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Transformations of phosphazane ligands in the coordination sphere of transition metals. Reactions of phosphinotriazene Ph2P-N(Ph)-N=NPh with Ni0 and NiI complexes

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Abstract

3-(Diphenylphosphino)-1,3-diphenyltriazene Ph2P-NPh-N=NPh was synthesized. The reactions of this compound with bis(cycloocta-1,5-diene)nickel, (cod)2Ni, and nickel(I) bis(triphenylphosphino)bis(trimethylsilyl)amide, (Ph3P)2Ni-N(SiMe3)2, afforded the anionic nickel complex [Ph4P]+[Ni(PhNNNPh)3]− in 15 and 78% yields, respectively.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    V. V. Sushev, A. N. Kornev, Yu. A. Kurskii, O. V. Kuznetsova, G. K. Fukin & G. A. Abakumov

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  1. V. V. Sushev
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  2. A. N. Kornev
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  3. Yu. A. Kurskii
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  4. O. V. Kuznetsova
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  5. G. K. Fukin
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  6. G. A. Abakumov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1585–1589, July, 2005.

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Sushev, V.V., Kornev, A.N., Kurskii, Y.A. et al. Transformations of phosphazane ligands in the coordination sphere of transition metals. Reactions of phosphinotriazene Ph2P-N(Ph)-N=NPh with Ni0 and NiI complexes. Russ Chem Bull 54, 1632–1636 (2005). https://doi.org/10.1007/s11172-006-0015-7

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  • DOI: https://doi.org/10.1007/s11172-006-0015-7

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