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Intramolecular spin state switching mechanisms of transition metal complexes

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Abstract

The principal molecular mechanisms that control spin state switching rearrangements of transition metal complexes are considered. A new approach to the structural design of valence tautomeric compounds involving the formation of adducts of four-coordinate metal complexes with bidentate redox-active ligands is proposed. By means of theoretical modeling methods, new molecular systems with photo-switchable magnetic properties based on transition metal complexes with photochromic ligands are suggested.

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  1. Institute of Physical and Organic Chemistry, Southern Federal University, Southern Scientific Center, Russian Academy of Sciences, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    V. I. Minkin & A. G. Starikov

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  1. V. I. Minkin
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  2. A. G. Starikov
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Correspondence to V. I. Minkin.

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Based on the plenary lecture delivered at the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0475—0498, March, 2015.

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Minkin, V.I., Starikov, A.G. Intramolecular spin state switching mechanisms of transition metal complexes. Russ Chem Bull 64, 475–497 (2015). https://doi.org/10.1007/s11172-015-0891-9

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