Skip to main content
SpringerLink
Log in

Molecular and electronic structures and magnetic properties of multilayer graphene nanoclusters and their changes under the influence of adsorbed molecules

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The results of investigations of the structures and properties of multilayer graphene nano-clusters (nanographites), structural blocks of activated carbon fibers, and their changes under the influence of adsorbed molecules are presented. The presence of specific edge p-electron-ic states in the nanographites and a reversible decrease in their density at the Fermi level upon the interaction of the graphite nanoparticles with adsorbed molecules of oxygen, chlorine, and water were found. The explanation of the discovered effect was proposed in the terms of the model of spin splitting of edge p-electronic states initiated by the transfer of a small fraction of the electron density from the nanographites to adsorbed molecules. The change in the sign of the temperature coefficient of current carrier spin relaxation rate in the presence of adsorbates can be accounted for by their interaction with edge spin-split (magnetically ordered) states. The preservation of peripheral p-electronic states of the nanographites of free (dangling) s-orbitals of edge carbon atoms at saturation with chlorine was substantiated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Natelson, Nanostructures and Nanotechnology, Cambridge University Press, Cambridge, United Kingdom, 2015, 639 pp.

    Book  Google Scholar 

  2. A. Krueger, Carbon Materials and Nanotechnology, Wiley-VCH Verlag GmbH, Weinheim, Germany, 2010, 475 pp.

    Book  Google Scholar 

  3. T. Enoki, T. Ando, Physics and Chemistry of Graphene: Graphene to Nanographene, Pan Stanford Publishing Pte Ltd., Singapore, Singapore, 2013, 476 pp.

    Book  Google Scholar 

  4. T. Fauster, F. J. Himpsel, J. E. Fischer, E. W. Plummer, Phys. Rev. Lett., 1983, 51, 430.

    Article  CAS  Google Scholar 

  5. M. Posternak, A. Baldereschi, A. J. Freeman, E. Wimmer, Phys. Rev. Lett., 1984, 52, 863.

    Article  CAS  Google Scholar 

  6. A. M. Ziatdinov, N. M. Mishchenko, Yu. M. Nikolenko, Synth. Met., 1993, 59, 253.

    Article  CAS  Google Scholar 

  7. A. M. Ziatdinov, Yu. M. Nikolenko, Phys. Sol. State, 1993, 35, 1122.

    Google Scholar 

  8. M. Fujita, K. Wakabayashi, K. Nakada, K. Kusakabe, J. Phys. Soc. Jpn, 1996, 65, 1920.

    Article  CAS  Google Scholar 

  9. K. Nakada, M. Fujita, G. Dresselhaus, M. S. Dresselhaus, Phys. Rev. B, 1996, 54, 17954.

    Article  CAS  Google Scholar 

  10. K. Wakabayashi, M. Fujita, H. Ajiki, M. Sigrist, Phys. Rev. B, 1999, 59, 8271.

    Article  CAS  Google Scholar 

  11. A. M. Ziatdinov, Mendeleev Chem. J., 2004, 48, No. 5, 5.

    CAS  Google Scholar 

  12. Y. Niimi, T. Matsui, H. Kambara, K. Tagami, M. Tsukada, H. Fukuyama, Appl. Surf. Sci., 2005, 241, 43.

    Article  CAS  Google Scholar 

  13. Y. Kobayashi, K. Fukui, T. Enoki, K. Kusakabe, Phys. Rev. B, 2005, 71, 193406.

    Article  Google Scholar 

  14. Z. Klusek, W. Kozlowski, Z. Waqar, S. Datta, J. S. Burnell-Gray, I. V. Makarenko, N. R. Gall, E. V. Rutkov, A. Ya. Tontegode, A. N. Titkov, Appl. Surf. Sci., 2005, 252, 1221.

    Article  CAS  Google Scholar 

  15. K. Takai, H. Kumagai, H. Sato, T. Enoki, Phys. Rev. B, 2006, 73, 035435.

    Article  Google Scholar 

  16. Y. Shimomura, Y. Takane, K. Wakabayashi, J. Phys. Soc. Jpn, 2011, 80, 054710.

    Article  Google Scholar 

  17. M. Ziatdinov, S. Fujii, K. Kusakabe, M. Kiguchi, T. Mori, T. Enoki, Phys. Rev. B, 2013, 87, 115427.

    Article  Google Scholar 

  18. M. Ohtsuka, S. Fujii, M. Kiguchi, T. Enoki, ACS Nano, 2013, 7, 6868.

    Article  CAS  Google Scholar 

  19. X. Zhan, O. V. Yazyev, J. Feng, L. Xie, C. Tao, Y.-C. Chen, L. Jiao, Z. Pedramrazi, A. Zettl, S. G. Louie, H. Dai, M. F. Crommie, ACS Nano, 2013, 7, 198.

