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Synthesis, structures, sorption and magnetic properties of coordination polymers based on 3d metal pivalates and polydentate pyridine-type ligands

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Abstract

The reactions of 3d metal pivalates with pyridine-containing ligands of different structures afforded the 1D coordination polymers [Co2(Piv)4(dpe)2] n , [Ni(Piv)2(dpe)(EtOH)2] n , [Cu2(Piv)4(dpe)] n , [Cu(Piv)2(dpe)] n , [Ni(Piv)2(4-ptz)(EtOH)2] n , and [Cu2(Piv)4(4-ptz)· ·mSolv] n (Solv is EtOH, m = 2; Solv is C6H6, m = 1; Piv− is pivalate, dpe is trans-1,2-bis(4-pyridyl)ethylene, 4-ptz is 2,4,6-tris(4-pyridyl)-1,3,5-triazine), as well as the 3D coordination polymer [{Cu2(Piv)4}3(3-ptz)2] n (3-ptz is 2,4,6-tris(3-pyridyl)-1,3,5-triazine). The sorption and magnetic properties of a series of the synthesized compounds and magnetic properties of the earlier characterized coordination polymer [Mn2(O2CC6H5)4(dpe)2·dpe] n were studied. It was shown that the desolvation of the complexes [Ni(Piv)2(4-ptz)(EtOH)2] n and [Cu2(Piv)4-(4-ptz)·2EtOH] n resulted in the formation of the crystal structures, in which the pores are accessible to nitrogen and hydrogen at 78 K (S BET are up to 92 m2 g−1). The temperature dependences of the molar magnetic susceptibility for [Co2(Piv)4(dpe)2] n , [Mn2(O2CC6H5)4-(dpe)2·dpe] n , [Ni(Piv)2(dpe)(EtOH)2] n , [Ni(Piv)2(4-ptz)(EtOH)2] n , and [Cu2(Piv)4-(4-ptz)·2EtOH] n are described in terms of models taking into account the zero-field splitting and exchange interactions or isotropic exchange Hamiltonians.

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References

  1. D. Maspoch, D. Ruiz-Molina, J. Veciana, J. Mater. Chem., 2004, 14, 2713.

    Article  CAS  Google Scholar 

  2. M. Kurmoo, Chem. Soc. Rev., 2009, 38, 1353.

    Article  CAS  Google Scholar 

  3. R. Zou, A. I. Abdel-Fattah, H. Xu, Y. Zhaob, D. D. Hickmott, Cryst. Eng. Comm., 2010, 12, 1337.

    Article  CAS  Google Scholar 

  4. M. D. Allendorf, C. A. Bauer, R. K. Bhakta, R. J. T. Houk, Chem. Soc. Rev., 2009, 38, 1330.

    Article  CAS  Google Scholar 

  5. Y. Cui, Y. Yue, G. Qian, B. Chen, Chem. Rev., 2012, 112, 1126.

    Article  CAS  Google Scholar 

  6. T. L. A. Nguyen, R. Demir-Cakan, T. Devic, M. Morcrette, T. Ahnfeldt, P. Auban-Senzier, N. Stock, A.-M. Goncalves, Y. Filinchuk, J.-M. Tarascon, G. Fèrey, Inorg. Chem., 2010, 49, 7135.

    Article  CAS  Google Scholar 

  7. D. Farrusseng, S. Aguado, C. Pinel, Angew. Chem., Int. Ed., 2009, 48, 7502.

    Article  CAS  Google Scholar 

  8. J. S. Seo, D. Whang, H. Lee, S. I. Jun, J. Oh, Y. J. Jeon, K. Kim, Nature, 2000, 404, 982.

    Article  CAS  Google Scholar 

  9. H. Han, S. Zhang, H. Hou, Y. Fan, Y. Zhu, Eur. J. Inorg. Chem., 2006, 1594.

    Google Scholar 

  10. S. Qiu, G. Zhu, Chem. Rev., 2009, 253, 2891.

    CAS  Google Scholar 

  11. D. J. Tranchemontagne, J. L. Mendoza-Cortés, M. O’Keeffe, O. M. Yaghi, Chem. Soc. Rev., 2009, 38, 1257.

    Article  CAS  Google Scholar 

  12. M. A. Golubnichaya, A. A. Sidorov, I. G. Fomina, M. O. Ponina, S. M. Deomidov, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev, Russ. Chem. Bull. (Engl. Transl.), 1999, 48, 1751 [Izv. Akad. Nauk, Ser. Khim., 1999, 1773].

