Abstract
Kinetic regularities of electrical mass transfer of sodium chloride and glycine in electromembrane systems containing cation-exchange membranes MK-40 and MF-4SK in aqueous solutions of sodium chloride and glycine are studied using a rotating membrane disk. Limiting current densities and limiting steps of the cation transport are determined. Parameters of homogeneous reaction of protonation of glycine zwitterions near the membranes’ surface (limiting reaction current density, reaction layer thickness, rate constant of the protonation reaction) are evaluated under limiting concentration polarization.
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Translated from Elektrokhimiya, Vol. 41, No. 3, 2005, pp. 310–316.
Original Russian Text Copyright © 2005 by Zagorodnykh, Bobreshova, Kulintsov, Aristov.
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Zagorodnykh, L.A., Bobreshova, O.V., Kulintsov, P.I. et al. Kinetics of the electrical mass transfer of sodium and glycine cations with allowance for the protonation of zwitterions in conditions of limiting concentration polarization of electromembrane systems with cation-exchange membranes. Russ J Electrochem 41, 275–279 (2005). https://doi.org/10.1007/s11175-005-0062-7
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DOI: https://doi.org/10.1007/s11175-005-0062-7