Abstract
In the past decades, there was considerable controversy over the Lucas–Washburn (LW) equation widely applied in capillary imbibition kinetics. Many experimental results showed that the time exponent of the LW equation is less than 0.5. Based on the tortuous capillary model and fractal geometry, the effect of tortuosity on the capillary imbibition in wetting porous media is discussed in this article. The average height growth of wetting liquid in porous media driven by capillary force following the \({\overline L _{\rm {s}}(t)\sim t^{1/{2D_{\rm {T}}}}}\) law is obtained (here D T is the fractal dimension for tortuosity, which represents the heterogeneity of flow in porous media). The LW law turns out to be the special case when the straight capillary tube (D T = 1) is assumed. The predictions by the present model for the time exponent for capillary imbibition in porous media are compared with available experimental data, and the present model can reproduce approximately the global trend of variation of the time exponent with porosity changing.
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Abbreviations
- A :
-
Cross-sectional area (cm2)
- A p :
-
Total pore cross-sectional area (cm2)
- C 1 :
-
Constant, as defined by Eq. 1
- C 2 :
-
Water absorption coefficient
- d :
-
Euclidean dimension
- D :
-
Fractal dimension
- D f :
-
Pore fractal dimension
- D T :
-
Tortuosity fractal dimension
- K :
-
Effective permeability (Darcy)
- k :
-
Time exponent
- L f :
-
Actual length that the flow travels (cm)
- L s :
-
Straight-line length (cm)
- M :
-
Imbibed weight in porous media (g)
- m :
-
Imbibed weight in a single capillary (g)
- N wt :
-
Imbibed volume in porous media
- n :
-
Pores/capillaries number
- P c :
-
Capillary pressure (Pa)
- \({\overline r }\) :
-
Effective radius for pores (cm)
- r eff :
-
Statistical effective radius (cm)
- S wf :
-
Water saturation behind imbibition front (fraction)
- S wi :
-
Initial water saturation (fraction)
- t :
-
Imbibition time (s)
- V b :
-
Bulk volume
- V p :
-
Pore volume
- δ :
-
Pore shape factor
- σ :
-
Surface tension (N/m)
- μ :
-
Viscosity (Pa s)
- \({\varepsilon }\) :
-
Measuring unit
- λ:
-
Pore diameter (cm)
- \({\phi _2}\) :
-
Areal porosity
- \({\phi _3}\) :
-
Volume porosity
- Ω:
-
Integrating region ranging the minimum to the maximum capillaries
- θ :
-
Contact angle
- ρ :
-
Liquid density (g/cm3)
- τ :
-
Tortuosity
- av:
-
Average value
- max:
-
Maximum value
- min:
-
Minimum value
References
Balankin A.S., Paredes R.G., Susarrey O., Morales D., Vacio F.C.: Kinetic roughening and pinning of two coupled interfaces in disordered media. Phys. Rev. Lett. 96, 056101 (2006)
Balankin A.S., Susarrey O., Máquez Gonzáes J.: Scaling properties of pinned interfaces in fractal media. Phys. Rev. Lett. 90, 096101 (2003)
Barenblatt G.I., Entov V.M., Ryzhik V.M.: Theory of unsteady filtration of liquid and gases (in Russian). Nedra, Moscow (1972)
Bear J.: Dynamics of fluids in porous media. Elsevier, New York (1972)
Bell J.M., Cameron F.K.: The flow of liquids through capillary spaces. J. Phys. Chem. 10, 658–674 (1906)
Benavente D., Lock P., Ángeles García Del Cura M., Ordóñez S.: Predicting the capillary imbibition of porous rocks from microstructure. Transp. Porous Med. 49, 59–76 (2002)
Brú A., Pastor J.M.: Experimental characterization of hydration and pinning in bentonite clay, a swelling, heterogeneous, porous medium. Geoderma 134, 295–305 (2006)
Cai J.C., Yu B.M., Luo L., Mei M.F.: Capillary rise in a single tortuous capillary. Chin. Phys. Lett. 27, 054701 (2010a)
Cai J.C., Yu B.M., Zou M.Q., Luo L.: Fractal characterization of spontaneous co-current imbibition in porous media. Energy Fuels 24, 1860–1867 (2010b)
