Abstract
Magnetic measurements of deposited atmospehric dust can serve as an additional parameter in assessing environmental pollution. This method is based on the assumption that atmospherically deposited particles contain significant portion of ferrimagnetic iron oxides of anthropogenic origin, which can be easily detected. Aim of this paper is to identify clearly magnetic fraction of daily samples of particulate matter less than 10 μm (PM10), routinely used for air quality assessment and monitoring. We used combination of thermomagnetic analyses and other physical and chemical methods, including scanning electron microscopy (SEM) and Mössbauer spectroscopy. Our results show that daily samples of PM10, collected at sites with different degree of atmospheric pollution, contain magnetite of spherical shape, which is presumably of industrial origin. Thus, magnetic methods can be applied directly to the same substances, which are used routinely in air quality assessment and monitoring.
Similar content being viewed by others
References
Aguilar Reyes B., Cejudo Ruiz R., Martínez-Cruz J., Bautista F., Goguitchaichvili A., Carvallo C. and Morales J., 2012. Ficus benjamina leaves as indicator of atmospheric pollution: a reconaissance study. Stud. Geophys. Geod., 56, 879–887, DOI: 10.1007/s11200-011-0265-1.
Blaha U., Sapkota B., Appel E., Stanjek H. and Rösler W., 2008. Micro-scale grain-size analysis and magnetic properties of coal-fired power plant fly ash and its relevance for environmental magnetic pollution studies. Atmos. Environ., 42, 8359–8370.
Bućko M.S., Magiera T., Johanson B., Petrovský E. and Pesonen L.J., 2011. Identification of magnetic particulates in road dust accumulated on roadside snow using magnetic, geochemical and micro-morphological analyses. Environ. Pollut., 159, 1266–1276, DOI: 10.1016/j.envpol.2011.01.030.
Čapek L., Kreibich V., Dědeček J., Grygar T., Wichterlová B., Sobalík Z., Martens J.A., Brosius R. and Tokarová V., 2005. Analysis of Fe species in zeolites by UV-VIS-NIR, IR spectra and voltammetry. Effect of preparation, Fe loading and zeolite type. Micropor. Mesopor. Mater., 80, 279–289.
Chester R., Sharples E.J., Sanders G.S., Oldfield F. and Saydam A.C., 1984. The distribution of natural and non-crustal ferrimagnetic minerals in soil-sized particulates from the Mediterranean atmosphere. Water Air Soil Pollut., 23, 25–36.
CHMI, 2007. Air Pollution Data. Annual Report, Czech Hydrometeorological Institue, Prague, Czech Republic, http://www.chmi.cz/uoco/isko/tab_roc/2007_enh/eng/index.html.
Cornell R.M. and Schwertmann U., 2003. The Iron Oxides, Structure, Properties, Reactions, Occurrences and Use. 2nd Edition. Wiley-VCH, 152–160.
Davila A.F., Rey D., Mohamed K., Rubio B. and Guerra A.P., 2006. Mapping the sources of urban dust in a coastal environment by measuring magnetic parameters of Platanus hispanica leaves. Environ. Sci. Technol., 40, 3922–3928.
Dvorská A., Lammel G., Klánová J. and Holoubek I., 2008. Kosetice, Czech Republic — ten years of air pollution monitoring and four years of evaluating the origin of persistent organic pollutants. Environ. Pollut., 156, 403–408.
Fialová H., Maier G., Petrovský E., Kapička A., Boyko T., Scholger R. and MAGPROX Team, 2006. Magnetic properties of soils from sites with different geological and environmental settings. J. Appl. Geophys., 59, 273–283.
Flanders P.J., 1994. Collection, measurement, and analysis of airborne magnetic particulates from pollution in the environment. J. Appl. Phys., 75, 5931–5936.
Flanders P.J., 1999. Identifying fly ash at a distance from fossil fuel power stations. Environ. Sci. Technol., 33, 528–532.
Gautam P., Blaha U. and Appel E., 2005. Magnetic susceptibility of dust-loaded leaves as a proxy of traffic-relatedheavy metal pollution in Kathmandu city, Nepal. Atmos. Environ., 39, 2201–2211.
