Skip to main content
SpringerLink
Log in

Pd complexes of (RR)- and (SS)-1,5-methylbenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane as catalysts in alternating cooligomerization of CO with dienes

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Alternating copolymerization of CO with norbornadiene and ethylidenenorbornene is studied in the presence of Pd complex with (SS)-1,5-methylbenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane ligand. The structure of cooligomers formed and cooligomerization rate are shown to depend on the catalytic system composition and comonomer structure. The obtained cooligomers are characterized by structural methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Sen, A., Acc. Chem. Res., 1993, vol. 26, no.6, p. 303.

    Article  CAS  Google Scholar 

  2. Drent, E. and Budzelaar, P.H.M., Chem. Rev., 1996, vol. 96, no.2, p. 663.

    Article  CAS  PubMed  Google Scholar 

  3. Belov, G.P., Vysokomol. Soedin., Ser. C, 2001, vol. 43, no.9, p. 1651.

    Google Scholar 

  4. Bianchini, C. and Meli, A., Coord. Chem. Rev., 2002, vol. 225, nos.1–2, p. 35.

    Article  Google Scholar 

  5. Sen, A. and Lai, T.W., J. Am. Chem. Soc., 1982, vol. 104, no.12, p. 3520.

    Article  CAS  Google Scholar 

  6. Karasik, A.A., Naumov, R.N., Sinyashin, O.G., et al., J. Chem. Soc., Dalton Trans., 2003, no. 11, p. 2209.

  7. Yuan, J.-C. and Lu, S.-J., Tetrahedron Lett., 2001, vol. 42, no.16, p. 4069.

    Article  CAS  Google Scholar 

  8. Gordon, A.J. and Ford, R.A., A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.

    Google Scholar 

  9. Karasik, A.A. and Nikonov, G.N., Zh. Obshch. Khim., 1993, vol. 19, no.12, p. 2775.

    Google Scholar 

  10. Karasik, A.A., Nikonov, G.N., Dokuchaev, A.S., and Litvinov, I.A., Koord. Khim., 1994, vol. 20, no.4, p. 300.

    CAS  Google Scholar 

  11. Karasik, A.A., Bobrov, S.V., Nikonov, G.N., et al., Koord. Khim., 1995, vol. 21, no.7, p. 574.

    Google Scholar 

  12. Bobrov, S.V., Karasik, A.A., and Sinyashin, O.G., Phosporus, Sulfur, Silicon, 1999, vols. 144–146, p. 289.

    Google Scholar 

  13. Karasik, A.A., Krashilina, A.V., Gubaidullin, A.T., et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2000, no. 10, p. 1806.

  14. Karasik, A.A., Naumov, R.N., Sommer, R., et al., Polyhedron, 2002, vol. 21, no.22, p. 2251.

    CAS  Google Scholar 

  15. Arbuzov, B.A., Erastov, O.A., Nikonov, G.N., et al., Dokl. Akad. Nauk SSSR, 1981, vol. 257, no.1, p. 127.

    CAS  Google Scholar 

  16. Arbuzov, B.A., Erastov, O.A., Nikonov, G.N., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1980, no. 3, p. 721.

  17. Arbuzov, B.A., Erastov, O.A., Nikonov, G.N., et al., Dokl. Akad. Nauk SSSR, 1982, vol. 267, no.3, p. 650.

    CAS  Google Scholar 

  18. Tsuji, J. and Hosaka, S., J. Polym. Sci., Polym. Lett., 1965, vol. 3, no.9, p. 703.

    Google Scholar 

  19. Liaw, D.J. and Tsai, J.S., J. Polym. Sci., Part A, 1997, vol. 35, no.7, p. 1157.

    Google Scholar 

  20. Kawaguchi, T., Kanno, M., Yanagihara, T., and Inoue, Y., J. Mol. Catal. A, 1999, vol. 143, nos.1–3, p. 253.

    Google Scholar 

  21. Zhang, S.-W. and Takahashi, S., J. Chem. Soc., Chem. Commun., 2000, no. 4, p. 315.

  22. Carey, F. and Sandberg, R., Advanced Organic Chemistry, New York: Plenum, 1984.

    Google Scholar 

  23. Novikova, E.V., Belov, G.P., Klauie, W., and Solotnov, A.A., Vysokomol. Soedin., Ser. C, 2003 vol. 45, no.10, p. 1605.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    E. V. Novikova & G. P. Belov

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    A. A. Karasik

  3. Institut für Anorganische Chemie der Universität, Leipzig, Germany

    E. Hey-Hawkins

Authors
  1. E. V. Novikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Karasik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Hey-Hawkins
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. P. Belov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 4, 2005, pp. 280–288.

Original Russian Text Copyright © 2005 by Novikova, Karasik, Hey-Hawkins, Belov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Novikova, E.V., Karasik, A.A., Hey-Hawkins, E. et al. Pd complexes of (RR)- and (SS)-1,5-methylbenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane as catalysts in alternating cooligomerization of CO with dienes. Russ J Coord Chem 31, 260–268 (2005). https://doi.org/10.1007/s11173-005-0087-1

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11173-005-0087-1

Keywords

Search

Navigation