Skip to main content
SpringerLink
Log in

Voltammetric determination of vitamin B6 (pyridoxine) at a graphite screen-printed electrode modified with graphene oxide/Fe3O4@SiO2 nanocomposite

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The preparation and study of electrochemical properties of a graphite screen-printed electrode (SPE) modified with the GO/Fe3O4@SiO2 (GO is graphene oxide) nanocomposites are described. The morphologies of the GO/Fe3O4@SiO2 nanocomposites were examined by scanning electron microscopy. The electrochemical oxidation of vitamin B6 (pyridoxine) on SPE modified with the GO/Fe3O4@SiO2 nanocomposite was investigated by cyclic voltammetry, differential pulse voltammetry, and chronoamperometry. Under optimum conditions (pH 7.0), the vitamin B6 oxidation at the surface of the modified SPE occurs at a potential about 190 mV less positive than that at the unmodified SPE. A linear voltammetric response for vitamin B6 was obtained in the concentration range 1.0•10 6—9.0•10 4 mol L–1 with a detection limit of 5.2•10 7 mol L–1 using differential pulse voltammetry. The developed sensor was also successfully applied for determination of trace level of vitamin B6 in both the standard vitamin B6 sample and biological samples (urine).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Ravisankar, A. Abhishekar-Reddy, B. Nagalakshmi, O. Sai-Koushik, B. Vijaya-Kumar, P. Sai-Anvith, IOSR J. Pharm., 2015, 5, 12.

    CAS  Google Scholar 

  2. W. Qu, K. Wu, S. Hu, J. Pharm. Biomed. Anal., 2004, 36, 631.

    Article  CAS  Google Scholar 

  3. M. Arriaga-Alba, N. J. Ruiz-Perez, J. Sanchez-Navarrete, B. L. de Angel, J. Flores-Lozada, J. L. Blasco, Food Chem. Toxicol., 2013, 53, 228.

    Article  CAS  Google Scholar 

  4. B. Habibi, H. Phezhhan, M. H. Pournaghi-Azar, J. Iran. Chem. Soc., 2010, 7, 103.

    Article  Google Scholar 

  5. M. Koneswaran, R. Narayanaswamy, Sens. Actuators, B, 2015, 210, 811.

    Article  CAS  Google Scholar 

  6. A. A. Alwarthan, F. A. Aly, Talanta, 1998, 45, 1131.

    Article  CAS  Google Scholar 

  7. M. L. Marszall, A. Lebiedzin´ska, W. Czarnowski, P. Szefer, J. Chromatogr. A, 2005, 1094, 91.

    Article  CAS  Google Scholar 

  8. J. H. Yang, R. J. Han, B. Y. Su, C. G. Lin, N. H. Wang, J. T. Hu, Anal. Sci., 1998, 14, 956.

    Google Scholar 

  9. G. Chen, X. Ding, Z. Cao, J. Ye, Anal. Chim. Acta, 2000, 408, 249.

    Article  CAS  Google Scholar 

  10. M. Motaghedifard, M. Behpour, S. M. Ghoreishi, E. Honar-mand, Russ. J. Electrochem. (Engl. Transl.), 2016, 52, 477.

    Article  CAS  Google Scholar 

  11. I. G. David, M. A. Florea, O. G. Cracea, D. E. Popa, M. Buleandra, E. E. Iorgulescu, A. A. Ciucu, Chem. Pap., 2015, 69, 901.

    Article  CAS  Google Scholar 

  12. T. Alizadeh, M.R. Ganjali, M. Zare, P. Norouzi, Electro-chim. Acta, 2010, 55, 1568.

    Article  CAS  Google Scholar 

  13. H. Razmi, M. Jabbari, R. Mohammad-Rezaei, Anal. Chem. Lett., 2014, 4, 73.

    Article  CAS  Google Scholar 

  14. J. P. Smith, J. P. Metters, D. K. Kampouris, C. Lledo-Fernandez, O.B. Sutcliffe, C. E. Banks, Analyst, 2013, 138, 6185.

