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Spin crossover in homo- and heteroligand iron(II) complexes with tris(pyrazol-1-yl)methane derivatives

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Abstract

The studies concerning coordination compounds of various salts of iron(II) with tris(pyrazol-1-yl)methane derivatives (HC(pz)3) are discussed. The results of a number of studies on the synthesis and investigation of the homo- and heteroligand iron(II) complexes with tris(3,5- dimethylpyrazol-1-yl)methane (HC(3,5-Me2pz)3) are considered. The study of the temperature dependence μeff (T) showed that the spin crossover (SCO) 1A1↔5T2 observed in a series of the compounds discussed is accompanied by thermochromism (color change pink (purple) ↔ colorless). Specific features of the SCO and their dependence on the outer-sphere anion in the iron(II) complexes are discussed. The data of the recently published work devoted to the synthesis of the iron(II) complexes with three N-substituted HC(pz)3 derivatives (general formula xL, where x = H, CH2C6H5 (Bn) and p-SO3C6H4CH3 (Ts)) are considered.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 3 prosp. Akad. Lavrent´eva, 630090, Novosibirsk, Russian Federation

    L. G. Lavrenova

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    L. G. Lavrenova

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  1. L. G. Lavrenova
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Correspondence to L. G. Lavrenova.

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Based on the materials of the XXVII International Chugaev Conference on Coordination Chemistry (October 2–6, 2017, Nizhny Novgorod, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1142–1152, July, 2018.

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Lavrenova, L.G. Spin crossover in homo- and heteroligand iron(II) complexes with tris(pyrazol-1-yl)methane derivatives. Russ Chem Bull 67, 1142–1152 (2018). https://doi.org/10.1007/s11172-018-2195-3

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  • DOI: https://doi.org/10.1007/s11172-018-2195-3

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