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Superacids Based on Zirconium Dioxide

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Abstract

The synthesis of the superacidic materials SO 2−4 /ZrO2 and WO3/ZrO2 is examined. The structure of their acidic centers and their activity in the isomerization and acylation of hydrocarbons are discussed.

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REFERENCES

  1. K. Tanabe and W. F. Holderich, Appl. Catal. A, 181, 399–434 (1999).

    Article  Google Scholar 

  2. K. Tanabe, Solid Acids and Bases [Russian translation], Mir, Moscow (1973).

    Google Scholar 

  3. K. Tanabe, Catalysts and Catalytic Processes [Russian translation], Mir, Moscow (1993).

    Google Scholar 

  4. A. Corma, Chem. Rev., 95, No.3, 559–614 (1995).

    Article  Google Scholar 

  5. G. A. Olah, G. K. S. Prakash, and J. Sommer, Superacids, Wiley, New York (1985), pp. 243–335.

    Google Scholar 

  6. K. Arata, Adv. Catal., 37, 165–211 (1990).

    Google Scholar 

  7. W. E. Farneth and Q. Sun, J. Am. Chem. Soc., 118, 7708–7715 (1996).

    Article  Google Scholar 

  8. Y. Ono, K. Yamaguchi, and N. Kitajima, J. Catal., 64, No.1, 13–17 (1980).

    Article  Google Scholar 

  9. M. Misono and T. Okuhara, Chemtech, 23–29, November (1993).

  10. Y. Onoue, Y. Mizutzni, S. Akiyama, and Y. Izumi, Chemtech., 432–435, July (1978).

  11. T. Okuhara, Catal. Today, 73, 167–176 (2002).

    Article  Google Scholar 

  12. M. Hino and K. Arata, J. Chem. Soc., Chem. Commun., No. 18, 851–852 (1980).

  13. M. Hino and K. Arata, J. Chem. Soc., Chem. Commun., No. 18, 1259–1260 (1988).

  14. T. Yamaguchi, Catal. Today, 20, 199–218 (1994).

    Article  Google Scholar 

  15. A. V. Ivanov and L. M. Kustov, Izv. Akad. Nauk, Ser. Khim., No. 1, 38–44 (2000).

  16. V. M. Mastikhin, O. B. Lapina, and I. L. Mudrakovskii, Nuclear Magnetic Resonance in Heterogeneous Catalysis [in Russian], Nauka, Novosibirsk (1992).

    Google Scholar 

  17. V. N. Strekalovskii, Yu. M. Polezhaev, and S. F. Pal’guev, Oxides with Impurity Disorder: Composition, Structure, Phase Transformations [in Russian], Nauka, Moscow (1987).

    Google Scholar 

  18. C. R. Vera, C. L. Pieck, K. Shimizu, and J. M. Parera, Appl. Catal. A, 230, 137–151 (2002).

    Article  Google Scholar 

  19. S. N. Orlik, V. L. Struzhko, T. V. Mironyuk, and G. M. Tel’biz, Kinet. Katal., 44, No.5, 744–754 (2003).

    Google Scholar 

  20. F. R. Chen, G. Coudurier, J. F. Joly, and J. C. Vedrine, J. Catal., 143, No.2, 616–626 (1993).

    Article  Google Scholar 

  21. D. A. Ward and E. I. Ko, J. Catal., 150, 18–33 (1994).

    Article  Google Scholar 

  22. A. Corma, V. Fornes, M. I. Juan-Rajadell, and J. M. Lopez Nieto, Appl. Catal. A, 116, 151–163 (1994).

    Article  Google Scholar 

  23. T. Tatsumi, H. Matsuhashi, and K. A. Arata, Bull. Chem. Soc. Jpn, 69, No.5, 1191–1194 (1996).

    Google Scholar 

  24. K. I. Patrilyak, V. V. Brei, A. V. Melezhik, and N. N. Levchuk, Chemistry, Physics, and Technology of Surfaces [in Russian], No. 3, 20–24 (1999).