Górka-Kostrubiec B., Król E. and Jeleńska M., 2012. Dependence of air pollution on meteorological conditions based on magnetic susceptibility measurements: a case study from Warsaw. Stud. Geophys. Geod., 56, 861–877, DOI: 10.1007/s11200-010-9094-x.
Grygar T., Bezdička P., Hradil D., Doménech-Carbó A, Marken F., Pikna L. and Cepriá G., 2002. Voltammetric analysis of iron oxide pigments. Analyst, 127, 1100–1107.
Hanesch M., Scholger R. and Rey D., 2003. Mapping dust distribution around an industrial site by measuring magnetic parameters of tree leaves. Atmos. Environ., 37, 5125–5133.
Hrouda F., 1994. A technique for the measurement of thermal-changes of magnetic-susceptibility of weakly magnetic rocks by the CS-2 apparatus and KLY-2 kappabridge. Geophys. J. Int., 118, 604–612.
Hunt A., 1986. The application of mineral magnetic methods to atmospheric aerosol discrimination. Phys. Earth Planet. Inter., 42, 10–21.
Kapička A., Jordanova N., Petrovský E. and Podrázský V., 2003. Magnetic study of weakly contaminated forest soils. Water Air Soil Pollut., 148, 31–44.
Kapička A., Jordanova N., Petrovský E. and Ustjak S., 2001. Effect of different soil conditions on magnetic parameters of power-plant fly ashes. J. Appl. Geophys., 48, 93–102.
Kim W., Doh S.J., Yu Y., 2009. Anthropogenic contribution of magnetic particulates in urban roadside dust. Atmos. Environ., 43, 3137–3144.
Kim W., Doha S.J., Park Z.H. and Yun S.T., 2007. Two-year magnetic monitoring in conjunction with geochemical and electron microscopic data of roadside dust in Seoul, Korea. Atmos. Environ., 41, 7627–7641.
Kruiver P.P., Dekkers M.J. and Heslop D., 2001. Quantification of magnetic coercivity components by the analysis of acquisition curves of isothermal remanent magnetisation. Earth Planet. Sci. Lett., 189, 269–276.
Kukier U., Ishak C.F., Sumner M.E. and Miller W.P., 2003. Composition and element solubility of magnetic and non-magnetic fly ash fractions. Environ. Pollut., 123, 255–266.
Lecoanet H., Leveque F. and Ambrosi J.P., 2003. Combination of magnetic parameters: an efficient way to discriminate soil-contamination sources (south France). Environ. Pollut., 122, 229–234.
Lehndorff E., Urbat M. and Schwark L., 2006. Accumulation histories of magnetic particles on pine needles as function of air quality. Atmos. Environ., 40, 7082–7096.
Maher B., Moore C. and Matyka J., 2008. Spatial variation in vehicle-derived metal pollution identified by magnetic and elemental analysis of roadside tree leaves. Atmos. Environ., 42, 364–373.
Mang C. and Kontny A., 2013. Origin of two Verwey transitions in different generations of magnetite from the Chesapeake Bay impact structure, USA. J. Geophys. Res. (in print).
Matzka J. and Maher B.A., 2002. Magnetic biomonitoring of roadside tree leaves: identification of spatial and temporal variations in vehicle-derived particulates. Atmos. Environ., 33, 4565–4569.
McIntosh G., Gomez-Paccard M. and Osete M.L., 2007. The magnetic properties of particles deposited on Platanus x hispanica leaves in Madrid, Spain, and their temporal and spatial variations. Sci. Tot. Environ., 382, 135–146.
Moreno E., Sagnotti L., Dinares-Turell J., Winkler A. and Cascella A., 2003. Biomonitoring of traffic air pollution in Rome using magnetic properties of tree leaves. Atmos. Environ., 37, 2967–2977.
Mugica V., Maubert M., Torres M., Munoz J. and Rico E., 2002. Temporal and spatial variations of metal content in TSP and PM10 in Mexico City during 1996–1998. J. Aerosol. Sci., 33, 91–102.