    Article  Google Scholar 

  20. L. Talirz, H. Sode, J. Cai, P. Ruffiex, S. Blankenburg, R. Jafaar, R. Berger, X. Feng, K. Mullen, D. Passerone, R. Fasel, C. A. Pignedoli, J. Am. Chem. Soc., 2013, 135, 2060.

    Article  CAS  Google Scholar 

  21. S. Fujii, M. Ziatdinov, M. Ohtsuka, K. Kusakabe, M. Kiguchi, T. Enoki, Faraday Discuss., 2014, 173, 173.

    Article  CAS  Google Scholar 

  22. M. Ziatdinov, S. Fujii, M. Ohtsuka, K. Kusakabe, M. Kiguchi, T. Mori, T. Enoki, Phys. Rev. B, 2014, 89, 115405.

    Article  Google Scholar 

  23. A. M. Ziatdinov, Russ. Chem. Bull., 2015, 64, 1.

    Article  CAS  Google Scholar 

  24. Y.-W. Son, M. L. Cohen, S. G. Louie, Nature, 2006, 444, 347.

    Article  CAS  Google Scholar 

  25. O. V. Yazyev, M. I. Katsnelson, Phys. Rev. Lett., 2008, 100, 047209.

    Article  Google Scholar 

  26. K. Sasaki, J. Jiang, R. Saito, S. Onari, Y. Tanaka, J. Phys. Soc. Jpn, 2007, 76, 033702.

    Article  Google Scholar 

  27. M. Kiguchi, K. Takai, V. L. J. Joly, T. Enoki, R. Sumii, K. Amemiya, Phys. Rev. B, 2011, 84, 045421.

    Article  Google Scholar 

  28. Yu. M. Nikolenko, A. M. Ziatdinov, Russ. J. Inorg. Chem., 2012, 57, 1436.

    Article  CAS  Google Scholar 

  29. A. Bellunato, H. A. Tash, Y. Cesa, G. F. Schneider, ChemPhysChem, 2016, 17, 785.

    Article  CAS  Google Scholar 

  30. F. G. Cherkasov, I. V. Ovchinnikov, A. N. Turanov, S. G. L´vov, V. A. Goncharov, A. Ya. Vitols, Low Temperature Phys., 1997, 23, 174.

    Article  Google Scholar 

  31. B. D. Shanina, A. M. Danishevski, A. I. Veynger, D. A. Kurdyukov, S. K. Gordeev, Phys. Sol. State, 2009, 51, 632.

    Article  CAS  Google Scholar 

  32. A. E. Sovestnov, A. A. Naberezhnov, Yu. A. Kumzerov, A. A. Sysoeva, V. A. Ganzha, A. I. Egorov, N. M. Okuneva, V. I. Fedorov, E. V. Fomin, Phys. Sol. State, 2013, 55, 837.

    Article  CAS  Google Scholar 

  33. D. I. Svergun, J. Appl. Crystallogr., 1992, 25, 495.

    Article  Google Scholar 

  34. O. E. Andersson, B. L. V. Prasad, H. Sato, T. Enoki, Y. Hishiyama, Y. Kaburagi, M. Yoshikawa, S. Bandow, Phys. Rev. B, 1998, 58, 16387.

    Article  CAS  Google Scholar 

  35. J. Weil, J. R. Bolton, Electron Paramagnetic Resonance: Elementary Theory and Practical Applications, Wiley-Interscience, New Jersey, 2007, 664 pp.

