Abstract
Axial coordination of the pyrrolidine nitrogen atom in cis-1,3-di(2-pyridyl)[60]fullereno[1,2-c]pyrrolidine to zinc meso-tetraphenylporphyrinate in cyclohexane gives rise to a donor-acceptor complex. The formation constant of the 1: 1 porphyrin—fullerenopyrrolidine complex was determined by spectrophotometric and fluorescence titration. The values of the constant estimated by spectrophotometric and fluorescence methods are 1.2·104 and 9.7·103 L mol−1, respectively.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2265–2269, October, 2005.
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Lapshin, A.N., Smirnov, V.A., Lyubovskaya, R.N. et al. Spectroscopic study of the reaction of cis-1,3-di(2-pyridyl)[60]fullereno[1,2-c]pyrrolidine and 2-(2-pyridylmethyl)-1,3-di(2-pyridyl)[60]fullereno[1,2-c]pyrrolidine with zinc meso-tetraphenylporphyrinate. Russ Chem Bull 54, 2338–2342 (2005). https://doi.org/10.1007/s11172-006-0119-0
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DOI: https://doi.org/10.1007/s11172-006-0119-0