    Article  CAS  Google Scholar 

  13. I. L. Eremenko, M. A. Golubnichaya, S. E. Nefedov, A. A. Sidorov, I. F. Golovaneva, V. I. Burkov, O. G. Ellert, V. M. Novotortsev, L. T. Eremenko, A. Sousa, M. R. Bermezho, Russ. Chem. Bull. (Engl. Transl.), 1998, 47, 704 [Izv. Akad. Nauk, Ser. Khim., 1998, 725].

    Article  CAS  Google Scholar 

  14. I. L. Eremenko, S. E. Nefedov, A. A. Sidorov, I. I. Moiseev, Russ. Chem. Bull. (Engl. Transl.), 1999, 48, 405 [Izv. Akad. Nauk, Ser. Khim., 1999, 409].

    Article  CAS  Google Scholar 

  15. T. O. Denisova, E. V. Amel’chenkova, I. V. Pruss, Zh. V. Dobrokhotova, O. F. Fialkovskii, S. E. Nefedov, Zh. Neorg. Khim., 2006, 51, 1098 [Russ. J. Inorg. Chem. (Engl. Transl.), 2006, 51].

    CAS  Google Scholar 

  16. L. A. Barrios, J. Ribas, G. Aromí, Inorg. Chem., 2007, 46, 7154.

    Article  CAS  Google Scholar 

  17. R. A. Polunin, S. V. Kolotilov, M. A. Kiskin, K. S. Gavrilenko, L. Uab, I. L. Eremenko, V. M. Novotortsev, V. V. Pavlishchuk, Russ. Chem. Bull., Int. Ed., 2010, 59, 1217 [Izv. Akad. Nauk, Ser. Khim., 2010, 1192].

    Article  CAS  Google Scholar 

  18. A. Malik, P. Peedikakkal, Y.-M. Song, R.-G. Xiong, S. Gao, J. J. Vittal, Eur. J. Inorg. Chem., 2010, 3856.

    Google Scholar 

  19. M. Eddaoudi, D. B. Moler, H. Li, B. Chen, T. M. Reineke, M. O’Keeffe, O. M. Yaghi, Acc. Chem. Res., 2001, 34, 319.

    Article  CAS  Google Scholar 

  20. R. Nukada, W. Mori, S. Takamizawa, M. Mikuriya, M. Handa, H. Naono, Chem. Lett., 1999, 5, 367.

    Article  Google Scholar 

  21. R. S. Rarig, Jr., J. Zubieta, J. Chem. Soc., Dalton Trans., 2001, 3446.

    Google Scholar 

  22. O. Ohmori, M. Kawano, M. Fujita, Cryst. Eng. Commun., 2005, 7, 255.

    CAS  Google Scholar 

  23. L. A. Barrios, J. Ribas, G. Aromí, Inorg. Chem., 2007, 46, 7154.

    Article  CAS  Google Scholar 

  24. A. L. Spek, Acta Crystallogr., Sect. A, 1990, 46, 34.

    Google Scholar 

  25. C. F. Macrae, I. J. Bruno, J. A. Chisholm, P. R. Edgington, P. McCabe, E. Pidcock, L. Rodriguez-Monge, R. Taylor, J. van de Streek, P. A. Wood, J. Appl. Cryst., 2008, 41, 466.

    Article  CAS  Google Scholar 

  26. S. J. Gregg, K. S. W. Sing, Adsorption, Surface Area and Porosity, 2nd ed., London-New York, Academic Press, 1982.

    Google Scholar 

  27. J.-R. Li, R. J. Kuppler, H.-C. Zhou, Chem. Soc. Rev., 2009, 38, 1477.

    Article  CAS  Google Scholar 

  28. R. L. Carlin, Magnetochemistry, Springer-Verlag, Berlin-New York, 1986, 328 pp.

    Book  Google Scholar 

  29. R. A. Polunin, S. V. Kolotilov, M. A. Kiskin, O. Cador, E. A. Mikhalyova, A. S. Lytvynenko, S. Golhen, L. Ouahab, V. I. Ovcharenko, I. L. Eremenko, V. M. Novotortsev, V. V. Pavlishchuk, Eur. J. Inorg. Chem., 2010, 5055.

