sci. Technol. 28(8), 362A–368A (1994)
Ma C.: Transport, fate and remediation of perchloroethylene in groundwater. Shanghai Jiao Tong University, Shanghai (2007)
Ma C., Wu Y.: Dechlorination of perchloroethylene using zero-valent metal and microbial community. Environ. Geol. 55(1), 47–54 (2008)
Mitchell M.: An introduction to genetic algorithms. The MIT press, Cambridge (1998)
Partick R., Ford E., Quarles J.: Groundwater contamination in the USA. University of Pennsylvania Press, Philadelphia (1987)
Semprini L., Roberts P.V., Hopkins G.D. et al.: A field evaluation of in situ biodegradation of chlorinated ethenes: part 2, results of biostimulation and biotransformation experiments. Ground Water 28(5), 715–727 (1990)
Sun Y., Petersen J.N., Clement T.P. et al.: Development of analytical solutions for multispecies transport with serial and parallel reactions. Water Resour. Res. 35(1), 185–190 (1999)
Sun Y., Lu X., Petersen J.N. et al.: An analytical solution of tetrachloroethylene transport and biodegradation. Transp. Porous Med. 55(3), 301–308 (2004)
Teles V., Delay F., de Marsily G.: Comparison of transport simulations and equivalent dispersion coefficients in heterogeneous media generated by different numerical methods: a genesis model and a simple geostatistical sequential Gaussian simulator. Geosphere 2(5), 275–286 (2006)
U.S. Environmental Protection Agency.: Cleaning up the nation’s waste sites: markets and technology trends. EPA-542-R-96-005, PB96-178041 (1997)
U.S. Environmental Protection Agency.: Field applications of in situ remediation technologies: permeable reactive barriers. U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response, Technology Innovation Office, Washington, DC 20460 (2002)
U.S. Environmental Protection Agency.: The remediation technologies development forum: Major accomplishments (1992-2006). EPA 542-F-06-005 (2006)
U.S. Geological Survey.: Volatile organic compounds in the nation’s ground water and drinking-water supply wells-a summary. Fact Sheet 2006–3048 (2006)
Wadley Sharon L.S., Gillham R.W., Gui L.: Remediation of DNAPL source zones with granular iron: laboratory and field tests. Ground water 43(1), 9–18 (2005)
Wiedemeier T. H., Swanson M. A., Moutoux D. E., et al.: Technical protocol for evaluating natural attenuation of chlorinated solvents in groundwater, Air Force Center for Environmental Excellence, Technology Transfer Division, Brooks AFB, San Antonio (1996)
Zhang K., Woodbury A.D.: A Krylov finite element approach for multi-species contaminant transport in discretely fractured porous media. Adv. Water Resour. 25(7), 705–721 (2002)
Zheng C.: MT3D’99 a modular 3D multispecies transport simulator. S.S Papadopulos & Associates, Inc, Bethesda (1999)
Zheng, C.: MT3DMS v5.2 Supplemental User’s Guide. Department of Geological Sciences University of Alabama (2006)
Zheng C., Bennett G.D.: Applied contaminant transport modeling, 2th edn. Higher Education Press, Beijing (2009)
Zheng C.: Recent developments and future directions for MT3DMS and related transport codes. Ground Water 47(5), 620–625 (2009a)
Zheng C.: MT3DMS v5.3 Supplemental User’s Guide. Department of Geological Sciences University of Alabama (2009b)
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Xu, Z., Wu, Y. & Yu, F. A Three-Dimensional Flow and Transport Modeling of an Aquifer Contaminated by Perchloroethylene Subject to Multi-PRB Remediation. Transp Porous Med 91, 319–337 (2012). https://doi.org/10.1007/s11242-011-9847-1
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DOI: https://doi.org/10.1007/s11242-011-9847-1