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Synthesis, structure, and luminescence properties of complex ZnLClb2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline)

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Abstract

A complex ZnLClb2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline) was synthesized. According to X-ray diffraction data, the Znp2+ ions in mononuclear molecules of the obtained complex coordinate two N atoms of the bidentate chelating ligand L and two Cl atoms. The coordination polyhedron Cl2Nb2 represents a distorted tetrahedron. In solid state at 300 K, the ligand L exhibits weak photoluminescence in the visible spectral range. The complex ZnLClb2 exhibits bright blue photoluminescence.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    Z. A. Savel’eva, R. F. Klevtsova, L. A. Glinskaya, E. M. Uskov & S. V. Larionov

  2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    S. A. Popov & A. V. Tkachev

Authors
  1. Z. A. Savel’eva
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  2. S. A. Popov
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  3. R. F. Klevtsova
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  4. L. A. Glinskaya
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  5. E. M. Uskov
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  6. A. V. Tkachev
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  7. S. V. Larionov
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Corresponding author

Correspondence to S. V. Larionov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1780–1783, September, 2009.

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Savel’eva, Z.A., Popov, S.A., Klevtsova, R.F. et al. Synthesis, structure, and luminescence properties of complex ZnLClb2 (L is 2-(3,5-dimethylpyrazol-1-yl)-4-methylquinoline). Russ Chem Bull 58, 1837–1840 (2009). https://doi.org/10.1007/s11172-009-0250-9

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  • DOI: https://doi.org/10.1007/s11172-009-0250-9

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