Abstract
Four samples of active carbons with specific micropore volumes of 0.4—1.33 cm3g-1 at 77 K and pressures up to 5 MPa were used to study hydrogen adsorption. The highest amount of of hydrogen adsorbed on these active carbons at the boiling point 20.38 K and pressure 0.101 MPa was calculated by methods derived from the theory of volumetric filling of micropores (TVFM). The adsorbent FAS-1-05 prepared by the liquid-phase polymerization of furfurol was shown to have the highest adsorption capacity. The amounts of hydrogen adsorbed on FAS-1-05 at temperatures 77, 196, and 300 K and pressures 7 and 20 MPa were calculated using the TVFM methods with allowance for linearity of the isosters. The results were compared with the experimental values obtained at 77 K and pressure below 5.1 MPa and at 293 K and pressures up to 16.1 MPa. The highest amounts of hydrogen adsorbed (6.2 wt.% for the adsorbent FAS-1-05) were obtained under pressures below 5.1 MPa and at 77 K.
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1 nm3(H2) m-3 is the cubic meter of hydrogen under normal pressure and temperature (101 kPa, 293 K) referred to the cubic meter of the volume of the storage material.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 697–701, April, 2009.
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Fomkin, A.A., Sinitsyn, V.A. & Gur’yanov, V.V. Adsorption of hydrogen on nanoporous carbon adsorbents. Russ Chem Bull 58, 712–716 (2009). https://doi.org/10.1007/s11172-009-0082-7
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DOI: https://doi.org/10.1007/s11172-009-0082-7