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Sulfoethylated polyethylenimine: synthesis in gel and sorption properties

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Abstract

Using the gel synthesis approach of polymer-analogous transformations, N-sulfoethylation of polyethylenimine was carried out by treating the polymer with sodium vinyl sulfonate. The compositions and structures of the products were characterized by elemental analysis, FT-IR spectroscopy, and 1H NMR spectroscopy. At pH 3.0–4.5 sulfoethylated polyethylenimine can selectively extract AgI and CuII from an ammonia—acetate buffer solution in the presence of a series of transition and alkaline-earth metals. At pH > 6.5 the sorbent can be used for the group extraction of a number of transition metal ions. The structural feature of the obtained derivative eliminates the selectivity of sorption of AgI ions compared to CuII ions, which has previously been revealed for the sulfoethylated derivatives of chitosan and polyaminostyrene.

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Authors and Affiliations

  1. Institute of Natural Sciences and Mathematics, Ural Federal University named after First President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    E. I. Kapitanova, A. V. Pestov, A. R. Sinelshchikova, Yu. S. Petrova & L. K. Neudachina

  2. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620990, Ekaterinburg, Russian Federation

    E. O. Zemlyakova & A. V. Pestov

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  1. E. I. Kapitanova
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  2. E. O. Zemlyakova
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  3. A. V. Pestov
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  4. A. R. Sinelshchikova
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  5. Yu. S. Petrova
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  6. L. K. Neudachina
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Correspondence to A. V. Pestov.

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Dedicated to Academician of the Russian Academy of Sciences O. N. Chupakhin on the occasion of his 85th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1252–1256, June, 2019.

The study was carried out using the equipment of the Center for Collective Use “Spectroscopy and Analysis of organic Compounds.”

This work was financially supported by the Govern ment of the Russian Federation (Resolution No. 211, Contract No. 02.A03.21.0006) and in the framework of the state task of the I. Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences.

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Kapitanova, E.I., Zemlyakova, E.O., Pestov, A.V. et al. Sulfoethylated polyethylenimine: synthesis in gel and sorption properties. Russ Chem Bull 68, 1252–1256 (2019). https://doi.org/10.1007/s11172-019-2549-5

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  • DOI: https://doi.org/10.1007/s11172-019-2549-5

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