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On the formation of unusual complex salts in the ternary system M(NO3)2 (M = Ni, Co)-4,4′-bipyridine-biphenylene-4,4′-bis(methylphosphinic acid)

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Abstract

It was shown for the first time that the products of the reaction of biphenylene-4,4′-bis(methylphosphinic acid), 4,4′-bipyridine, and M(NO3)2 (M = Ni, Co) under the solvothermal synthesis conditions are complex salts with the phosphinate anion instead of the expected coordination polymers. The coordination environment of the nickel ion contains, along with water molecules, only one nitrogen atom of the 4,4′-bipyridine molecule, whereas the environment of cobalt includes two nitrogen atoms of two 4,4′-bipyridine molecules.

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References

  1. R. E. Morris, P. S. Wheatley, Angew. Chem., Int. Ed., 2008, 47, 4966.

    Article  CAS  Google Scholar 

  2. A. Zamboulis, N. Moitra, J. J. E. Moreau, X. Cattoen, M. W. C. Man, J. Mater. Chem., 2010, 20, 9322–9338.

    Article  CAS  Google Scholar 

  3. S. Di Bella, Chem. Soc. Rev., 2001, 30, 355.

    Article  Google Scholar 

  4. Y. Yao, B. Guo, L. Ji, K. Jung, Z. Lin, M. Alcoutlabi, H. Hamouda, X. Zhang, Electrochem. Commun., 2011, 13, 1005.

    Article  CAS  Google Scholar 

  5. J. Yuan, Y. Xub, A. H. E. Muller, Chem. Soc. Rev., 2011, 40, 640.

    Article  CAS  Google Scholar 

  6. A. Lan, K. Li, H. Wu, D.H. Olson, T. J. Emge, W. Ki, M. Hong, J. Li, Angew. Chem., Int. Ed., 2009, 48, 2334.

    Article  CAS  Google Scholar 

  7. Z. Wang, J. M. Heising, A. Clearfield, J. Am. Chem. Soc., 2003, 125, 10375.

    Article  CAS  Google Scholar 

  8. V. Guillerm, F. Ragon, M. Dan-Hardi, T. Devic, M. Vishnuvarthan, B. Campo, A. Vimont, G. Clet, Q. Yang, G. Maurin, G. Ferey, A. Vittadini, S. Gross, Ch. Serre, Angew. Chem., Int. Ed., 2012, 51, 9267.

    Article  CAS  Google Scholar 

  9. Y.-Y. Liu, S. Couck, M. Vandichel, M. Grzywa, K. Leus, S. Biswas, D. Volkmer, J. Gascon, F. Kapteijn, J. F. M. Denayer, M. Waroquier, V. V. Speybroeck, P. D. Voort, Inorg. Chem., 2013, 52, 113.

    Article  CAS  Google Scholar 

  10. A. Lan, K. Li, H. Wu, L. Kong, N. Nijem, D. H. Olson, T. J. Emge, Y. J. Chabal, D. C. Langreth, M. Hong, J. Li, Inorg. Chem., 2009, 48, 7165.

    Article  CAS  Google Scholar 

  11. L. Pan, H. Liu, X. Lei, X. Huang, D. H. Olson, N. J. Turro, J. Li, Angew. Chem., 2003, 115, 560–564.

    Article  Google Scholar 

  12. W. Ouellette, G. Wang, H. Liu, G. T. Yee, Ch. J. O’Connor, J. Zubieta, Inorg. Chem., 2009, 48, 953.

    Article  CAS  Google Scholar 

  13. A. Baldwin, C. O. Wilson, Jr., R. I. Wagner, J. Org. Chem., 1967, 32, 2172.

    Article  CAS  Google Scholar 

  14. K. O. Kongshaug, H. Fjellvag, J. Solid State Chem., 2003, 175, 182.

    Article  CAS  Google Scholar 

  15. V. V. Kormachev, M. S. Fedoseev, Preparativnaya khimiya fosfora [Preparative Chemistry of Phosphorus], UrO RAN, Perm, 1992 (in Russian).

    Google Scholar 

  16. CrysAlis Pro: Data collection and data reduction software package, Agilent Technologies, Yarnton, Oxfordshire, UK.

  17. SCALE3 ABSPACK: Empirical absorption correction using spherical harmonics, Agilent Technologies, Yarnton, Oxfordshire, UK.

  18. G. M. Sheldrick, SHELX-97: Programs for Crystal Structure Analysis, University of Göttingen, Germany, 1997.

    Google Scholar 

  19. A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, J. Appl. Crystallogr., 1993, 26, 343.

    Article  Google Scholar 

  20. F. Macrae, I. J. Bruno, J. A. Chisholm, P. R. Edgington, P. McCabe, E. Pidcock, L. Rodriguez-Monge, R. Taylor, J. van de Streek, P. A. Wood, J. Appl. Crystallogr., 2008, 41, 466.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    A. V. Krayushkina, V. A. Milyukov & O. G. Sinyashin

  2. Institute of Inorganic Chemistry, University of Leipzig, 29 Johannisallee, D-04103, Leipzig, Germany

    P. Lönnecke & E. Hey-Hawkins

Authors
  1. A. V. Krayushkina
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  2. V. A. Milyukov
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  3. O. G. Sinyashin
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  4. P. Lönnecke
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  5. E. Hey-Hawkins
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Corresponding author

Correspondence to V. A. Milyukov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. N. Chupakhin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1599–1605, July, 2014.

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Krayushkina, A.V., Milyukov, V.A., Sinyashin, O.G. et al. On the formation of unusual complex salts in the ternary system M(NO3)2 (M = Ni, Co)-4,4′-bipyridine-biphenylene-4,4′-bis(methylphosphinic acid). Russ Chem Bull 63, 1599–1605 (2014). https://doi.org/10.1007/s11172-014-0640-5

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  • DOI: https://doi.org/10.1007/s11172-014-0640-5

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