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Synthesis and structure of new dinitrosyl iron complexes with bridging thiolate ligands [Fe2(μ-SR)2(NO)4]

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Abstract

Two new dinitrosyl iron complexes with bridging thiolate ligands [Fe2(µ-SR)2(NO)4], where R = n-Hex or cyclo-Hex, were synthesized and their molecular structures were analyzed. The structure of the [Fe2(µ-S-n-Hex)2(NO)4] complex was determined by X-ray diffraction. For the [Fe2(µ-S-cyclo-Hex)2(NO)4] complex, the geometry was assigned based on the results of structure-sensitive spectroscopic methods and DFT quantum chemical calculations.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute, 26 Moskovskii prosp., 190013, St. Petersburg, Russian Federation

    P. B. Davidovich, A. V. Garabadzhiu & A. N. Belyaev

  2. St. Petersburg State University, 7/9 Universitetskaya nab., 199034, St. Petersburg, Russian Federation

    V. V. Gurzhiy

Authors
  1. P. B. Davidovich
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  2. V. V. Gurzhiy
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  3. A. V. Garabadzhiu
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  4. A. N. Belyaev
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Correspondence to P. B. Davidovich.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2663—2666, November, 2015.

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Davidovich, P.B., Gurzhiy, V.V., Garabadzhiu, A.V. et al. Synthesis and structure of new dinitrosyl iron complexes with bridging thiolate ligands [Fe2(μ-SR)2(NO)4]. Russ Chem Bull 64, 2663–2666 (2015). https://doi.org/10.1007/s11172-015-1205-y

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  • DOI: https://doi.org/10.1007/s11172-015-1205-y

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