Comiti J., Renaud M.: A new model for determining mean structure parameters of fixed beds from pressure measurements: application to beds packed with parallelepipedal particles. Chem. Eng. Sci. 44, 1539–1545 (1989)
De Boer J.J.: The wettability of scoured and dried cotton fabrics. Textile Res. J. 50, 624–631 (1980)
Delker T., Pengra D.B., Wong P.-z.: Interface pinning and the dynamics of capillary rise in porous media. Phys. Rev. Lett. 76, 2902–2905 (1996)
Dicke M., Burrough P.A.: Using fractal dimensions for characterizing tortuosity of animal trails. Physiol. Entomol. 13, 393–398 (1988)
Doyen P.M.: Permeability, conductivity, and pore geometry of sandstone. J. Geophys. Res. 93, 7729–7740 (1988)
Dubé M., Rost M., Alava M.: Conserved dynamics and interface roughening in spontaneous imbibition: A critical overview. Eur. Phys. J. B 15, 691–699 (2000)
Dubé M., Rost M., Elder K.R., Alava M., Majaniemi S., Ala-Nissila T.: Liquid conservation and nonlocal interface dynamics in imbibition. Phys. Rev. Lett. 83, 1628–1631 (1999)
Dullien F.A.L.: Porous media: fluid transport and pore structure. Academic Press, San Diego (1992)
Eklund D.E., Salminen P.J.: Water transport in the blade coating process. Tappi J. 69, 116–119 (1986)
Family F., Chan K.C.B., Amar J.G.: Surface disordering: growth, roughening and phase transitions. Nova Science, New York (1992)
Fries N., Dreyer M.: An analytic solution of capillary rise restrained by gravity. J. Colloid Interface Sci. 320, 259–263 (2008)
Hammecker C., Barbiéro L., Boivin P., Maeght J.L., Diaw E.H.B.: A geometrical pore model for estimating the microscopical pore geometry of soil with infiltration measurements. Transp. Porous Med. 54, 193–219 (2004)
Hammecker C., Mertz J.-D., Fischer C., Jeannette D.: A geometrical model for numerical simulation of capillary imbibition in sedimentary rocks. Transp. Porous Med. 12, 125–141 (1993)
Handy L.L.: Determination of effective capillary pressures for porous media from imbibition data. Pet. Trans. AIME 219, 75–80 (1960)
Horváh V.K., Stanley H.E.: Temporal scaling of interfaces propagating in porous media. Phys. Rev. E 52, 5166–5169 (1995)
Huber P., Grüner S., Schäfer C., Knorr K., Kityk A.V.: Rheology of liquids in nanopores: a study on the capillary rise of water, n-Hexadecane and n-Tetracosane in mesoporous silica. Eur. Phys. J. Spec. Top. 141, 101–105 (2007)
Karoglou M., Moropoulou A., Giakoumaki A., Krokida M.K.: Capillary rise kinetics of some building materials. J. Colloid Interface Sci. 284, 260–264 (2005)
Katz , A.J. , Thompson A.H.: Fractal sandstone pores: implications for conductivity and formation. Phys. Rev. Lett. 54, 1325–1328 (1985)
Kopelman R., Parus S., Prasad J.: Fractal-Like exciton kinetics in porous glasses, organic membranes, and filter papers. Phys. Rev. Lett. 56, 1742–1745 (1986)
Koponen A., Kataja M., Timonen J.: Permeability and effective porosity of porous media. Phys. Rev. E 56, 3319–3325 (1997)
Kwon T.H., Hopkins A.E., O’Donnell S.E.: Dynamic scaling behavior of a growing self-affine fractal interface in a paper-towel-wetting experiment. Phys. Rev. E 54, 685–690 (1996)
Lam C.H., Lam C.H., Lam C.H.: Pipe network model for scaling of dynamic interfaces in porous media. Phys. Rev. Lett. 85, 1238–1241 (2000)
Laughlin R.D., Davis J.E.: Some aspects of capillary absorption in fibrous textile wicking. Textile Res. J. 31, 904–910 (1961)
Leventis A., Verganelakis D.A., Halse M.R., Webber J.B., Strange J.H.: Capillary imbibition and pore characterisation in eement pastes. Transp. Porous Med. 39, 143–157 (2000)
Li K.W.: Scaling of spontaneous imbibition data with wettability included. J. Contam. Hydrol. 89, 218–230 (2007)
Li K.W., Chow K., Horne N.: Influence of initial water saturation on recovery by spontaneous imbibition in Gas/Water/Rock systems and the calculation of relative permeability. SPE Res. Eval. Eng. 9, 295–301 (2006)
