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Conformational analysis of 1,3,6,2-dioxazaphosphocanes and 1,3,6,2-dioxazasilocanes

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Abstract

The steric structure of 1,3,6,2-dioxazaphosphocanes and 1,3,6,2-dioxazasilocanes in solution was established by high-resolution 1H, 13C, and 31P NMR spectroscopy and PM3 calculations. It is shown that the preferred conformation of the eight-membered heterocycle is chair-chair (crown).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    T. A. Zyablikova, E. A. Ishmaeva, V. E. Kataev, Ya. A. Vereshchagina, Z. G. Bazhanova, A. V. Il’yasov, S. A. Terent’eva & M. A. Pudovik

  2. Kazan State University, Kazan, Tatarstan, Russia

    T. A. Zyablikova, E. A. Ishmaeva, V. E. Kataev, Ya. A. Vereshchagina, Z. G. Bazhanova, A. V. Il’yasov, S. A. Terent’eva & M. A. Pudovik

  3. Kazan State Technological University, Kazan, Tatarstan, Russia

    T. A. Zyablikova, E. A. Ishmaeva, V. E. Kataev, Ya. A. Vereshchagina, Z. G. Bazhanova, A. V. Il’yasov, S. A. Terent’eva & M. A. Pudovik

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  1. T. A. Zyablikova
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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 8, 2004, pp. 1266–1272.

Original Russian Text Copyright © 2004 by Zyablikova, Ishmaeva, Kataev, Vereshchagina, Bazhanova, Il’yasov, Terent’eva, Pudovik.

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Zyablikova, T.A., Ishmaeva, E.A., Kataev, V.E. et al. Conformational analysis of 1,3,6,2-dioxazaphosphocanes and 1,3,6,2-dioxazasilocanes. Russ J Gen Chem 74, 1171–1176 (2004). https://doi.org/10.1007/s11176-005-0132-2

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  • DOI: https://doi.org/10.1007/s11176-005-0132-2

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