    Google Scholar 

  36. H. Kodera, J. Phys. Soc. Jpn, 1970, 28, 89.

    Article  CAS  Google Scholar 

  37. A. Manivannan, M. Chirila, N. C. Giles, M. S. Seehra, Carbon, 1999, 37, 1741.

    Article  CAS  Google Scholar 

  38. B. E. Warren, Phys. Rev., 1941, 59, 693.

    Article  CAS  Google Scholar 

  39. H. Fujimoto, Carbon, 2003, 41, 1585.

    Article  CAS  Google Scholar 

  40. F. Tuinstra, J. L. Koenig, J. Chem. Phys., 1970, 53, 1126.

    Article  CAS  Google Scholar 

  41. R. J. Nemanich, S. A. Solin, Phys. Rev. B, 1979, 20, 392.

    Article  CAS  Google Scholar 

  42. R. P. Vidano, D. B. Fischbach, L. J. Willis, T. M. Loehr, Solid State Commun., 1981, 39, 341.

    Article  CAS  Google Scholar 

  43. C. Beny-Bassez, J. N. Rouzaud, Scan. Electron. Microsc., 1985, 1, 119.

    Google Scholar 

  44. D. S. Knight, W. B. White, J. Mater. Res., 1989, 4, 385.

    Article  CAS  Google Scholar 

  45. A. Cuesta, P. Dhamelincourt, J. Laureyns, A. Martinez-Alonso, J. M. D. Tascon, Carbon, 1994, 32, 1523.

    Article  CAS  Google Scholar 

  46. A. C. Ferrari, J. Robertson, Phys. Rev. B, 2000, 61, 14095.

    Article  CAS  Google Scholar 

  47. A. C. Ferrari, J. Robertson, Phil. Trans. R. Soc. Lond. A., 2004, 362, 2477.

    Article  CAS  Google Scholar 

  48. S. Reich, C. Thomsen, Phil. Trans. R. Soc. Lond. A., 2004, 362, 2271.

    Article  CAS  Google Scholar 

  49. S. S. Bukalov, L. A. Mikhalitzin, Y. V. Zubavisus, L. A. Leytes, Yu. N. Novikov, Mendeleev Chem. J., 2006, 50, No. 1, 83.

    CAS  Google Scholar 

  50. M. A. Pimenta, G. Dresselhaus, M. S. Dresselhaus, L. G. Cancado, A. Jorio, R. Saito, Phys. Chem. Chem. Phys., 2007, 9, 1276.

    Article  CAS  Google Scholar 

  51. A. C. Ferrari, Solid State Commun., 2007, 143, 47.

    Article  CAS  Google Scholar 

  52. L. G. Cancado, A. Jorio, E. H. Martins Ferreira, F. Stavale, C. A. Achete, R. B. Capaz, M. V. Moutinho, A. Lombardo, T. S. Kulmala, A. C. Ferrari, Nano Lett., 2011, 11, 3190.

    Article  CAS  Google Scholar 

  53. Ping Heng Tan, S. Dimovski, Y. Gogotsi, Phil. Trans. R. Soc. Lond. A, 2004, 362, 2289.

    Article  Google Scholar 

  54. O. V. Pupysheva, A. Farajian, C. R. Knick, A. Zhamu, B. Z. Jang, J. Phys. Chem. C, 2010, 114, 21083.

    Article  CAS  Google Scholar 

  55. K. W. R. Gilkes, H. S. Sands, D. N. Batchelder, J. Robertson, W. I. Milne, Appl. Phys. Lett., 1997, 70, 1980.

    Article  CAS  Google Scholar 

  56. G. Adamopoulos, K. W. R. Gilkes, J. Robertson, N. M. J. Conway, B. Y. Kleinsorge, A. Buckley, D. N. Batchelder, Diam. Relat. Mater., 1999, 8, 541.

    Article  CAS  Google Scholar 

  57. L. J. Cancado, K. Takai, T. Enoki, M. Endo, Y. A. Kim, H. Mizusaki, A. Jorio, L. N. Coelho, R. Magalhaes-Paniago, M. A. Pimenta, Appl. Phys. Lett., 2006, 88, 163106.

    Article  Google Scholar 

  58. L. G. Cancado, A. Jorio, M. A. Pimenta, Phys. Rev. B, 2007, 76, 064304.

    Article  Google Scholar 

  59. D. R. Lenski, M. S. Fuhrer, J. Appl. Phys., 2011, 110, 013720.

    Article  Google Scholar 

  60. L. Abello, N. Rosman, F. Genet, G. Lucazeau, J. Phys. C, 1991, 7, 497.

    Google Scholar 

  61. M. M. Lucchese, F. Stavale, E. H. Martins Ferreira, C. Vilani, M. V. O. Moutinho, R. B. Capaz, C. A. Achete, A. Jorio, Carbon, 2010, 48, 1592.

    Article  CAS  Google Scholar 

  62. T. Iiyama, K. Nishikawa, N. Suzuki, K. Kaneko, Chem. Phys. Lett., 1997, 274, 152.

    Article  CAS  Google Scholar 

  63. M. Sliwinska-Bartkowiak, H. Drozdowski, M. Kempinski, M. Jazdzewska, Y. Long, J. C. Palmer, K. E. Gubbins, Phys. Chem. Chem. Phys., 2012, 14, 7145.

    Article  CAS  Google Scholar 

  64. A. M. Ziatdinov, N. M. Mishchenko, Solid State Commun., 1996, 97, 1085.

    Article  CAS  Google Scholar 

  65. J. Tian, H. Cao, W. Wu, Q. Yu, Y. P. Chen, Nano Lett., 2011, 11, 3663.

    Article  CAS  Google Scholar 

  66. M. Yamamoto, S. Obata, K. Saiki, Surf. Interface Anal., 2010, 42, 1637.

    Article  CAS  Google Scholar 

  67. D. Sabramanian, F. Libisch, Y. Li, C. Pauly, V. Geringer, R. Reiter, T. Mashoff, M. Liebmann, J. Burgdorfer, C. Busse, T. Michely, R. Mazzarello, M. Pratzer, M. Morgenstern, Phys. Rev. Lett., 2012, 108, 046801.