  25. A. V. Ivanov and L. M. Kustov, Ross. Khim. Zh., 44, 21–53 (2000).

    Google Scholar 

  26. A. S. Ivanova, Kinet. Katal., 42, No.3, 394–405 (2001).

    Google Scholar 

  27. J. M. Parera, Catal. Today, 15, No.3/4, 481–490 (1992).

    Article  Google Scholar 

  28. V. V. Strelko, Kinet. Katal., 44, No.4, 909–914 (2004).

    Google Scholar 

  29. A. Clearfield, G. P. D. Serette, and A. H. Khazi-Syed, Catal. Today, 20, 295–312 (1994).

    Article  Google Scholar 

  30. L. M. Kustov, V. B. Kazansky, F. Figueras, et al., J. Catal., 150, No.1, 143–149 (1994).

    Article  Google Scholar 

  31. F. Haase and J. Sauer, J. Am. Chem. Soc., 120, No.51, 13503–13512 (1998).

    Article  Google Scholar 

  32. B. H. Davis, R. A. Keogh, and R. Srinivasan, Catal. Today, 20, 219–256 (1994).

    Article  Google Scholar 

  33. C. D. Chang, R. D. Bastian, S. Han, and J. G. Santiesteban, “Combined Paraffin Isomerization/Ring Opening Process,” US Patent No. 5382731, C07 C001/00; C07 C005/13; Mobil Oil Corp., No. 095885, Filed July 22, 1993; Publ. January 17, 1995.

  34. R. A. Boyse and E. I. Ko, J. Catal., 171, 191–207 (1997).

    Article  Google Scholar 

  35. J. G. Santiesteban, J. C. Vartuli, S. Han, et al., J. Catal., 168, 431–441 (1997).

    Article  Google Scholar 

  36. D. G. Barton, S. L. Soled, and E. Iglesia, Top. Catal., 6, 87–99 (1998).

    Article  Google Scholar 

  37. V. V. Brei, O. V. Melezhyk, S. V. Prudius, et al., Stud. Surf. Sci. Catal., 143, 387–395 (2002).

    Google Scholar 

  38. S. V. Prudius, Synthesis and Physicochemical Properties of Superacidic Tungstate-Containing Zirconium Dioxide [in Russian], Author’s Abstract of Thesis for Candidate of Chemical Sciences, Kiev (2003).

