Abstract
The enthalpies of formation in the standard state and in the gas phase were recommended for a series of secondary nitramines and n-butyldinitramine on the basis of the experimental enthalpies of combustion and vaporization and literature data. An analysis of the main thermochemical values (the enthalpies of formation in the gas phase and the enthalpies of atomization) showed that the energy properties of the nitramine group are independent of the structure of the molecules studied and of the number of functional groups in them. The enthalpies of formation of the alkylnitramine radicals were determined. The values obtained make it possible to calculate the bond dissociation energies in the nitramines and their radicals of different structures.
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O. A. Luk’yanov, V. P. Gorelik, V. A. Tartakovsky, Izv. Akad. Nauk, Ser. Khim., 1994, 94 [Russ. Chem. Bull. (Engl. Transl.), 1994, 43, 89].
O. A. Luk’yanov, Yu. V. Konnova, T. A. Klimova, V. A. Tartakovsky, Izv. Akad. Nauk, Ser. Khim., 1994, 1264 [Russ. Chem. Bull. (Engl. Transl.), 1994, 43, 1200].
E. A. Miroshnichenko, L. I. Korchatova, B. L. Korsunskii, B. S. Fedorov, Yu. D. Orlov, L. T. Eremenko, F. I. Dubovitskii, Dokl. Akad. Nauk SSSR, 1987, 295, 419 [Dokl. Chem. (Engl. Transl.), 1987].
B. L. Korsunskii, G. V. Sitonina, B. S. Fedorov, F. I. Dubovitskii, L. T. Eremenko, Izv. Akad. Nauk, Ser. Khim., 1989, 790 [Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1989, 38, 710].
Yu. D. Orlov, Yu. A. Lebedev, I. Sh. Saifullin, Termokhimiya organicheskikh svobodnykh radikalov [Thermochemistry of Organic Free Radicals], Nauka, Moscow, 2001, 304 (in Russian).
E. A. Miroshnichenko, V. P. Vorob’va, Zh. Fiz. Khim., 1999, 73, 419 [Russ. J. Phys. Chem. (Engl. Transl.), 1999, 73, No. 7].
Yu. N. Matyushin, T. S. Kon’kova, A. B. Vorob’ev, Author’s Certificate 1 221 568 USSR; Byul. Izobret. [Invention Bulletin], 1986, 12 (in Russian).
Yu. A. Lebedev, E. A. Miroshnichenko, Termokhimiya paroobrazovaniya organicheskikh veshchestv, Nauka, Moscow 1981, 216 (in Russian).
N. V. Chukanov, V. V. Dubikhin, A. V. Raevskii, N. I. Golovina, B. L. Korsunskii, V. V. Nedel’ko, S. M. Aldoshin, Tez. dokl. 9-i Nauchn. konf. IKhF im. N. N. Semenova RAN [Abstrs 9th Scientific Conf. N. N. Semenov Inst. Chem. Phys. Russ. Acad. Sci.], Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 2003, 44 (in Russian).
ICT Thermochemical Database, Institute of Chemical Technology, Karlsrue, Germany, 2004.
JANAF Thermochemical Tables, Suppl. Phys. Chem. Ref. Data, 1974, 3, 311.
J. D. Cox, G. Pilcher, Thermochemistry of Organic and Metalloorganic Compounds, Academic Press, London—New York, 1970, 643.
N. N. Semenov, O nekotorykh problemakh khimicheskoi kinetiki i reaktsionnoi sposobnosti [On Some Problems of Chemical Kinetics and Reactivity], Izd-vo Akad. Nauk SSSR, Moscow, 1958, 686 (in Russian).
Yu. D. Orlov, Yu. K. Knobel’, Yu. A. Lebedev, Zh. Fiz. Khim., 1987, 61, 3175 [Russ. J. Phys. Chem. (Engl. Transl.), 1987, 61, No. 12].
Yu. M. Burov, G. M. Nazin, Kinetika i kataliz, 1982, 23, 12 [Kinet. Catal. (Engl. Transl.), 1982, 23, No. 1].
Yu. Shu, B. L. Korsunskii, G. M. Nazin, Usp. Khim., 2004, 73, 320 [Russ. Chem. Rev. (Engl. Transl.), 2004, 73, No. 3].
S. W. Benson, The Foundations of Chemical Kinetics, McGrow-Hill Inc., New York—Toronto—London, 1960, 603.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1953–1957, October, 2009.
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Miroshnichenko, E.A., Kon’kova, T.S., Matyushin, Y.N. et al. Bond dissociation energies in nitramines. Russ Chem Bull 58, 2015–2019 (2009). https://doi.org/10.1007/s11172-009-0275-0
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DOI: https://doi.org/10.1007/s11172-009-0275-0