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The structure and phase transitions of crystalline polydimethylsilane [Me2Si] n revisited

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Abstract

The results of vibrational spectroscopy and X-ray diffraction obtained at the present level of the methods confirm the planar trans (all-A) conformation of the polydimethylsilane chain recently called in question. The differential scanning calorimetry data also verify the first order phase transitions at about –35 and 145 °C which proceed with retention of the all-A chain conformation and are of order-disorder type.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. S. Bukalov, L. A. Leites, R. R. Aysin, I. S. Bushmarinov, A. O. Dmitrienko, A. A. Korlyukov, M. I. Buzin, V. S. Papkov, N. A. Chernyavskaya & A. I. Chernyavskii

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  1. S. S. Bukalov
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  2. L. A. Leites
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  4. I. S. Bushmarinov
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Correspondence to S. S. Bukalov.

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Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday and the 60th anniversary of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2515—2526, November, 2014.

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Bukalov, S.S., Leites, L.A., Aysin, R.R. et al. The structure and phase transitions of crystalline polydimethylsilane [Me2Si] n revisited. Russ Chem Bull 63, 2515–2526 (2014). https://doi.org/10.1007/s11172-014-0770-9

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