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Phosphoryl-containing acidic podands as extractants for recovery of f-elements

1. Synthesis and comparison of podands different in polyether chain length and structure

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Abstract

The extraction efficiency of uranium(vi), thorium(iv), and lanthanum(iii) from nitric acid solutions to 1,2-dichloroethane was compared for a series of phosphoryl podands of the acidic type different in polyether chain length and number of oxygen atoms: 2-[(HO)(EtO)(O)P]–C6H4–(OCH2CH2) m –OC6H4–2-[P(O)(EtO)(OH)] (1–3, where m = 1–3) and 2-[(HO)(EtO)(O)P]–C6H4–O(CH2)5O–C6H4–2-[P(O)(EtO)(OH)] (4). The synthesis of podands 1 and 4 obtained for the first time is described. The molecular and crystal structures of podand 1 were determined by X-ray diffraction analysis, and the formation of a strong intramolecular hydrogen bond was observed. Podand 2 is the most efficient extractant for the selective recovery of ThIV in the presence of UVI and LaIII among the studied podands. Micellar aggregates 3–5, 6–90, 3–70, and 7–10 nm in size were found by the dynamic light scattering data in thorium extracts of podands 1–4, respectively.

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Authors and Affiliations

  1. OJSC Uralchem Joint Chemical Company, 10 Presnenskaya nab., 123317, Moscow, Russian Federation

    A. M. Safiulina

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. G. Matveeva

  3. OJSC Leading Research Institute of Chemical Technology, 33 Kashirskoe sh., 115409, Moscow, Russian Federation

    D. V. Ivanets & E. M. Kudryavtsev

  4. National Research Nuclear Institute MIFI, 31 Kashirskoe sh., 115409, Moscow, Russian Federation

    E. M. Kudryavtsev

  5. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 4/31 Leninsky prosp., 119071, Moscow, Russian Federation

    M. S. Grigor´ev, V. E. Baulin & A. Yu. Tsivadze

  6. Institute of Physiologically Active Substances, Russian Academy of Sciences, 1 Severnyi proezd, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. E. Baulin

Authors
  1. A. M. Safiulina
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  2. A. G. Matveeva
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  3. D. V. Ivanets
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  4. E. M. Kudryavtsev
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  5. M. S. Grigor´ev
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  6. V. E. Baulin
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  7. A. Yu. Tsivadze
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Correspondence to A. M. Safiulina or A. G. Matveeva.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0161–0168, January, 2015.

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Safiulina, A.M., Matveeva, A.G., Ivanets, D.V. et al. Phosphoryl-containing acidic podands as extractants for recovery of f-elements. Russ Chem Bull 64, 161–168 (2015). https://doi.org/10.1007/s11172-015-0837-2

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  • DOI: https://doi.org/10.1007/s11172-015-0837-2

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