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Effect of Mechanochemical Treatment on Acidic and Catalytic Properties of MgO-SiO2 Composition in the Conversion of Ethanol To 1,3-Butadiene

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Theoretical and Experimental Chemistry Aims and scope

It was shown that mechanochemical treatment of the MgO-SiO2 composition leads to an increase of its activity and selectivity in the heterogeneous catalytic conversion of ethanol into 1,3-butadiene. This results from the formation of active reaction sites for aldol–crotonic condensation on the surface of the —Mg—O—Si≡ structural fragments, which are Lewis acidic sites.

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References

  1. J. A. Posada, A. D. Patel, A. Roes, et al., Bioresour. Technol., 135, 490–499 (2013).

    Article  CAS  Google Scholar 

  2. E. V. Makshina, M. Dusselier, W. Janssens, et al., Chem. Soc. Rev., 43, 7917–7953 (2014).

    Article  CAS  Google Scholar 

  3. E. V. Makshina, W. Janssens, B. F. Sels, and P. A. Jacobs, Catal. Today, 198, 338–344 (2012).

    Article  CAS  Google Scholar 

  4. M. Gao, Z. Liu, M. Zhang, and L. Tong, Catal. Lett., 144, 2071–2079 (2014).

    Article  CAS  Google Scholar 

  5. W. Janssens, E. V. Makshina, P. Vanelderen, et al., ChemSusChem, 8, 994–1008 (2015).

    Article  CAS  Google Scholar 

  6. C. Angelici, M. E. Z. Velthoen, B. M. Weckhuysen, and P. C. A. Bruijnincx, ChemSusChem, 7, 2505–2515 (2014).

    Article  CAS  Google Scholar 

  7. M. Lewandowski, G. S. Babu, M. Vezzoli, et al., Catal. Commun., 49, 25–28 (2014).

    Article  CAS  Google Scholar 

  8. O. V. Larina, P. I. Kyriienko, and S. O. Soloviev, Teor. Éksp. Khim., 51, No. 4, 244–249 (2015). [Theor. Exp. Chem., 51, No. 4, 252–258 (2015) (English translation).]

  9. C. Angelici, B. M. Weckhuysen, and P. C. A. Bruijnincx, ChemSusChem, 6, 1595–1614 (2013).

    Article  CAS  Google Scholar 

  10. A. Chieregato, J. Velasquez Ochoa, C. Bandinelli, et al., ChemSusChem, 8, 377–388 (2015).

    Article  CAS  Google Scholar 

  11. C. Angelici, M. E. Z. Velthoen, B. M. Weckhuysen, and P. C. A. Bruijnincx, Catal. Sci. Technol., 2869–2879 (2015).

  12. M. Zhang, M. Gao, J. Chen, and Y. Yu, RSC Adv., 5, 25959–25966 (2015).

    Article  CAS  Google Scholar 

  13. O. V. Larina, P. I. Kyriienko, and S. O. Soloviev, Catal. Lett., 145, 1162–1168 (2015).

    Article  CAS  Google Scholar 

  14. J. Temuujin, K. Okada, and K. J. D. MacKenzie, J. Solid State Chem., 138, 169–177 (1998).

    Article  CAS  Google Scholar 

  15. N. V. Vlasenko, Y. N. Kochkin, and A. M. Puziy, J. Mol. Catal. A, 253, 192–197 (2006).

    Article  CAS  Google Scholar 

  16. G. I. Kapustin and T. R. Brueva, Thermochim. Acta, 379, 71–75 (2001).

    Article  CAS  Google Scholar 

  17. I. M. Abdulmajeed, F. A. Chyad, M. M. Abbas, and H. A. Kareem, Int. J. Innov. Res. Sci., 2, 5101–5106 (2013).

    Google Scholar 

  18. H. Pang, G. Ning, W. Gong, et al., Chem. Commun., 47, 6317–6319 (2011).

    Article  CAS  Google Scholar 

  19. F. Tavangarian, R. Emadi, and A. Shafyei, Powder Technol., 198, 412–416 (2010).

    Article  CAS  Google Scholar 

  20. K. J. D. MacKenzie and M. E. Smith, Multinuclear Solid-State Nuclear Magnetic Resonance of Inorganic Materials, Pergamon Press, Amsterdam (2002).

    Google Scholar 

  21. J. M. Griffin, A. J. Berry, and S. E. Ashbrook, Solid State Nucl. Magn. Reson., 40, 91–99 (2011).

    Article  CAS  Google Scholar 

  22. J. Temuujin, K. Okada, and K. J. D. MacKenzie, J. Am. Ceram. Soc., 81, 754–756 (2005).

    Article  Google Scholar 

  23. J.-B. d’Espinose de la Caillerie, M. Kermarec, and O. Clause, J. Phys. Chem., 99, 17273–17281 (1995).

    Article  Google Scholar 

  24. S. Haukka, E.-L. Lakomaa, and A. Root, J. Phys. Chem., 97, 5085–5094 (1993).

    Article  CAS  Google Scholar 

  25. A. Corma, Chem. Rev., 95, 559–614 (1995).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    O. V. Larina, P. I. Kyriienko & S. O. Soloviev

  2. Technical Center, National Academy of Sciences of Ukraine, Vul. Pokrovs’ka, 13, Kyiv, 04070, Ukraine

    V. V. Trachevskii & N. V. Vlasenko

Authors
  1. O. V. Larina
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  2. P. I. Kyriienko
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  3. V. V. Trachevskii
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  4. N. V. Vlasenko
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  5. S. O. Soloviev
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Corresponding authors

Correspondence to O. V. Larina or V. V. Trachevskii.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 51, No. 6, pp. 378–384, November-December, 2015.

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Larina, O.V., Kyriienko, P.I., Trachevskii, V.V. et al. Effect of Mechanochemical Treatment on Acidic and Catalytic Properties of MgO-SiO2 Composition in the Conversion of Ethanol To 1,3-Butadiene. Theor Exp Chem 51, 387–393 (2016). https://doi.org/10.1007/s11237-016-9440-3

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  • DOI: https://doi.org/10.1007/s11237-016-9440-3

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