Abstract
Reactions of Pd(Acac)2 and Pd(Acac)2PPh3 complexes with triethylaluminium in an inert atmosphere are studied by the NMR and IR, electronic microscopy, and X-ray powder diffraction methods. The final products of conversion of the initial Pd(II) complexes are the Pd(0) nanoparticles with the predominant diameter 2–4 nm. The main factors determining the size of Pd(0) particles and the nature of the ligand shell are considered.
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 10, 2005, pp. 757–762.
Original Russian Text Copyright © 2005 by Belykh, Goremyka, Rokhin, Titova, Umanets, Schmidt.
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Belykh, L.B., Goremyka, T.V., Rokhin, A.V. et al. Reactions of Pd β-Diketonate Complexes with Triethylaluminium. Russ J Coord Chem 31, 719–724 (2005). https://doi.org/10.1007/s11173-005-0159-2
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DOI: https://doi.org/10.1007/s11173-005-0159-2