Abstract
Hexachlorobenzene and 1,2,4,5-tetrachlorobenzene react with phenylboronic acid by a C—C cross-coupling mechanism with a Pd(dba)2/P(But)3 system (dba is dibenzylideneacetone) or palladium-azole complexes as catalysts, or with organozinc compounds in the presence of Pd(PPh3)4 to afford substitution products of one or two chlorine atoms in moderate yields.
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Dedicated to Corresponding Member of the Russian Academy of Sciences E. P. Serebryakov on the occasion of his 70th birthday.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 947–951, April, 2005.
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Burukin, A.S., Vasil'ev, A.A., Chizhov, A.O. et al. Cross-coupling of polychloroarenes with phenylboronic acid and organozinc compounds catalyzed by palladium complexes. Russ Chem Bull 54, 970–974 (2005). https://doi.org/10.1007/s11172-005-0342-0
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DOI: https://doi.org/10.1007/s11172-005-0342-0