  39. D. G. Barton, M. Shtein, R. D. Wilson, et al., J. Phys. Chem. B, 103, 630–640 (1999).

    Article  Google Scholar 

  40. U. Ciesla, M. Froba, G. Stucky, and F. Schuth, Chem. Mater., 11, No.2, 227–234 (1999).

    Article  Google Scholar 

  41. O. V. Melezhyk, S. V. Prudius, and V. V. Brei, Micropor. Mesopor. Mater., 49, No.1–3, 39–44 (2001).

    Article  Google Scholar 

  42. M. Valigi, D. Gazzoli, I. Pettiti, et al., Appl. Catal. A, 231, 159–172 (2002).

    Article  Google Scholar 

  43. C. D. Baertsch, S. L. Soled, and E. Iglesia, J. Phys. Chem. B, 105, 1320–1330 (2001).

    Article  Google Scholar 

  44. F. Di Gregorio and V. Keller, J. Catal., 225, 45–55 (2004).

    Article  Google Scholar 

  45. V. V. Brei, O. V. Melezhyk, S. V. Prudius, et al., Ads. Sci. Techn., 23, No.2, 909–914 (2005).

    Google Scholar 

  46. M. Scheithauer, T.-K. Cheung, R. E. Jentoft, et al., J. Catal., 180, 1–13 (1998).

    Article  Google Scholar 

  47. S. Triwahyono, T. Yamada, and H. Hattori, Appl. Catal. A, 242, 101–109 (2003).

    Article  Google Scholar 

  48. E. A. Paukshtis and E. N. Yurchenko, Usp. Khim., 52, 426–454 (1983).

    Google Scholar 

  49. J. Macht, C. D. Baertsh, M. May-Lozano, et al., J. Catal., 227, 479–491 (2004).

    Article  Google Scholar 

  50. J. Kh’yui, Inorganic Chemistry [in Russian], Khimiya, Moscow (1987).

    Google Scholar 

  51. R. P. Ozerov, Usp. Khim., 24, 951–984 (1955).

    Google Scholar 

  52. V. V. Brei, N. N. Levchuk, A. V. Melezhik, and K. I. Patrilyak, Katal. Neftekhim., No. 5/6, 59–65 (2000).

    Google Scholar 

  53. M. Occhiuzzi, D. Cordischi, D. Gazzoli, et al., Appl. Catal. A, 269, 169–177 (2004).

    Article  Google Scholar 

  54. S. Kuba, P. Lukinskas, R. K. Grasselli, et al., J. Catal., 216, 353–361 (2003).

    Article  Google Scholar 

  55. E. Iglesia, S. L. Soled, and G. M. Kramer, J. Catal., 144, 238–253 (1993).

    Article  Google Scholar 

  56. C. Morterra, G. Cerrato, F. Pinna, et al., J. Catal., 149, 181–188 (1994).

    Article  Google Scholar 

  57. V. Avdeeva, J. W. de Haan, J. Janchen, et al., J. Catal., 151, 364–372 (1995).

    Article  Google Scholar 

  58. T. Lopes, J. Navarrete, R. Gomes, et al., Appl. Catal. A, 125, 217–232 (1995).

    Article  Google Scholar 

  59. J. A. Navio, G. Colon, M. Masfas, et al., J. Catal., 161, 605–613 (1996).

    Article  Google Scholar 

  60. M. R. Gonzalez, J. V. Kobe, K. B. Fogash, and J. A. Dumesic, J. Catal., 160, 290–298 (1996).

    Article  Google Scholar 

  61. V. Parvulescu, S. Coman, V. I. Parvulescu, et al., J. Catal., 180, 66–84 (1998).

    Article  Google Scholar 

  62. M. Scheithauer, E. Bosh, U. A. Schubert, et al., J. Catal., 177, No.1, 137–146 (1998).

    Article  Google Scholar 

  63. Z. Gao, Y. Xia, W. Hua, and C. Miao, Top. Catal., 6, 101–106 (1998).

    Article  Google Scholar 

  64. A. V. Ivanov, T. V. Vasina, O. V. Masloboishchikova, et al., Kinet. Katal., 39, No.3, 396–406 (1998).

    Google Scholar 

  65. G. D. Yadav and J. J. Nair, Micropor. Mesopor. Mater., 33, No.1–3, 1–48 (1999).

    Article  Google Scholar 

  66. Chong-Jiang Cao, Song Han, Chang-Lin Chen, et al., Catal. Commun., 4, 511–515 (2003).

    Article  Google Scholar 

  67. M. Hino and K. Arata, React. Kinet. Catal. Lett., 81, No.2, 321–326 (2004).

    Article  Google Scholar 

  68. S. De Rossi, G. Ferraris, M. Valigi, and D. Gazzoli, Appl. Catal., 231, 173–184 (2002).

    Article  Google Scholar 

  69. W. Hua and J. Sommer, Appl. Catal., 232, 129–135 (2002).

    Article  Google Scholar 

  70. S. T. Wong, T. Li, S. Cheng, et al., J. Catal., 215, 45–56 (2003).

    Article  Google Scholar 

  71. M. Hino and K. Arata, J. Chem. Soc., Chem. Commun., 112–113 (1985).

  72. K. Arata, H. Nakamura, and M. Shouji, Appl. Catal. A, 197, 213–219 (2000).

    Article  Google Scholar 

  73. V. D. Kumari, G. Saroja, A. Ratnamala, et al., React. Kinet. Catal. Lett., 79, No.1, 45–51 (2003).

    Google Scholar 

  74. J. Deutsch, A. Trunschke, D. Muller, et al., J. Mol. Catal. A, 207, 51–57 (2004).

    Article  Google Scholar 

  75. S. Sakthivel, H. Prescott, and E. Kemnitz, J. Mol. Catal. A, 223, 137–142 (2004).

    Google Scholar 

  76. H. Sato, K. Hirose, K. Nagai, et al., Appl. Catal. A, 175, 201 (1998).

    Article  Google Scholar 

  77. V. V. Brei, S. V. Prudius, and O. V. Melezhik, Appl. Catal. A, 239, No.l, 11–16 (2003).

    Article  Google Scholar 

  78. Yu. G. Egiazarov, M. F. Savchits, and E. Ya. Ustilovskaya, Heterogeneous-Catalytic Isomerization of Hydrocarbons, Nauka i Tekhnika, Minsk (1989).

    Google Scholar 

  79. K. I. Patrylak, F. M. Bobonich, Yu. G. Voloshina, et al., Catal. Today, 65, 129–135 (2001).

    Article  Google Scholar 

  80. L. K. Patrilyak, I. A. Manza, V. I. Vypirailenko, et al., Teor. Eksp. Khim., 39, No.4, 255–259 (2003).

    Google Scholar 

  81. J. Kaur, E. F. Kozhevnikova, L. I. Griffin, et al., Kinet. Katal., 44, No.2, 190–197 (2004).

    Google Scholar 

  82. M. Hino, M. Kurashige, and K. Arata, Catal. Commun., 5, 107–109 (2004).

    Article  Google Scholar 

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Translated from Teoreticheskaya i Eksperimental’naya Khimiya, Vol. 41, No. 3, pp. 156–165, May–June, 2005.

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Brei, V.V. Superacids Based on Zirconium Dioxide. Theor Exp Chem 41, 165–175 (2005). https://doi.org/10.1007/s11237-005-0035-7

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  • DOI: https://doi.org/10.1007/s11237-005-0035-7

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