    Article  CAS  Google Scholar 

  15. F. Arduini, C. Zanardi, S. Cinti, F. Terzi, D. Moscone, G. Palleschi, R. Seeber, Sens. Actuators, B, 2015, 212, 536.

    Article  CAS  Google Scholar 

  16. C. W. Foster, J. P. Metters, D. K. Kampouris, C. E. Banks, Electroanalysis, 2014, 26, 262.

    Article  CAS  Google Scholar 

  17. K. F. Chan, H. N. Lim, N. Shams, S. Jayabal, A. A. Pandi-kumar, N. M. Huang, Mater. Sci. Eng., C, 2016, 58, 666.

    Article  CAS  Google Scholar 

  18. M. L. Yola, V. K. Gupta, N. Atar, Mater. Sci. Eng., C, 2016, 61, 368.

    Article  CAS  Google Scholar 

  19. S. Mohammadi, H. Beitollahi, Sens. Lett., 2013, 11, 388.

    Article  CAS  Google Scholar 

  20. M. Mazloum-Ardakani, B. Ganjipour, H. Beitollahi, H. Nae-imi, M. Nejati-Barzoki, Electrochim. Acta, 2011, 56, 9113.

    Article  CAS  Google Scholar 

  21. H. Beitollahi, M. A. Taher, M. Ahmadipour, R. Hosseinza-deh, Measurement, 2014, 47, 770.

    Article  Google Scholar 

  22. E. K. Beloglazkina, A. G. Majouga, I. V. Yudin, N. A. Frol-ova, N. V. Zyk, V. D. Dolzhikova, A. A. Moiseeva, R. D. Rakhimov, K. P. Butin, Russ. Chem. Bull., 2006, 55, 1015.

    Article  CAS  Google Scholar 

  23. N. Atar, M. L. Yola, T. Eren, Appl. Surf. Sci., 2016, 362, 315.

    Article  CAS  Google Scholar 

  24. M. M. Foroughi, H. Beitollahi, S. Tajik, M. Hamzavi, H. Parvan, Int. J. Electrochem. Sci., 2014, 9, 2955.

    Google Scholar 

  25. H. Beitollahi, A. Gholami, M. R. Ganjali, Mater. Sci. Eng., C, 2015, 57, 107.

    Article  CAS  Google Scholar 

  26. L. Yang, D. Liu, J. Huang, T. You, Sens. Actuators, B, 2014, 193, 166.

    Article  CAS  Google Scholar 

  27. M. Hasheminejad, A. Nezamzadeh-Ejhieh, Food Chem., 2015, 172, 794.

    Article  CAS  Google Scholar 

  28. Z. Taleat, M. Mazloum Ardakani, H. Naeimi, M Nejati, H. Reza Zare, Anal. Sci., 2008, 24, 1039.

    Article  CAS  Google Scholar 

  29. N. B. Ashoka, B. K. Swamy, H. Jayadevappa, Anal. Bioanal. Electrochem., 2015, 7, 197.

    CAS  Google Scholar 

  30. H. Beitollahi, J. B. Raoof, H. Karimi-Maleh, R. Hosseinza-deh, J. Solid State Electrochem., 2012, 16, 1701.

    Article  CAS  Google Scholar 

  31. M. R. Akhgar, H. Beitollahi, M. Salari, H. Karimi-Maleh, H. Zamani, Anal. Methods, 2012, 4, 259.

    Article  CAS  Google Scholar 

  32. H. Bagheri, A. Afkhami, Y. Panahi, H. Khohssafar, A. Shirzadmehr, Mater. Sci. Eng. C, 2014, 37, 264.

    Article  CAS  Google Scholar 

  33. S. Tajik, M. A. Taher, H. Beitollahi, Sens. Actuators, B, 2014, 197, 228.

    Article  CAS  Google Scholar 

  34. B. Nigovi, A. Mornar, M. Serti, Microchim. Acta, 2016, 183, 1459.

    Article  Google Scholar 

  35. B. Liu, X. Ouyang, Y. Ding, L. Luo, D. Xu, Y. Ning, Talanta, 2016, 146, 114.

    Article  CAS  Google Scholar 

  36. Y. Shao, J. Wang, H. Wu, J. Liu, I. A. Aksay, Y. Lin, Electro-analysis, 2010, 22, 1027.

    Article  CAS  Google Scholar 

  37. W. Song, X. Ji, W. Deng, Q. Chen, C. Shen, C. E. Banks, Phys. Chem. Chem. Phys., 2013, 15, 4799.

    Article  CAS  Google Scholar 

  38. M. Arvand, M. Hassannezhad, Mater. Sci. Eng., C, 2014, 36, 160.

    Article  CAS  Google Scholar 

  39. A. J. Bard, L. R. Faulkner, Electrochemical Methods: Funda-mentals and Applications, 2nd ed., Wiley, New York, 2001.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran

    H. Beitollahi

  2. Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran

    F. Garkani Nejad

Authors
  1. H. Beitollahi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Garkani Nejad
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. Beitollahi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Beitollahi, H., Garkani Nejad, F. Voltammetric determination of vitamin B6 (pyridoxine) at a graphite screen-printed electrode modified with graphene oxide/Fe3O4@SiO2 nanocomposite. Russ Chem Bull 67, 238–242 (2018). https://doi.org/10.1007/s11172-018-2064-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-018-2064-0

Key words

Search

Navigation