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Catalytic hydrochlorination of acetylene on mechanochemically-activated K2PdCl4

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Theoretical and Experimental Chemistry Aims and scope

We report the catalysis of the hydrochlorination of acetylene on the surface of dry K2PdCl4 subjected to prior mechanical activation in an atmosphere of acetylene or propylene. The stereochemistry of the reaction corresponds to trans addition of the halogen and hydrogen atoms to the C-C triple bond. The hydrogen halide is the source of the halogen atom in the reaction product. The mechanical activation of K2PdCl4, in contrast to the case of K2PtCl4, is also capable of activating the C-C double bond: propylene is hydrochlorinated under similar conditions to isopropyl chloride.

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References

  1. I. P. Beletskaya and C. Moberg, Chem. Rev., 99, No. 12, 3435–3461 (1999).

    Article  CAS  Google Scholar 

  2. F. Alonso, I. P. Beletskaya, and M. Yus, Chem. Rev., 104, No. 6, 3079–3159 (2004).

    Article  CAS  Google Scholar 

  3. O. N. Temkin, G. K. Shestakov, and Yu. A. Treger, Acetylene: Chemistry, Reaction Mechanisms, and Technology [in Russian], Khimiya, Moscow (1991).

    Google Scholar 

  4. J. B. Agnew and H. S. Shankar, Ind. Eng. Chem. Prod. Res. Dev., 25, 19–25 (1986).

    Article  CAS  Google Scholar 

  5. B. Nkosi, N. J. Coville, and G. J. Hutchings, Appl. Catal., 43, 33 (1988).

    Article  CAS  Google Scholar 

  6. M. Conte, A. F. Carley, C. Heirene, et al., J. Catal., 250, 231 (2007).

    Article  CAS  Google Scholar 

  7. S. A. Panova, G. K. Shestakov, and O. N. Temkin, J. Chem. Soc., Chem. Commun., 977 (1974).

  8. S. A. Mitchenko, E. V. Khomutov, A. A. Shubin, and Yu. M. Shul'ga, J. Mol. Catal. A, 212, 345 (2004).

    Article  CAS  Google Scholar 

  9. S. A. Mitchenko, T. V. Krasnyakova, R. S. Mitchenko, and A. N. Korduban, J. Mol. Catal. A, 275, 101 (2007).

    Article  CAS  Google Scholar 

  10. I. N. Chernyaev (ed.), Synthesis of Platinum Group Metal Complexes [in Russian], Nauka, Moscow (1964).

    Google Scholar 

  11. F. M. Rapoport and A. A. Il'inskaya, Laboratory Methods for the Preparation of Pure Gases [in Russian], Goskhimizdat, Moscow (1963).

    Google Scholar 

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Vul. R. Luxemburg, 70, Donets’k, 83114, Ukraine

    S. A. Mitchenko & T. V. Krasnyakova

  2. Taras Shevchenko Lugans’k National University, Vul. Oboronna, 2, Lugans’k, 91011, Ukraine

    I. V. Zhikharev

  3. Donets’k Branch of the A. A. Galkin Institute of Physics Technology, National Academy of Sciences of Ukraine, at Taras Shevchenko Lugans’k National University, Vul. Oboronna, 2, Lugans’k, 91011, Ukraine

    S. A. Mitchenko, T. V. Krasnyakova & I. V. Zhikharev

Authors
  1. S. A. Mitchenko
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  2. T. V. Krasnyakova
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  3. I. V. Zhikharev
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Correspondence to S. A. Mitchenko.

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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 44, No. 5, pp. 306–309, September–October, 2008.

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Mitchenko, S.A., Krasnyakova, T.V. & Zhikharev, I.V. Catalytic hydrochlorination of acetylene on mechanochemically-activated K2PdCl4 . Theor Exp Chem 44, 316–319 (2008). https://doi.org/10.1007/s11237-008-9039-4

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  • DOI: https://doi.org/10.1007/s11237-008-9039-4

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