Li K.W., Li K.W., Li K.W.: Characterization of spontaneous water imbibition into gas-saturated rocks. SPEJ 6, 375–384 (2001)
Li K.W., Horne R.N.: An analytical scaling method for spontaneous imbibition in gas–water–rock systems. SPEJ 9, 322–329 (2004)
Lucas R.: Rate of capillary ascension of liquids. Kolloid-Zeitschrift 23, 15–22 (1918)
Lundblad A., Bergman B.: Determination of contact-angle in porous molten-carbonate fuel-cell Electrodes. J. Electrochem. Soc. 144, 984–987 (1997)
Ma S., Morrow N.R., Zhang X.: Generalized scaling of spontaneous imbibition data for strongly water-wet systems. In: Paper 95–138, presented at the 6th Petroleum Conference of the South Saskatchewan Section, the Petroleum Society of CIM, held in Regina, 16–18 Oct, 1995
Majumdar A.: Role of fractal geometry in the study of thermal phenomena. Annu. Rev. Heat. Trans. 4, 51–110 (1992)
Perfect E., Kay B.D.: Fractal theory applied to soil aggregation. Soil Sci. Soc. Am. J. 55, 1552–1558 (1991)
Shou D.H., Fan J.T., Ding F.: A difference-fractal model for the permeability of fibrous porous media. Phys. Lett. A. 374, 1201–1204 (2010)
Washburn E.W.: Dynamics of capillary flow. Phys. Rev. 17, 273–283 (1921)
Wheatcraft S.W., Tyler S.W.: An explanation of scale-dependent dispersivity in heterogeneous aquifers using concepts of fractal geometry. Water Resour. Res. 24, 566–578 (1988)
XiaoB.Q. Gao S.H., Chen L.X.: A fractal model for nucleate pool boiling of nanofluids at high heat flux including CHF. Fractals 18, 409–415 (2010a)
Xiao B.Q., Jiang G.P., Chen L.X.: A fractal study for nucleate pool boiling heat transfer of nanofluids. Sci. China Phys. Mech. Astron. 53, 30–37 (2010b)
Xu P., Yu B.M.: Developing a new form of permeability and Kozeny-Carman constant for homogeneous porous media by means of fractal geometry. Adv. Water Resour. 31, 74–81 (2008)
Yu B.M.: Fractal character for tortuous streamtubes in porous media. Chin. Phys. Lett. 22, 158–160 (2005)
Yu B.M.: Analysis of flow in fractal porous media. Appl. Mech. Rev. 61, 050801 (2008)
Yu B.M., Cai J.C., Zou M.Q.: On the physical properties of apparent two-phase fractal porous media. Vadose Zone J. 8, 177–186 (2009)
Yu B.M., Cheng P.: A fractal permeability model for bi-dispersed porous media. Int. J. Heat Mass Trans. 45, 2983–2993 (2002)
Yu B.M., Lee L.J., Cao H.Q.: A fractal in-plane permeability model for fabrics. Polym. Compos. 22, 201–221 (2002)
Yu B.M., Li J.H.: Some fractal characters of porous media. Fractals 9, 365–372 (2001)
Yu B.M., Li J.H.: A geometry model for tortuosity of flow path in porous media. Chin. Phys. Lett. 21, 1569–1571 (2004)
Yun M.J., Yu B.M., Cai J.C.: Analysis of seepage characters in fractal porous media. Int. J. Heat Mass Trans. 52, 3272–3278 (2009)
Zhao, H.Y., Li, K.W.: A fractal model of production by spontaneous water imbibition. In: SPE119525, presented at the Latin American and Caribbean Petroleum Engineering Conference held in Cartagena, 31 May– 3 June, 2009
Zhou L., Selim H.M.: A conceptual fractal model for describing time-dependent dspersivity. Soil Sci. 167, 173–183 (2002)
Zhuang Q., Harlock S.C., Brook D.B.: Longitudinal wicking of weft knitted fabrics: part II: wicking mechanism of knitted fabrics used in undergarments for outdoor activities. J. Textile Inst. 93, 97–107 (2002)
Zimmerman R.W., Bodvarsson G.S.: A simple approximate solution for horizontal infiltration in a Brooks–Corey medium. Transp. Porous Med. 6, 195–205 (1991)
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Cai, J., Yu, B. A Discussion of the Effect of Tortuosity on the Capillary Imbibition in Porous Media. Transp Porous Med 89, 251–263 (2011). https://doi.org/10.1007/s11242-011-9767-0
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DOI: https://doi.org/10.1007/s11242-011-9767-0