    Google Scholar 

  30. A. S. Litvinenko, E. A. Mikhalyova, S. V. Kolotilov, V. V. Pavlishchuk, Theor. Experim. Chem., 2010, 46, 422.

    Article  Google Scholar 

  31. https://sites.google.com/site/mjollnirmagn/

  32. S. M. Ostrovsky, R. Werner, D. A. Brown, W. Haase, Chem. Phys. Lett., 2002, 353, 290.

    Article  CAS  Google Scholar 

  33. V. V. Pavlishchuk, S. V. Kolotilov, A. W. Addison, M. J. Prushan, D. Schollmeyer, L. K. Thompson, T. Weyhermüller, E. A. Goreshnik J. Chem. Soc., Dalton Trans., 2003, 1587.

    Google Scholar 

  34. S. V. Kolotilov, D. Schollmeyer, L. K. Thompson, V. Golub, A. W. Addison, V. V. Pavlishchuk, Dalton Trans., 2008, 3007.

    Google Scholar 

  35. O. Kahn, Molecular Magnetism, Wiley-VCH, Weinheim, Germany, 1993.

    Google Scholar 

  36. C. Ma, C. Chen, Q. Liu, D. Liao, L. Li, L. Sun, New J. Chem., 2003, 27, 890.

    Article  CAS  Google Scholar 

  37. C. Ma, M. Hu, C. Chen, Q. Liu, Inorg. Chem. Commun., 2005, 8, 219.

    Article  CAS  Google Scholar 

  38. B. Albela, M. Corbella, J. Ribas, I. Castro, J. Sletten, H. Stoeckli-Evans, Inorg. Chem., 1998, 37, 788.

    Article  CAS  Google Scholar 

  39. C. S. Hong, J. H. Yoon, J. H. Lim, H. H. Ko, Eur. J. Inorg. Chem., 2005, 4818.

    Google Scholar 

  40. J. J. Borres-Almenar, J. M. Clemente-Juan, E. Coronado, F. Lloret, Chem. Phys. Lett., 1997, 275, 79.

    Article  Google Scholar 

  41. T. K. Maji, I. R. Laskar, G. Mostafa, A. J. Welch, P. S. Mukherjee, N. R. Chaudhuri, Polyhedron, 2001, 20, 651.

    Article  CAS  Google Scholar 

  42. A. V. Yakovenko, S. V. Kolotilov, O. Cador, S. Golhen, L. Ouahab, V. V. Pavlishchuk, Eur. J. Inorg. Chem., 2009, 2354.

    Google Scholar 

  43. SMART (Control) and SAINT (Integration) Software, Version 5.0, Bruker AXS Inc., Madison (WI), 1997.

  44. G. M. Sheldrick, SHELXS-97 and SHELXL97, University of Göttingen, Göttingen, Germany, 1997.

    Google Scholar 

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 prosp. Nauki, 03028, Kiev, Ukraine

    R. A. Polunin, S. V. Kolotilov & S. A. Sotnik

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. P. Burkovskaya, M. A. Kiskin & I. L. Eremenko

  3. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov

Authors
  1. R. A. Polunin
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  2. N. P. Burkovskaya
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  3. S. V. Kolotilov
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  4. M. A. Kiskin
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  5. A. S. Bogomyakov
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  6. S. A. Sotnik
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  7. I. L. Eremenko
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Correspondence to S. V. Kolotilov.

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Dedicated to Academician of the Russian Academy of Sciences A. I. Konovalov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0252–0266, January, 2014.

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Polunin, R.A., Burkovskaya, N.P., Kolotilov, S.V. et al. Synthesis, structures, sorption and magnetic properties of coordination polymers based on 3d metal pivalates and polydentate pyridine-type ligands. Russ Chem Bull 63, 252–266 (2014). https://doi.org/10.1007/s11172-014-0421-1

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  • DOI: https://doi.org/10.1007/s11172-014-0421-1

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