Skip to main content
SpringerLink
Log in

New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Hydride-containing 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9 osmacarborane bearing a charge-compensated ligand was synthesized via a reaction of the deprotonated form of medium non-icosahedral 5,6-nido-C2B8H12 carborane with (PPh3)3OsCl2 in a THF solution. The structure of this complex was assigned using 1H, 11B/11B{1H}, and 31P{1H} NMR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. W. C. Kelb, Z. Demidowich, D. M. Speckman, C. B. Knobler, R. G. Teller, M. F. Hawthorne, Inorg. Chem., 1982, 21, 4027.

    Article  Google Scholar 

  2. L. Zheng, R. T. Baker, C. B. Knobler, J. A. Walker, M. F. Hawthorne, Inorg. Chem., 1983, 22, 3350.

    Article  CAS  Google Scholar 

  3. P. E. Behnken, T. B. Marder, R. T Baker, C. B. Knobler, M. R. Thompson, M. F. Hawthorne, J. Am. Chem. Soc., 1985, 107, 932.

    Article  CAS  Google Scholar 

  4. J. A. Walker, C. B. Knobler, M. F. Hawthorne, Inorg. Chem., 1985, 24, 2688.

    Article  CAS  Google Scholar 

  5. J. A. Walker, L. Zheng, C. B. Knobler, J. Soto, M. F. Hawthorne, Inorg. Chem., 1987, 26, 1608.

    Article  CAS  Google Scholar 

  6. L. I. Zakharkin, I. T. Chizhevsky, G. G. Zhigareva, P. V. Petrovskii, A. V. Polyakov, A. I. Yanovsky, Yu. T. Struchkov, J. Organomet. Chem., 1988, 358, 449.

    Article  CAS  Google Scholar 

  7. T. E. Paxon, M. F. Hawthorne, J. Am. Chem. Soc., 1974, 96, 4674.

    Article  Google Scholar 

  8. M. S. Delaney, C. B. Knobler, M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1980, 849.

  9. J. A. Belmont, J. Soto, R. E. King III, A. J. Donaldson, H. J. Dewes, M. F. Hawthorne, J. Am. Chem. Soc., 1989, 111, 7475.

    Article  CAS  Google Scholar 

  10. H. C. Kang, M. F Hawthorne, Organometallics, 1990, 9, 2327.

    Article  CAS  Google Scholar 

  11. L. I. Zakharkin, G. G. Zhigareva, Bull. Akad. Sci. USSR. Div. Chem. Sci. (Engl. Transl.), 1992, 41, 1284.

    Google Scholar 

  12. A. Demonceau, E. Saive, Y. de Froidmont, A. F. Noels, A. J. Hubert, I. T. Chizhevsky, I. A. Lobanova, V. I. Bregadze, Tetrahedron Lett., 1992, 33, 2009.

    Article  CAS  Google Scholar 

  13. I. T. Chizhevsky, P. V. Petrovskii, P. V. Sorokin, V. I. Bregadze, F. M. Dolgushin, A. I. Yanovsky, Y. T. Struchkov, A. Demonceau, A. F. Noels, Organometallics, 1996, 15, 2619.

    Article  CAS  Google Scholar 

  14. E. V. Balagurova, D. N. Cheredilin, G. D. Kolomnikova, O. L. Tok, F. M. Dolgushin, A. I. Yanovsky, I. T. Chizhevsky, J. Am. Chem. Soc., 2007, 129, 3745.

    Article  CAS  Google Scholar 

  15. V. E. Konoplev, I. V. Pisareva, E. V. Vorontsov, F. M. Dolgushin, A. Franken, J. D. Kennedy, I. T. Chizhevsky, Inorg. Chem. Commun., 2003, 6, 1454.

