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Thermodynamic Characteristics of Gaseous GaCl3pyz and GaCl3pyzGaCl3 Complexes

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Abstract

Thermodynamic characteristics of vaporization and gas-phase dissociation of the complexes GaCl3pyz and GaCl3pyzGaCl3 (pyz is pyrazine) were determined by static tensimetry with a membrane zero gage. Structural and thermodynamic characteristics of the complexes were calculated by the B3LYP/pVDZ quantum-chemical method.

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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 8, 2005, pp. 1239–1245.

Original Russian Text Copyright © 2005 by Timoshkin, Berezovskaya, Suvorov, Misharev.

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Timoshkin, A.Y., Berezovskaya, E.A., Suvorov, A.V. et al. Thermodynamic Characteristics of Gaseous GaCl3pyz and GaCl3pyzGaCl3 Complexes. Russ J Gen Chem 75, 1173–1179 (2005). https://doi.org/10.1007/s11176-005-0391-y

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  • DOI: https://doi.org/10.1007/s11176-005-0391-y

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