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Photochemical arene exchange in the naphthalene complex [CpRu(η6-C 10H8)]+

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Abstract

The cation [CpRu(η6-C10H8)]+ was shown to exchange naphthalene for other arenes under visible-light irradiation to form the complexes [CpRu (η6-arene)]+ (arene = C6H6, 1,4-C6H4Me2, 1,3,5-C6H3Me3, or 1,2,4,5-C 6H2Me4) in 70–95% yields. The reaction rate of exchange decreases in the series arene = 1,4-C6H4Me2 > C6H6 > 1,3,5-C6H3Me3 > 1,2,4,5-C 6H2Me4 >> C6Me6 and increases with the coordinating ability of the solvent in the order CH2Cl2 < THF—CH2Cl2 mixture (1: 1) < acetone.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    E. E. Karslyan, D. S. Perekalin, P. V. Petrovskii, A. O. Borisova & A. R. Kudinov

Authors
  1. E. E. Karslyan
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  2. D. S. Perekalin
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  3. P. V. Petrovskii
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  4. A. O. Borisova
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  5. A. R. Kudinov
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Corresponding author

Correspondence to A. R. Kudinov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 572–574, March, 2009.

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Karslyan, E.E., Perekalin, D.S., Petrovskii, P.V. et al. Photochemical arene exchange in the naphthalene complex [CpRu(η6-C 10H8)]+ . Russ Chem Bull 58, 585–588 (2009). https://doi.org/10.1007/s11172-009-0059-6

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  • DOI: https://doi.org/10.1007/s11172-009-0059-6

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