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Kinetics of the oxidation of diethyl sulfide in the B(OH)3-H2O2/H2O system

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Abstract

Data obtained for the kinetics of oxidation of diethyl sulfide (Et2S) by hydrogen peroxide in aqueous solution catalyzed by boric acid indicate that monoperoxoborates B(O2H)(OH) −3 and diperoxoborates B(O2H)2(OH) −2 are the active species. The rates of the reactions of Et2S with B(O2H)(OH) −3 and B(O2H)2(OH) −2 are 2.5 and 100 times greater than with H2O2.

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Vul. R. Luxemburg, 70, Donets’k, 83114, Ukraine

    V. L. Lobachev, G. P. Zimtseva, Ya. V. Matvienko & E. S. Rudakov

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  1. V. L. Lobachev
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  2. G. P. Zimtseva
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  3. Ya. V. Matvienko
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  4. E. S. Rudakov
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 43, No. 1, pp. 38–42, January–February, 2007.

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Lobachev, V.L., Zimtseva, G.P., Matvienko, Y.V. et al. Kinetics of the oxidation of diethyl sulfide in the B(OH)3-H2O2/H2O system. Theor Exp Chem 43, 44–49 (2007). https://doi.org/10.1007/s11237-007-0004-4

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  • DOI: https://doi.org/10.1007/s11237-007-0004-4

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