Muxworthy A.R., Matzka J., Davila A.F. and Petersen N., 2003. Magnetic signature of daily sampled urban atmospheric particles. Atmos. Environ., 37, 4163–4169.
Oldfield F., Hunt A., Jones M.D.H., Chester L., Dearing J.A., Olsson L. and Prospero J.M., 1985. Magnetic differentiation of atmospheric dusts. Nature, 317, 516–518.
Petrovský E. and Kapička A., 2006. On determination of the Curie point from thermomagnetic curves. J. Geophys. Res., 111, B12S27, DOI: 10.1029/2006JB004507.
Protonotarios V., Petsas N. and Moutsatsou A., 2002. Levels and composition of atmospheric particulates (PM10) in a mining-industrial site in the city of Lavrion, Greece. J. Air. Waste Manag. Assoc., 52, 11263–1273.
Sagnotti L., Macri P., Egli R. and Mondino M., 2006. Magnetic properties of atmospheric particulate matter from automatic air sampler stations in Latium (Italy): Toward a definition of magnetic fingerprints for natural and anthropogenic PM10 sources. J. Geophys. Res., 111, B12S22, DOI: 10.1029/2006JB004508.
Sagnotti L., Taddeucci J., Winkler A. and Cavallo A., 2009. Compositional, morphological, and hysteresis characterization of magnetic airborne particulate matter in Rome, Italy. Geochem. Geophys. Geosyst., 10, Q08Z06, DOI: 10.1029/2009GC002563.
Salo H., Bućko M.S., Vaahtovuo E., Limo J., Mäkinen J. and Pesonen L.J., 2012. Biomonitoring of air pollution in SW Finland by magnetic and chemical measurements of moss bags and lichens. J. Geochem. Explor., 115, 69–81, DOI: 10.1016/j.gexplo.2012.02.009.
Samet J.M., Dominici F., Curriero F.C., Coursac I. and Zeger S.L., 2000. Fine particulate air pollution and mortality in 20 US Cities, 1987–1994. N. Eng. J. Med., 343, 1742–1749.
Shu J., Dearing J.A., Morse A.P., Yu L. and Yuan N., 2001. Determining the sources of atmospheric particles in Shanghai, China, from magnetic and geochemical properties. Atmos. Environ., 35, 2615–2625.
Scholz F., Schröder U. and Gulaboski R., 2005. Electrochemistry of Immobilized Particles and Droplets. Springer. Heidelberg, Berlin, Germanz, XIII, 290 pp., ISBN: 3-540-22005-4.
Strzyszcz Z., Magiera T. and Heller F., 1996. The influence of industrial imissions on the magnetic susceptibility of soils in Upper Silesia. Stud. Geophys. Geod., 40, 276–286.
Urbat M., Lehndorff E. and Schwark L., 2004. Biomonitoring of air quality in the Cologne conurbation using pine needles as a passive sampler — Part I: magnetic properties. Atmos. Environ., 38, 3781–3792.
Xia D.S., Chen F.H., Bloemendal J., Liu X.M., Yu Y. and Yang L.P., 2008. Magnetic properties of urban dustfall in Lanzhou, China, and its environmental implications. Atmos. Environ., 42, 2198–2207.
Zhang C., Huang B., Li Y. and Liu H., 2006. Magnetic properties of high-road-side pine tree leaves in Beijing and their environ-mental significance. Chinese Sci. Bull., 51, 3041–3052, DOI: 10.1007/s11434-006-2189-7.
Zhang C., Huang B., Piper J.D.A. and Luo R., 2008. Biomonitoring of atmospheric particulate matter using magnetic properties of Salix matsudana tree ring cores. Sci. Tot. Environ., 93, 177–190, DOI: 10.1016/j.scitotenv.2007.12.032.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Petrovský, E., Zbořil, R., Grygar, T.M. et al. Magnetic particles in atmospheric particulate matter collected at sites with different level of air pollution. Stud Geophys Geod 57, 755–770 (2013). https://doi.org/10.1007/s11200-013-0814-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11200-013-0814-x