    Article  CAS  Google Scholar 

  16. B. Stibr, J. Plesek, S. Hermanek, Collect. Czech. Chem. Commun., 1973, 38, 338.

    Article  CAS  Google Scholar 

  17. M. Bown, X. L. Fontaine, N. N. Greenwood, J. D. Kennedy, M. Thornton-Pett, Organometallics, 1987, 6, 2254.

    Article  CAS  Google Scholar 

  18. M. Bown, B. Grüner, B. Stibr, X. L. R. Fontaine, M. Thornton-Pett, J. D. Kennedy, J. Organomet. Chem., 2000, 614–615, 269.

    Article  Google Scholar 

  19. S. V. Timofeev, I. A. Lobanova, P. V. Petrovskii, Z. A. Starikova, V. I. Bregadze, Russ. Chem. Bull., 2001, 50, 1683.

    Article  CAS  Google Scholar 

  20. V. E. Konoplev, I. V. Pisareva, D. A. Lemenovskii, P. V. Petrovskii, O. L. Tok, F. M. Dolgushin, I. T. Chizhevsky, Collect. Czech. Chem. Commun., 2002, 67, 939.

    Article  Google Scholar 

  21. I. V. Pisareva, E. V. Balagurova, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky, Russ. Chem. Bull., 2014, 63, 777.

    Article  CAS  Google Scholar 

  22. I. V. Pisareva, E. V. Balagurova, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky, Russ. Chem. Bull., 2014, 63, 1451.

    Article  CAS  Google Scholar 

  23. E. V. Balagurova, I. V. Pisareva, A. F. Smol’yakov, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky, Inorg. Chem., 2016, 55, 11193.

    Article  CAS  Google Scholar 

  24. E. V. Balagurova, A. I. Silivonenko, A. Yu. Kostyukovich, D. I. D’yachihin, A. F. Smol’yakov, F. M. Dolgushin, V. V. Minin, S. M. Peregudova, I. T. Chizhevsky, Eur. J. Inorg. Chem., 2017, 38–39, 4618.

    Article  Google Scholar 

  25. A. I. Lazareva, I. V. Pisareva, E. V. Balagurova, A. F. Smolyakov, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky, Russ. Chem. Bull., 2017, 66, 2142.

    Article  CAS  Google Scholar 

  26. C. W. Jung, M. F. Hawthorne, J. Am. Chem. Soc., 1980, 102, 3024.

    Article  CAS  Google Scholar 

  27. S. Du, A. Franken, P. A. Jelliss, J. A. Kautz, F. G. A. Stone, P.-Y. Yu, J. Chem. Soc., Dalton Trans., 2001, 1846.

  28. A. Franken, S. Du, P. A. Jelliss, J. A. Kautz, F. G. A. Stone, Organometallics, 2001, 20, 1597.

    Article  CAS  Google Scholar 

  29. I. Lobanova, I. Kosenko, J. Laskova, I. Ananyev, A. Druzina, I. Godovikov, V. I. Bregadze, S. Qi, Z. J. Lesnikowski, A. Semioshkin, Dalton Trans., 2015, 4, 1571.

    Article  Google Scholar 

  30. J. Plešek, B. Grüner, J. Macháček, I. Císařová, J. Čáslavský, J. Organomet. Chem., 2007, 692, 4801.

    Article  Google Scholar 

  31. A. Oudeman, F. Van Rantwijk, H. Van Bekkum, J. Coord. Chem., 1974, 4, 1.

    Article  CAS  Google Scholar 

  32. H. M. Colguhoun, T. J. Greenhough, M. G. H. Wallbridge, S. Heřmanek, J. Plěsek, J. Chem. Soc., Dalton Trans., 1978, 944.

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    E. V. Balagurova, I. A. Godovikov & I. T. Chizhevsky

Authors
  1. E. V. Balagurova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Godovikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. T. Chizhevsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. V. Balagurova.

Additional information

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation.

On the occasion of the 65th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Deceased.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1189–1191, June, 2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Balagurova, E.V., Godovikov, I.A. & Chizhevsky, I.T. New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9. Russ Chem Bull 69, 1189–1191 (2020). https://doi.org/10.1007/s11172-020-2888-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-020-2888-2

Key words

Search

Navigation