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New cage-like metallasiloxane containing FeIII ions in different coordination spheres

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Abstract

The first cage-like ferrophenyl siloxane containing FeIII ions in different coordination spheres (four iron ions have a trigonal-bipyramidal coordination and two iron ions have a distorted octahedral coordination) was synthesized by the exchange reaction of sodium phenylsilanolate with FeIII chloride. An exotic lantern-like structure is formed with the involvement of two metal oxide fragments Fe—O—Fe. The structure of this compound was established by X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. N. Bilyachenko, A. A. Korlyukov, M. M. Levitskii, M. Yu. Antipin & B. G. Zavin

Authors
  1. A. N. Bilyachenko
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  2. A. A. Korlyukov
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  3. M. M. Levitskii
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  4. M. Yu. Antipin
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  5. B. G. Zavin
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Corresponding author

Correspondence to M. M. Levitskii.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 522–524, March, 2007.

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Bilyachenko, A.N., Korlyukov, A.A., Levitskii, M.M. et al. New cage-like metallasiloxane containing FeIII ions in different coordination spheres. Russ Chem Bull 56, 543–545 (2007). https://doi.org/10.1007/s11172-007-0087-z

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  • DOI: https://doi.org/10.1007/s11172-007-0087-z

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