Abstract
Tris(2-cyanomethoxyphenyl)phosphine oxide was synthesized by the reaction of tris-(2-hydroxyphenyl)phosphine oxide with chloroacetonitrile. Its coordination properties were studied for the complexation with neodymium(iii) and copper(ii) nitrates using vibrational spectroscopy, NMR, and quantum chemical calculations.
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H. H. Dam, D. N. Reinhoudt, W. Verboom, New J. Chem., 2007, 31, 1620.
M. W. Peters, E. J. Werner, M. J. Scott, Inorg. Chem., 2002, 41, 1707.
T. S. Cameron, B. Dahlen, J. Chem. Soc., Perkin Trans. 2, 1975, 1737.
I. Yu. Kudryavtsev, T. V. Baulina, V. N. Khrustalev, P. V. Petrovskii, M. P. Pasechnik, E. E. Nifant’ev, Dokl. Akad. Nauk, 2013, 448, 657 [Dokl. Chem. (Engl. Transl.), 2013, 448, No. 2, 55].
L. S. Melvin, Tetrahedron Lett., 1981, 22, 3375.
R. C. Cambie, B. D. Palmer, Austr. J. Chem., 1982, 35, 827.
B. Dhawan, D. Redmore, J. Org. Chem., 1984, 49, 4018.
K. A. Petrov, S. V. Agafonov, V. P. Pokatun, Zh. Obshch. Khim., 1987, 57, 98 [J. Gen. Chem. USSR (Engl. Transl.), 1987, 57, No. 1].
B. Dhawan, D. Redmore, Synth. Commun., 1987, 17, 465.
L. J. Bellamy, The Infra-Red Spectra of Complex Molecules, 4th ed., Methuen, London; Wiley, New York, 1962, 425 pp.].
W. Levanson, E. H. Newman, M. Webster, Polyhedron, 2000, 19, 2697.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., Wiley, New York-Chichester-Brisbane-Toronto-Singapure, 1986.
J. R. Ferraro, J. Mol. Spectrosc., 1960, 4, 99.
D. N. Laikov, Chem. Phys. Lett., 1997, 281, 151.
D. N. Laikov, Y. A. Ustynyuk, Russ. Chem. Bull. (Int. Ed.), 2005, 54, 820 [Izv. Acad. Nauk, Ser. Khim., 2005, 804].
J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865.
D. N. Laikov, Chem. Phys. Lett., 2005, 416, 116.
W. L. F. Armarego, C. L. L. Chai, Purification of Laboratory Chemicals, Butterworth-Heinemann, 2009.
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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1085–1089, April, 2013.
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Kudryavtsev, I.Y., Baulina, T.V., Pasechnik, M.P. et al. Synthesis and coordination properties of new preorganized ligand on the triphenylphosphine oxide platform. Russ Chem Bull 62, 1086–1090 (2013). https://doi.org/10.1007/s11172-013-0146-6
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DOI: https://doi.org/10.1007/s11172-013-0146-6