Skip to main content
SpringerLink
Log in

Sorption of gold(iii) from hydrochloric acid solutions by the sorbents based on benzo-15-crown-5

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Regularities of gold sorption by the impregnated type sorbents based on a 1 M solution of benzo-15-crown-5 in nitrobenzene and benzo-15-crown-5 (30%, without diluent) were studied. The sorption isotherms were constructed, and the sorption and desorption kinetics and sorption dynamics were studied. The time of reaching sorption equilibrium, maximum capacity of the sorbents, and adsorption constants were determined. The data obtained on the time dependence of the sorption parameters are described by the pseudo-second-order kinetic curve. The conditions of gold desorption were found. Gold is quantitatively desorbed from the sorbents by a 2 M solution of ammonium thiocyanate. The sorption and desorption of gold under the dynamic conditions were studied. The dynamic and total exchange capacities of the sorbents were determined. The sorbents studied efficiently sorb gold from hydrochloric acid solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. S. Atabekyan, V. G. Avakyan, A. K. Chibisov, S. P. Gromov, S. Z. Vatsadze, V. N. Nuriev, A. V. Medved’ko, Russ. Chem. Bull., 2019, 68, 2053; DOI: https://doi.org/10.1007/s11172-019-2666-1.

    Article  CAS  Google Scholar 

  2. N. F. Goldshleger, M. A. Lapshina, V. E. Baulin, A. A. Shiryaev, Y. G. Gorbunova, A. Y. Tsivadze, Russ. Chem. Bull., 2020, 69, 1223; DOI: https://doi.org/10.1007/s11172-020-2893-5.

    Article  CAS  Google Scholar 

  3. I. I. Dovhyi, D. A. Kremenchutskii, O. N. Kozlovskaia, N. A. Bezhin, V. V. Milyutin, E. A. Kozlitin, Phys. Oceanol., 2020, 36, 387.

    Google Scholar 

  4. Ž. Grahek, S. Dulanská, G. Karanović, I. Coha, I. Tucaković, M. Nodilo, E. Mátel, J. Environ. Radioact., 2018, 181, 18.

    Article  CAS  Google Scholar 

  5. A. Zhang, C. Xiao, Y. Liu, Q. Hu, C. Chen, E. Kuraoka, J. Porous Mater., 2010, 17, 153.

    Article  CAS  Google Scholar 

  6. V. V. Shapovalov, V. V. Kanygin, A. G. Naryshkin, N. A. Nerozin, E. Ya. Smetanin, Radiochem., 2006, 48, 53.

    Article  CAS  Google Scholar 

  7. S. R. Izatt, J. S. McKenzie, N. E. Izatt, R. L. Bruening, K. E. Krakowiak, R. M. Izatt, Molecular Recognition Technology: a Green Chemistry Process for Separation of Individual Rare Earth Metals, White Paper on Separation of Rare Earth Elements, American Fork, 2016, 12 pp.; https://www.semanticscholar.org/paper/MOLECULAR-RECOGNITION-TECHNOLOGY-%3A-A-GREEN-PROCESS-Izatt-McKenzie/477e71c5b2b5f8cc66d396235a810d996494be4d.

  8. S. R. Izatt, J. S. McKenzie, R. L. Bruening, R. M. Izatt, N. E. Izatt, K. E. Krakowiak, in Metal Sustainability, Ed. R. M. Izatt, John Wiley & Sons, Ltd., Chichester, 2016, pp. 317–332.

  9. H. Poorbaygi, A. Roozbahani, K. Moradi, A. A. Habibpanah, B. Pooremad, J. Radioanal. Nucl. Chem., 2021, 327, 985.

    Article  CAS  Google Scholar 

  10. D. Choudhury, S. Lahiri, T. N. Nag, S. Sodaye, A. Bombard, J. Radioanal. Nucl. Chem., 2021, 327, 1299.

    Article  CAS  Google Scholar 

  11. J. Lehto, X. Hou, Chemistry and Analysis of Radionuclides: Laboratory Techniques and Methodology, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2011.

    Google Scholar 

  12. R. M. Pallares, R. J. Abergel, Nano Res., 2020, 13, 2887.

    Article  CAS  Google Scholar 

  13. Y. Zhao, B. Pang, H. Luehmann, L. Detering, X. Yang, D. Sultan, S. Harpstrite, V. Sharma, C. S. Cutler, Y. Xia, Y. Liu, Adv. Healthc. Mater., 2016, 5, 928.

    Article  CAS  Google Scholar 

  14. M. F. Attallah, M. A. Gizawy, H. A. Shamsel-Din, N. M. A. Mohamed, A. M. I. Ali, J. Radioanal. Nucl. Chem., 2020, 325, 447.

    Article  CAS  Google Scholar 

  15. M. Akhter, A. Mushtaq, H. M. A. Karim, M. A. Khan, Radiochim. Acta, 1994, 64, 137.

    Article  Google Scholar 

  16. M. Sadeghi, M. R. A. Rovais, N. Zandi, M. Moradi, K. Yousefi, Appl. Radiat. Isot., 2019, 154, 108877.

    Article  CAS  Google Scholar 

  17. S. R. Izatt, R. L. Bruening, R. M. Izatt, J. K. Kujanpää, International Precious Metals Institute 41st Annual Conference (Orlando, June 10–13, 2017), International Precious Metals Institute, Orlando, 2017, pp. 280–294.

