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Photophysical and electrochemical properties of the outer-sphere associate of [Ru(bipy)3]2+ with p-sulfonatothiacalix[4]arene

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Abstract

1H NMR titration and X-ray diffraction analysis revealed that [Ru(bipy)3]2+ forms an outer-sphere inclusion complex with p-sulfonatothiacalix[4]arene in a ratio of 1: 1 in both aqueous solutions and the solid state. According to cyclic voltammograms and fluorimetric data, the outer-sphere association of [Ru(bipy)3]2+ with p-sulfonatothiacalix[4]arene changes the reversible character of the electrochemical oxidation of [Ru(bipy)3]2+ and lowers its emission intensity.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    A. R. Mustafina, V. V. Skripacheva, V. A. Burilov, A. T. Gubaidullin, N. V. Nastapova, V. V. Yanilkin, S. E. Solovieva, I. S. Antipin & A. I. Konovalov

  2. Kazan State University, 18 ul. Kremlevskaya, 420088, Kazan, Russian Federation

    I. S. Antipin

Authors
  1. A. R. Mustafina
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  2. V. V. Skripacheva
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  3. V. A. Burilov
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  4. A. T. Gubaidullin
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  5. N. V. Nastapova
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  6. V. V. Yanilkin
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  7. S. E. Solovieva
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  8. I. S. Antipin
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  9. A. I. Konovalov
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Corresponding author

Correspondence to V. V. Skripacheva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1863–1870, September, 2008.

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Mustafina, A.R., Skripacheva, V.V., Burilov, V.A. et al. Photophysical and electrochemical properties of the outer-sphere associate of [Ru(bipy)3]2+ with p-sulfonatothiacalix[4]arene. Russ Chem Bull 57, 1897–1904 (2008). https://doi.org/10.1007/s11172-008-0256-8

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  • DOI: https://doi.org/10.1007/s11172-008-0256-8

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