    Article  Google Scholar 

  68. S. K. Hamalainen, Z. Sun, M. P. Boneschanscher, A. Uppstu, M. Ijas, A. Harju, D. Vanmaekelbergh, P. Liljeroth, Phys. Rev. Lett., 2011, 107, 236803.

    Article  Google Scholar 

  69. G. O. Girit, J. C. Meyer, R. Erni, M. D. Rossell, C. Kisielovski, L. Yang, C.-H. Park, M. F. Crommie, M. L. Cohen, S. G. Louie, A. Zettl, Science, 2009, 323, 1705.

    Article  CAS  Google Scholar 

  70. M. Pan, E.C. Girao, X. Jia, S. Bhaviripudi, Q. Li, J. Kong, V. Meunier, M. S. Dresselhaus, Nano Lett., 2012, 12, 1928.

    Article  CAS  Google Scholar 

  71. P. A. Maksimov, A. V. Rozhkov, A. O. Sboychakov, Phys. Rev. B, 2013, 88, 245421.

    Article  Google Scholar 

  72. Y.-Z. Tan, B. Yang, K. Parvez, A. Narita, S. Osella, D. Beljonne, X. Feng, K. MuËllen, Nature Commun., 2013, 4, 2646.

    Google Scholar 

  73. D. C. Sorescu, K. D. Jordan, P. Avouris, J. Phys. Chem. B, 2001, 105, 11227.

    Article  CAS  Google Scholar 

  74. P. Giannozzi, R. Car, G. Scoles, J. Chem. Phys., 2003, 118, 1003.

    Article  CAS  Google Scholar 

  75. O. Leenaerts, B. Partoens, F. M. Peeters, Phys. Rev. B, 2008, 77, 1254.

    Article  Google Scholar 

  76. A. N. Rudenko, F. J. Keil, M. I. Katsnelson, A. I. Lichtenstein, Phys. Rev. B, 2010, 82, 035427.

    Article  Google Scholar 

  77. Y. Zou, F. Li, Z. H. Zhu, M. W. Zhao, X. G. Xu, X. Y. Su, Eur. Phys. J. B, 2011, 81, 475.

    Article  CAS  Google Scholar 

  78. X.-Y. Liu, J.-M. Zhang, K.-W. Xu, Physica B, 2014, 436, 54.

    Article  CAS  Google Scholar 

  79. L. Ma, J.-M. Zhang, K.-W. Xu, V. Ji, Appl. Surf. Sci., 2015, 343, 121.

    Article  CAS  Google Scholar 

  80. F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, K. S. Novoselov, Nature Mater., 2007, 6, 652.

    Article  CAS  Google Scholar 

  81. Z. H. Ni, H. M. Wang, Z. Q. Luo, Y. Y. Wang, T. Yu, Y. H. Wub, Z. X. Shena, J. Raman Spectrosc., 2010, 41, 479.

    Article  CAS  Google Scholar 

  82. V. Dua, S. P. Surwade, S. Ammu, S. R. Agnihotra, S. Jain, K. E. Roberts, S. Park, R. S. Ruoff, S. K. Manohar, Angew. Chem., Int. Ed., 2010, 49, 2154.

    Article  CAS  Google Scholar 

  83. C. W. Chen, S. C. Hung, M. D. Yang, C. W. Yeh, C. H. Wu, G. C. Chi, F. Ren, S. J. Pearton, Appl. Phys. Lett., 2011, 99, 243502.

    Article  Google Scholar 

  84. B. Huang, Z. Li, Z. Liu, G. Zhou, S. Hao, J. Wu, B. L. Gu, W. Duan, J. Phys. Chem. C, 2008, 112, 13442.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100 let Vladivostoku, 690022, Vladivostok, Russian Federation

    A. M. Ziatdinov, N. S. Saenko & P. G. Skrylnik

Authors
  1. A. M. Ziatdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. S. Saenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. G. Skrylnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Ziatdinov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0837—0848, May, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ziatdinov, A.M., Saenko, N.S. & Skrylnik, P.G. Molecular and electronic structures and magnetic properties of multilayer graphene nanoclusters and their changes under the influence of adsorbed molecules. Russ Chem Bull 66, 837–848 (2017). https://doi.org/10.1007/s11172-017-1816-6

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-017-1816-6

Keywords

Search

Navigation