    Google Scholar 

  18. R. M. Izatt, S. R. Izatt, N. E. Izatt, K. E. Krakowiak, R. L. Bruening, L. Navarro, Green Chem., 2015, 17, 2236.

    Article  CAS  Google Scholar 

  19. V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, B. N. Laskorin, Dokl. Akad. Nauk, 1992, 323, 334 [Dokl. Chem. (Engl. Transl.), 1992, 323] (in Russian).

    CAS  Google Scholar 

  20. V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, B. N. Laskorin, Dokl. Akad. Nauk, 1992, 324, 144 [Dokl. Chem. (Engl. Transl.), 1992, 324] (in Russian).

    CAS  Google Scholar 

  21. V. V. Yakshin, Sb. tez. dokl. uchastnikov II Mezhdunar. foruma po nanotekhnologiyam “Rusnanotech 09” [Abstracts of Participants of II International Forum on Nanotechnologies “Rusnanotech 09”] (Moscow, October 06–08, 2009), State Corporation “Russian Corporation of Nanotechnologies,” Moscow, 2009, pp. 533–534 (in Russian).

    Google Scholar 

  22. V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, A. Yu. Tsivadze, Dokl. Chem., 2010, 430, 32.

    Article  CAS  Google Scholar 

  23. V. V. Yakshin, O. M. Vilkova, S. M. Pluzhnik-Gladyr’, S. A. Kotlyar, Makrogeterotsikly [Macroheterocycles], 2010, 3, 114 (in Russia).

    CAS  Google Scholar 

  24. V. V. Yakshin, O. M. Vilkova, S. A. Kotlyar, A. Yu. Tsivadze, Russ. J. Coord. Chem., 2012, 38, 295.

    Article  CAS  Google Scholar 

  25. V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, A. Yu. Tsivadze, Russ. Chem. Bull., 2012, 61, 656; DOI: https://doi.org/10.1007/s11172-012-0095-5.

    Article  CAS  Google Scholar 

  26. A. A. Vydysh, I. I. Dovhyi, A. Yu. Lyapunov, Uch. zap. Krymskogo federal’nogo universiteta im. V. I. Vernadskogo. Ser. “Biologiya, khimiya” [Scientific Writings of V. I. Vernadsky Crimean Federal University. Ser. Biol. Chem.], 2015, 1, 197 (in Russian).

    Google Scholar 

  27. A. A. Vydysh, I. I. Dovhyi, N. A. Bezhin, Russ. Chem. Bull., 2018, 67, 2275; DOI: https://doi.org/10.1007/s11172-018-2370-6.

    Article  CAS  Google Scholar 

  28. Pat. RF 2699631; Byul. Izobret. [Invention Bulletin], 2019, 25, 2 pp. (in Russian).

  29. V. S. Yankovskaya, I. I. Dovhyi, V. V. Milyutin, N. A. Nekrasova, N. A. Bezhin, A. Yu. Lyapunov, J. Radioanal. Nucl. Chem., 2017, 314, 119.

    Article  CAS  Google Scholar 

  30. V. S. Yankovskaya, I. I. Dovhyi, N. A. Bezhin, V. V. Milyutin, N. A. Nekrasova, S. V. Kapranov, V. F. Shulgin, J. Radioanal. Nucl. Chem., 2018, 318, 1085.

    Article  CAS  Google Scholar 

  31. M. F. Attallah, E. H. Borai, K. F. Allan, Radiochem., 2009, 51, 622.

    Article  CAS  Google Scholar 

  32. K. Periasamy, C. Namasivayam, Ind. Eng. Chem. Res., 1994, 33, 317.

    Article  CAS  Google Scholar 

  33. Y. S. Ho, G. McKay, Process Biochem., 1999, 34, 451.

    Article  CAS  Google Scholar 

  34. V. C. Taty-Costades, H. Fauduest, C. Porte, A. Delacroix, J. Hazard. Mater., 2003, 105, 121.

    Article  Google Scholar 

Download references

Funding

This work was carried out in terms of state assignment of the Ministry of Science and Higher Education of the Russian Federation (theme “Oceanologic Processes” No. 0555-2021-0004).

Author information

Authors and Affiliations

  1. Marine Hydrophysical Institute, Russian Academy of Sciences, 2 ul. Kapitanskaya, 299011, Sevastopol, Russian Federation

    I. I. Dovhyi & N. A. Bezhin

Authors
  1. I. I. Dovhyi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Bezhin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. I. Dovhyi.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 254–259, February, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dovhyi, I.I., Bezhin, N.A. Sorption of gold(iii) from hydrochloric acid solutions by the sorbents based on benzo-15-crown-5. Russ Chem Bull 71, 254–259 (2022). https://doi.org/10.1007/s11172-022-3405-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-022-3405-6

Key words

Search

Navigation