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Liquid-phase catalytic hydrodechlorination of aromatic chloro derivatives with metal nanopowders

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Abstract

Liquid-phase catalytic hydrodechlorination of aromatic chloro derivatives by molecular hydrogen with metal nanopowders (Fe, Ni, and Pd) and metal-carbon systems based on them are studied. Systems on the base of palladium are shown to be the most active. They can be used for hydrodechlorination of chlorinated biphenyls and phenols. The use of metal-carbon systems is more preferable.

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Authors and Affiliations

  1. I. Ya. Postovsky Institute of Organic Synthesis, Urals Branch of the Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620041, Ekaterinburg, Russian Federation

    A. V. Mekhaev, O. N. Chupakhin, M. G. Pervova, T. I. Gorbunova, V. I. Saloutin & Yu. G. Yatluk

  2. Institute of Metal Physics, Urals Branch of the Russian Academy of Sciences, 18 ul. S. Kovalevskoi, 620041, Ekaterinburg, Russian Federation

    M. A. Uimin, A. E. Ermakov & A. A. Mysik

Authors
  1. A. V. Mekhaev
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  2. O. N. Chupakhin
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  3. M. A. Uimin
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  4. A. E. Ermakov
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  5. M. G. Pervova
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  6. T. I. Gorbunova
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  7. A. A. Mysik
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  8. V. I. Saloutin
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  9. Yu. G. Yatluk
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Corresponding author

Correspondence to A. E. Ermakov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1284–1287, June, 2009.

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Mekhaev, A.V., Chupakhin, O.N., Uimin, M.A. et al. Liquid-phase catalytic hydrodechlorination of aromatic chloro derivatives with metal nanopowders. Russ Chem Bull 58, 1321–1324 (2009). https://doi.org/10.1007/s11172-009-0175-3

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  • DOI: https://doi.org/10.1007/s11172-009-0175-3

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